Acta Phys. -Chim. Sin. ›› 1994, Vol. 10 ›› Issue (03): 230-234.doi: 10.3866/PKU.WHXB19940308

• ARTICLE • Previous Articles     Next Articles

A Study on the Co(II) Schiff Base Complex with Carrying O2 and N2 Properties

Li Chong-Jia, Zhang Wen-Tao, Guo Guo-Lin, Xie You-Chang   

  1. Institute of Physical Chemistry, Peking University, Beijing 100871
  • Received:1992-08-12 Revised:1993-02-05 Published:1994-03-15
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Abstract:

The character of Co(Ⅱ) Schiff base complex carrying O_2 was studied by INDO-UHF method. The results showed that the interaction between Co(Ⅱ) and O_2 was completed through σ bond, and the antiferro magnetic coupling was obvious. The ne cessity of fifth axial ligand in the reversible process of O_2 carring was discussed. The interaction between Co(Ⅱ) and N_2 was also studied in comparasion with Co-O_2. The cal culation showed that Co(Ⅱ) Schiff base have potential value for industrial application.

Key words: Co(II) Schiff base complex, INDO-UHF program, Carrying O2 property