NaBaPOM4:Tb3+绿色荧光粉制备及其发光特性

doi:10.3866/PKU.WHXB20101226

Acta Phys. -Chim. Sin. ›› 2010, Vol. 26 ›› Issue (12): 3317-3321.doi: 10.3866/PKU.WHXB20101226

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Preparation and Luminescent Characteristics of the NaBaPOM₄:Tb³⁺ Green Phosphor

WANG Zhi-Jun, YANG Zhi-Ping, GUO Qing-Lin, LI Pan-Lai

College of Physics Science & Technology, Hebei University, Baoding 071002, Hebei Province, P. R China

Received:2010-08-02 Revised:2010-09-20 Published:2010-12-01
Contact: WANG Zhi-Jun, LI Pan-Lai E-mail:lipanlai@sohu.com, wangzhijunmail@yahoo.com.cn
Supported by:
The project was supported by the National Natural Science Foundation of China (50902042), Natural Science Foundation of Hebei Province, China (E2009000209, E2010000283), Research Foundation of Education Bureau of Hebei Province, China (2009313), and Foundation of Key Laboratory of Luminescence and Optical Information, Ministry of Education, China (2010LOI12).

Abstract

Abstract:

We synthesized a kind of green phosphor, NaBaPOM₄:Tb³⁺, by the high temperature solid-state method, and investigated its luminescent characteristics. NaBaPO₄:Tb³⁺ has several emission peaks, and these are located at 437, 490, 543, 587, and 624 nm, which correspond to the ⁵D₃→⁷D₄ and ⁵D₄→⁷F_{J=6. 5, 4, 3} transitions of Tb³⁺, respectively. The main peak is at 543 nm. The excitation spectrum (monitored at an emission wavelength of 543 nm) consists of several bands, and the main peak is located at 380 nm. The effect of amount of Tb³⁺ doping content, the compensators (Li⁺, Na⁺, K⁺, or Cl^-), and the sensitizer activator Ce³⁺ on the emission intensity of the NaBaPOM₄:Tb³⁺ phosphor were also studied. The results show that the emission intensity can be controlled by the above factors, and the intensity can be enhanced by selecting the prime optimum conditions.

Key words: Luminescent characteristics, NaBaPOM₄：Tb³⁺, Green phosphor

WANG Zhi-Jun, YANG Zhi-Ping, GUO Qing-Lin, LI Pan-Lai. Preparation and Luminescent Characteristics of the NaBaPOM₄:Tb³⁺ Green Phosphor[J]. Acta Phys. -Chim. Sin. 2010, 26(12), 3317-3321. doi: 10.3866/PKU.WHXB20101226

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Preparation and Luminescent Characteristics of the NaBaPOM₄:Tb³⁺ Green Phosphor

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Preparation and Luminescent Characteristics of the NaBaPOM₄:Tb³⁺ Green Phosphor