Ca@C88和Ca@C90的合成、分离和表征

doi:10.3866/PKU.WHXB20040604

Acta Phys. -Chim. Sin. ›› 2004, Vol. 20 ›› Issue (06): 573-576.doi: 10.3866/PKU.WHXB20040604

• Communication • Previous Articles Next Articles

Preparation,Isolation and Characterization of Ca@C₈₈ and Ca@C₉₀

Zhang Ya;Shi Zu-Jin;Hao Ce;Xu Jian-Xun;He Xiao-Ran;Gu Zhen-Nan

College of Chemistry and Molecular Engineering, Peking University, Beijing　100871;School of Chemical Engineering, Dalian Institute of Technology, Dalian　116028

Received:2004-02-27 Revised:2004-03-25 Published:2004-06-15
Contact: Shi Zu-Jin E-mail:zjshi@chem.pku.edu.cn

Abstract

Abstract: Ca-containing Endohedral Metallofullerenes were synthesized by DC arc discharge method.C88 and C90-based group-2 metallofullerenes, Ca@C88 and Ca@C90 (I, II),were first isolated by multi-stage high-performance liquid chromatography (HPLC).All species were characterized by MAL-DI-TOF MS and UV-Vis-NIR absorption spectroscopy. Their electronic structure and possible molecular symmetries were discussed according to their retention times and absorption spectra.

Key words: Endohedral metallofullerenes, Calcium, Absorption spectrum

Zhang Ya;Shi Zu-Jin;Hao Ce;Xu Jian-Xun;He Xiao-Ran;Gu Zhen-Nan. Preparation,Isolation and Characterization of Ca@C₈₈ and Ca@C₉₀[J].Acta Phys. -Chim. Sin., 2004, 20(06): 573-576.

[1]	Yan WANG,Xiong LI,Shanwei HU,Qian XU,Huanxin JU,Junfa ZHU. Morphologies and Electronic Structures of Calcium-Doped Ceria Model Catalysts and Their Interaction with CO₂ [J]. Acta Phys. -Chim. Sin., 2018, 34(12): 1381-1389.
[2]	Qian ZHU,Chao-Tun CAO,Chen-Zhong CAO. Extension and Application of Excited-State Constants of meta-Substituents [J]. Acta Phys. -Chim. Sin., 2017, 33(4): 729-735.
[3]	Jin SUN,Zong-Ling DING,Yuan-Qin YU,Guang LI. Absorption Spectra of Azobenzene Molecules on Au Nanoparticle Surface [J]. Acta Phys. -Chim. Sin., 2017, 33(11): 2199-2206.
[4]	Ying-Chun JIN,Xu-Ming ZHENG. UV Absorption and Resonance Raman Spectra of 2, 4-Dithiouracil [J]. Acta Physico-Chimica Sinica, 2017, 33(10): 1989-1997.
[5]	Hua-Bin CHEN,Xiao-Hui ZHANG,Li-Zhen GONG,Jing HE,Xuan XU,Zhi-Guang XU,Hai-Yang LIU. Effect of β-Substituents on the Electronic Absorption Spectra of Manganese(Ⅴ)-oxo Corrole Complexes [J]. Acta Phys. -Chim. Sin., 2016, 32(8): 1983-1989.
[6]	Li-Mei. HOU,Zhi. WEN,Yin-Xiang. LI,Hua-You. HU,Yu-He. KAN,Zhong-Min. SU. Molecular Design of Indolizine Derivative as Sensitizers for Organic Dye-Sensitized Solar Cells [J]. Acta Phys. -Chim. Sin., 2015, 31(8): 1504-1512.
[7]	DING Jun-Jie, DING Xiao-Qin, LI Da-Yu, PAN Li, CHEN Ji-Sheng. Quantitative Structure-Activity Relationship and Virtual Screening of ω-Conotoxins [J]. Acta Phys. -Chim. Sin., 2014, 30(11): 2157-2167.
[8]	QIAO Yin-Po, YIN Hai-Rong, ZHANG Yan-Bin, PAN Yun-Juan, QIAO Lu, LIU Ting. Enhanced Photoluminescence Properties of CaF₂ in CaO-CaF₂-B₂O₃-SiO₂ Glass Doped with Sm₂O₃ [J]. Acta Phys. -Chim. Sin., 2013, 29(09): 2056-2061.
[9]	SONG Hong-Juan, ZHANG Meng-Ying, SUN Xiu-Xin, SUN Shi-Ling QIU Yong-Qing. Nonlinear Optical Properties of a Series of 6,12-Diethynylindeno[1,2-b]fluorene Derivatives [J]. Acta Phys. -Chim. Sin., 2012, 28(12): 2839-2844.
[10]	LI Ying-Ruo, ZHANG Hong-Tao, QI Chuan-Min, GUO Xue-Feng. New Spiropyran Derivatives: Ion Sensing and Information Processing at the Molecular Level [J]. Acta Phys. -Chim. Sin., 2012, 28(10): 2471-2479.
[11]	LIANG Gui-Jie, ZHONG Zhi-Cheng, CHEN Mei-Hua, XU Jie, XU Wei-Lin, HE Ping, HOU Qiu-Fei, LI Zai-Fang. Effect of Donor Moieties on the Electronic Structures and Absorption Spectra of Indoline Dyes [J]. Acta Phys. -Chim. Sin., 2012, 28(08): 1885-1891.
[12]	WANG Guo, WANG Wei-Ning. Experimental and Theoretical Investigations on the Terahertz Vibrational Spectroscopy of Alanine Crystal [J]. Acta Phys. -Chim. Sin., 2012, 28(07): 1579-1585.
[13]	CAO Zhen-Feng, CHEN Qi-Bin, LU Yun-Xiang, LIU Hong-Lai, HU Ying. Electronic Absorption Spectra of Meso-Substituted Porphyrins and Their Zinc Derivatives [J]. Acta Phys. -Chim. Sin., 2012, 28(05): 1085-1093.
[14]	ZHANG Jian-Hua, LIU Qiong, CHEN Yu-Miao, LIU Zhao-Qing, XU Chang-Wei. Determination of Acid Dissociation Constant of Methyl Red by Multi-Peaks Gaussian Fitting Method Based on UV-Visible Absorption Spectrum [J]. Acta Phys. -Chim. Sin., 2012, 28(05): 1030-1036.
[15]	ZHAN Wei-Shen, PAN Shi, WANG Qiao, LI Hong, ZHANG Yi. Comparison of D-SS and D-ST Dyes as Photo Sensitizers in Dye-Sensitized Solar Cells [J]. Acta Phys. -Chim. Sin., 2012, 28(01): 78-84.

Preparation,Isolation and Characterization of Ca@C₈₈ and Ca@C₉₀

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0

Preparation,Isolation and Characterization of Ca@C88 and Ca@C90

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0

Preparation,Isolation and Characterization of Ca@C₈₈ and Ca@C₉₀