固态Photo-CIDNP效应

doi:10.3866/PKU.WHXB201511272

Acta Phys. -Chim. Sin. ›› 2016, Vol. 32 ›› Issue (2): 399-404.doi: 10.3866/PKU.WHXB201511272

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The Solid-State Photo-CIDNP Effect

Xiao-Jie WANG^1,*(),Smitha Surendran THAMARATH^2,³,A. ALIA^2,^3,⁴,E. BODE Bela⁵,Jörg MATYSIK^2,^3,*()

¹ Department of Chemistry and Biology, College of Science, National University of Defense Technology, Changsha 410073, P. R. China
² Institut für Analytische Chemie, Universität Leipzig, Linnéstr. 3, 04103 Leipzig, Gemany
³ Leiden Institute of Chemistry, Einsteinweg 55, 2300 RA Leiden, The Netherlands
⁴ Institute of Medical Physics and Biophysics, University of Leipzig, D-04107 Leipzig, Germany
⁵ EaStCHEM School of Chemistry and Biomedical Sciences Research Complex, University of St Andrews, St Andrews, KY16 9ST, Scotland

Received:2015-09-21 Published:2016-01-30
Contact: Xiao-Jie WANG,Jörg MATYSIK E-mail:yj605@126.com;joerg.matysik@uni-leipzig.de
Supported by:
the Netherlands Organization for Scientific Research (NWO)(713.012.001)

Abstract

Abstract:

Photochemically induced dynamic nuclear polarization (photo-CIDNP) is an effect that produces non-Boltzmann nuclear spin polarization, which can be observed as a modification of signal intensity in nuclear magnetic resonance (NMR) spectroscopy. The effect is well known in liquid-state NMR, where it is explained most generally by the classical radical pair mechanism (RPM). In the solid-state, additional mechanisms are operative in the spin-dynamics of radical pairs, such as three-spin mixing (TSM), differential decay (DD) and differential relaxation (DR). The observed solid-state photo-CIDNP effect is strongly magnetic field dependent, and this field-dependence is well distinguished for the various nuclei. Here, we provide an account of the phenomenology, theory and properties of the magnetic field dependence of the solid-state photo-CIDNP effect.

Key words: Photo-CIDNP, Magic angle spinning, Nuclear magnetic resonance, Radical pair, Spin chemistry

Xiao-Jie WANG,Smitha Surendran THAMARATH,A. ALIA,E. BODE Bela,Jörg MATYSIK. The Solid-State Photo-CIDNP Effect[J]. Acta Phys. -Chim. Sin. 2016, 32(2), 399-404. doi: 10.3866/PKU.WHXB201511272

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The Solid-State Photo-CIDNP Effect

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