乙二胺导向合成的微孔晶体磷酸钴的转化现象

doi:10.3866/PKU.WHXB201302273

Abstract

Abstract:

Microporous cobalt phosphate structures can be synthesized using ethylenediamine as a structure directing agent. During the syntheses of CoPO-en-1, CoPO-en-2, CoPO-en-3, and CoPO-en-4, it was found that they could interconvert during hydrothermal or calcination conditions. CoPO-en-2 and CoPO-en-4 are the crystallization intermediates of CoPO-en-1 and CoPO-en-3, respectively. During hydrothermal synthesis, CoPO-en-2 and CoPO-en-4 could be obtained at lower temperature or higher temperature during the initial crystallization stage. Extended synthesis time at higher temperature the two former structures transform into the two latter. CoPO-en-2, CoPO-en-3, and CoPO-en-4 could also convert to CoPO-en-1 during calcination, and these transformations indicated the sequence of structure stability. During synthesis under hydrothermal conditions, CoPO-en-2, CoPO-en-3, and CoPO-en-4 could convert to CoPO-en-1. During muffle furnace roasting, CoPO-en-2, CoPO-en-3, and CoPO-en-4 could also convert to CoPO-en-1. Different structures in the liquid or solid phases could be transformed into the same structure using different approaches.

Key words: Cobalt phosphate, Ethylenediamine, Structural transformation, Hydrothermal synthesis, Calcination transformation

LUO Qian-Qian, ZHOU Shi-Dong, REN Yuan, Li Niu, HUANG Zhi-Peng, GUAN Nai-Jia, XIANG Shou-He. Phenomenon of Structural Transformation of Ethylenediamine- Oriented Synthesis of Microporous Cobalt Phosphate[J]. Acta Phys. -Chim. Sin. 2013, 29(05), 911-919. doi: 10.3866/PKU.WHXB201302273

References

(1) Pang, H.; Liu, Y.; Li, J.; Ma, Y.; Li, G.; Ai, Y.; Chen, J.; Zhang,J.; Zheng, H. Nanoscale 2013, 5, 503. doi: 10.1039/c2nr32597g
(2) Wang, F.; Yang, J.; Li, Y.;Wang, J. J. Power Sources 2011, 196,4806. doi: 10.1016/j.jpowsour.2011.01.055
(3) Nakayama, M.; Goto, S.; Uchimoto, Y.;Wakihara, M.;Kitajima, Y. Chem. Mater. 2004, 16, 3399. doi: 10.1021/cm049230t
(4) Tran-Vana, P.; Bartheleta, K.; Morcretteb, M.; Herlema, M.;Tarasconb, J.; Cheetham, A. K.; Férey, G. J. New Mater.Electrochem. Syst. 2003, 6, 29.
(5) Murugavel, R.; Choudhury, A.; Rao, C. C. N. R. Chem. Rev.2008, 108, 3549. doi: 10.1021/cr000119q
(6) Hogarth, C. A.; Basha, M. J. J. Phys. D: Appl. Phys. 1983, 16 (5), 869. doi: 10.1088/0022-3727/16/5/018
(7) Lee,W. H.; Seo, Y.; Bishop, P. L. Sensors and Actuators B:Chemical 2009, 137, 121. doi: 10.1016/j.snb.2008.10.032
(8) Kanan, M.W.; Surendranath, Y.; Nocera, D. G. Chem. Soc. Rev.2009, 38, 109. doi: 10.1039/b802885k
(9) Tsuhako, M.; Ikeuchi, S.; Matsuo, T.; Motooka, I.; Kobayashi,M. Bull. Chem. Soc. Jpn. 1979, 52, 1034. doi: 10.1246/bcsj.52.1034
(10) Onoda, H.; Nariai, H.; Maki, H.; Motooka, I. Mater. Chem.Phys. 2002, 73 (1), 19. doi: 10.1016/S0254-0584(01)00341-8
(11) Onoda, H.; Nariai, H.; Moriwaki, A.; Maki, H.; Motooka, I.J. Mater. Chem. 2002, 12 (6) 1754. doi: 10.1039/b110121h
(12) Onoda, H.; Takenaka, A.; Kojima, K.; Nariai, H. Mater. Chem.Phys. 2003, 82 (1), 194. doi: 10.1016/S0254-0584(03)00205-0
(13) Onoda, H.; Sugino, N.; Kojima, K.; Nariai, H. Mater. Chem.Phys. 2003, 82 (3), 831. doi: 10.1016/j.matchemphys.2003.07.006
(14) Takenaka, A.; Endo, T.; Onoda, H. Phosphorus Res. Bull. 2003,16, 33.
(15) Averbuch-Pouchat, M.T.; Durif, A. Topics in PhosphateChemistry;World Scientific Publishing Co. Pte. Ltd.:Singapore, 1996.
(16) Vogt, E. T. C.; Ricardson, J.W., Jr. J. Solid State Chem. 1990,87, 469. doi: 10.1016/0022-4596(90)90052-Y
(17) Oliver, S.; Kuperman, A.; Ozin, G. A. Angew. Chem. Int. Edit.1998, 37, 46.
(18) Le, S.; Navrotsky, A. J. Solid State Chem. 2008, 181, 20. doi: 10.1016/j.jssc.2007.10.017
(19) Chen, J.; Jones, R. H.; Natarajan, S.; Hursthouse, M. B.;Thomas, J. M. Angew. Chem. Int. Edit. 1994, 33, 639.
(20) Lu, A.; Li, N.; Ma, Y.; Song, H.; Li, D.; Guan, N.;Wang, H.;Xiang, S. Cryst. Growth Des. 2008, 8, 2377. doi: 10.1021/cg701231d
(21) Natarajan, S.; Neeraj, S.; Choudhury, A.; Rao, C. N. R. Inorg.Chem. 2000, 39, 1426. doi: 10.1021/ic991223x
(22) Chang,W.;Wur, C.;Wang, S.; Chiang, R. Inorg. Chem. 2006,45, 6622. doi: 10.1021/ic051634f
(23) Xu, R.; Pang,W.; Yu, J.; Huo, Q.; Chen, J. Chemistry of Zeolitesand Related Porous Materials: Synthesis and Structure; JohnWiley & Sons (Asia) Pte. Ltd.: Singupore, 2007; p 207.
(24) Yuan, H.; Chen, J.; Zhu, G.; Li, J.; Yu, J.; Yang, G.; Xu, R.Inorg. Chem. 2000, 39, 1476. doi: 10.1021/ic990719b

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Phenomenon of Structural Transformation of Ethylenediamine- Oriented Synthesis of Microporous Cobalt Phosphate

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