Acta Phys. -Chim. Sin. ›› 1989, Vol. 5 ›› Issue (04): 487-491.doi: 10.3866/PKU.WHXB19890421
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An Xuwu*; Zheng Xiaolin
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Abstract: By using an LKB 8721-3 vaporization calorimeter, enthalpies of vaporization of o-and m-dichlorobenzenes and enthalpy of sublimation of p-dichlorobenzene at 298.15K were determined as 48.53±0.12, 47.40±0.08 and 65.15±0.20 kJ mol~(-1) respectively. Data of ΔH_v~° and ΔH_s~° for chlorobenzenes reported here and in literature and their normal boiling points, t_b in ℃, can fit following two linear equations: ΔH_v~° (kJ mol~(-1))=17.51+0.17269 t_b; ΔH_s~° (kJ mol~(-1))=26.25+0.22349 t_b. From these equations other unknown values of ΔH_v~°and ΔH_s~°of chlorobenzenes have been estimated.
An Xuwu*; Zheng Xiaolin. DETERMINATION OF STANDARD ENTHALPIES OF VAPORIZATION AND SUBLIMATION OF THREE DICHLOROBENZENES[J]. Acta Phys. -Chim. Sin. 1989, 5(04), 487-491. doi: 10.3866/PKU.WHXB19890421
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URL: https://www.whxb.pku.edu.cn/EN/10.3866/PKU.WHXB19890421
https://www.whxb.pku.edu.cn/EN/Y1989/V5/I04/487
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