聚丙烯酸功能化高效发光的La1-xEuxF3纳米晶合成及细胞成像

doi:10.3866/PKU.WHXB201704102

Abstract

Abstract:

Monodisperse La_1-xEu_xF₃ nanoparticles (NPs) were functionalized by poly(acrylic acid) (PAA) via a one-pot modified hydrothermal method. The morphology, crystal structure, surface groups, and luminescence properties of the as-produced La_1-xEu_xF₃@PAA NPs were characterized by transmission electron microscopy (TEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and photoluminescence (PL) spectroscopy. The produced nanoparticles were (7±3) nm in size, water soluble, and buffer stable, with good photostability and biocompatibility. In vitro imaging revealed the low cytotoxicity of the as-synthesized NPs incubated with HeLa cancer cells. Thus, the colloidal La_1-xEu_xF₃@PAA NPs exhibit great potential for use as optical imaging probes in biological applications.

Key words: Lanthanide nanoparticle, Hydrothermal, Aqueous dispersion, Efficient luminescence, Bioimaging

Fan CHEN,Zhong-Yue WANG,Yan-Yan ZHANG,Ke-Han YU,Li-Xing WENG,Wei WEI. Synthesis of Poly(acrylic acid)-Functionalized La_1-xEu_xF₃ Nanocrystals with High Photoluminescence for Cellular Imaging[J]. Acta Phys. -Chim. Sin. 2017, 33(7), 1446-1452. doi: 10.3866/PKU.WHXB201704102

References

1	Fu X. Y. ; Shao G. S. ; Han R. C. ; Ma Y. ; Xue F. M. ; Yang F. ; Fu L. M. ; Zhang J. P. ; Wang Y. Acta Phys. -Chim. Sin. 2012, 28, 2480.
1	符小艺; 邵光胜; 韩荣成; 马严; 薛富民; 杨帆; 付立民; 张建平;王远. 物理化学学报, 2012, 28, 2480.
2	Ferrari M. Nat. Rev. Cancer 2005, 5, 161.
3	Lv R. ; Yang G. ; He F. ; Dai Y. ; Gai S. ; Yang P. Nanoscale 2014, 6, 14799.
4	Riehemann K. ; Schneider S. W. ; Luger T. A. ; Godin B. ; Ferrari M. ; Fuchs H. Angew. Chem. Int. Ed. 2009, 48, 872.
5	Michalet X. ; Pinaud F. F. ; Bentolila L. A. ; Tsay J. M. ; Doose S. ; Li J. J. ; Sundaresan G. ; Wu A. M. ; Gambhir S. S. ; Weiss S. Science 2005, 307, 538.
6	Dubertret B. ; Skourides P. ; Norris D. J. ; Noireaux V. ; Brivanlou A. H. ; Libchaber A. Science 2002, 298, 1759.
7	Yuwen L. H. ; Xue B. ; Wang L. H. Acta Phys. -Chim. Sin. 2014, 30, 994.
7	宇文力辉; 薛冰; 汪联辉. 物理化学学报, 2014, 30, 994.
8	Widengren J. ; Chmyrov A. ; Eggeling C. ; L fdahl P. A. ; Seidel C. A. J. Phys. Chem. A. 2007, 111, 429.
9	Eggeling C. ; Widengren J. ; Brand L. ; Schaffer J. ; Felekyan S. A. ; Seidel C. A. M. J. Phys. Chem. A. 2006, 110, 2979.
10	Barreto J. A. ; O'Malley W. ; Kubeil M. ; Graham B. ; Stephan H. ; Spiccia L. Adv. Mater. 2011, 23, 18.
11	Sutherland A. J. Curr. Opin. Solid State Mater. Sci. 2002, 6, 365.
12	Chen G. ; Ohulchanskyy T. Y. ; Liu S. ; Law W. C. ; Wu F. ; Swihart M. T. ; gren H. ; Prasad P. N. ACS Nano 2012, 6, 2969.
13	Bouzigues C. ; Gacoin T. ; Alexandrou A. ACS Nano 2011, 5, 8488.
14	Vetrone F. ; Capobianco J. A. Int. J. Nanotechnol. 2008, 5, 1306.
15	Shen J. ; Sun L. D. ; Yan C. H. Dalton Trans. 2008, 42, 5687.
16	Bünzli J. C. Chem. Rev. 2010, 110, 2729.
17	Li F. ; Li C. ; Liu X. ; Bai T. ; Dong W. ; Zhang X. ; Shi Z. ; Feng S. Dalton Trans. 2013, 42, 2015.
18	Mimun L. C. ; Ajithkumar G. ; Pokhrel M. ; Yust B. G. ; Elliott Z. G. ; Pedraza F. ; Dhanale A. ; Tang L. ; Lin A. L. ; Dravid V. P. J. Mater. Chem. 2013, 1, 5702.
19	Ghosh C. R. ; Paria S. Chem. Rev. 2011, 112, 2373.
20	Yu X. F. ; Chen L. D. ; Li M. ; Xie M. Y. ; Zhou L. ; Li Y. ; Wang Q. Q. Adv. Mater. 2008, 20, 4118.
21	Wang F. ; Zhang Y. ; Fan X. ; Wang M. Nanotechnology 2006, 17, 1527.
22	Ma Z. Y. ; Dosev D. ; Nichkova M. ; Gee S. J. ; Hammock B. D. ; Kennedy I. M. J. Mater. Chem. 2009, 19, 4695.
23	Zhang W. ; Hua R. ; Shao W. ; Zhao J. ; Na L. J. Nanosci. Nanotechnol. 2014, 14, 3690.
24	Wu X. ; Zhang Q. ; Wang X. ; Yang H. ; Zhu Y. Eur. J. Inorg. Chem. 2011, 2011, 2158.
25	Tian Y. ; Tian J. ; Li X. ; Yu B. ; Shi T. Chem. Commun. 2011, 47, 2847.
26	Gupta B. K. ; Narayanan T. N. ; Vithayathil S. A. ; Lee Y. ; Koshy S. ; Reddy A. L. M. ; Saha A. ; Shanker V. ; Singh V. N. ; Kaipparettu B. A. Small 2012, 8, 3028.
27	Chen G. ; Ohulchanskyy T. Y. ; Kumar R. ; Agren H. ; Prasad P. N. ACS Nano 2010, 4, 3163.
28	Wang L. ; Zhang Y. ; Zhu Y. Nano Res. 2010, 3, 317.
29	Ju Q. ; Luo W. ; Liu Y. ; Zhu H. ; Li R. ; Chen X. Nanoscale 2010, 2, 1208.

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Synthesis of Poly(acrylic acid)-Functionalized La_1-xEu_xF₃ Nanocrystals with High Photoluminescence for Cellular Imaging

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Synthesis of Poly(acrylic acid)-Functionalized La_1-xEu_xF₃ Nanocrystals with High Photoluminescence for Cellular Imaging