Acta Phys. -Chim. Sin. ›› 2003, Vol. 19 ›› Issue (11): 1081-1084.doi: 10.3866/PKU.WHXB20031120

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Rheological Characteristics of Aqueous Solutions of an Amphoteric Guar Gum Derivative

Zhou Jian-Fang;Zhang Li-Ming;Peter S. Hui   

  1. Institute of Polymer Science, Zhongshan University, Guangzhou 510275; China Agency Office of Economy Polymers & Chemicals Company of USA, Guangzhou 510030
  • Received:2003-04-25 Revised:2003-07-04 Published:2003-11-15
  • Contact: Zhang Li-Ming E-mail:ceszhlm@zsu.edu.cn

Abstract: The rheological characteristics of aqueous solutions of an amphoteric guar gum derivative, namely E-AMPHO-S, were studied in terms of the effects of its concentration, added salts and temperature by means of a rotating rheometer. It was found that E-AMPHO-S solutions investigated behaved as non-Newtonian shear-thinning fluids. With the increase of E-AMPHO-S concentration from 0.1% to 2.0%(g•mL-1), the consistency coefficient increased while the viscosity behavior index decreased. The thixotropic response became stronger when E-AMPHO-S concentration was increased from 1.0% to 3.0%(g•mL-1). The obvious viscosity behavior of “anti-polyelectrolye solution” was observed in aqueous salt solutions containing calcium chloride. The zero shear viscosity (η0) could be obtained by using Spencer-Dillon equation, and the temperature dependence of η0 could be expressed by a relation of the form of the Arrhenius equation.

Key words: Guar gum derivative, Rheological property, Pseudoplastic fluid,  Thixotropy, Anti-polyelectrolyte solution behavior, Zero shear viscosity