TiO2-MoO3复合纳米管阵列薄膜的制备及其可见光活性

doi:10.3866/PKU.WHXB20110103

Abstract

Abstract:

TiO₂-MoO₃ composite nanotube thin films were obtained by the thermal treatment of titanium dioxide nanotube thin films in the presence of MoO3. Titanium dioxide nanotubes (TiO₂ NTs) thin films were prepared by the anodic oxidation of titanium foil. The resultant thin films were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), electrochemical impedance spectroscopy (EIS), Mott-Schottky analysis, and photoelectrochemical methods. The XRD patterns showed that an anatase type TiO₂ was present in the thin films. Nanotube structures for the thin films were observed by SEM. MoO₃ was dispersed on the TiO₂ NT top surface. Elemental analysis by XPS showed that MoO₃ recombined with the TiO₂ NTs to form TiO₂-MoO₃ composite nanotube thin films. The influence of time and temperature of thermal treatment on the photoelectrochemical response for the TiO₂-MoO₃ composite nanotube thin film electrodes were investigated. The photoelectrochemical response of the TiO₂-MoO₃ composite nanotube thin film increased under visible light illumination compared with the pristine TiO₂ NTs. The highest photoelectrochemical response was observed for the TiO₂-MoO₃ composite nanotube thin film obtained by thermal treatment at 450 °C for 60 min.

Key words: TiO₂ nanotubes, MoO₃, Thermal treatment, Photoelectrochemical property

LUO Ying, CUI Xiao-Li, XIE Jing-Ying. Preparation and Visible Light Photoelectrochemical Response of TiO₂-MoO₃ Composite Nanotube Thin Films[J]. Acta Phys. -Chim. Sin. 2011, 27(01), 135-142. doi: 10.3866/PKU.WHXB20110103

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Preparation and Visible Light Photoelectrochemical Response of TiO₂-MoO₃ Composite Nanotube Thin Films

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Preparation and Visible Light Photoelectrochemical Response of TiO₂-MoO₃ Composite Nanotube Thin Films