覆银聚酰亚胺纳米棒阵列的制备及其SERS特性

doi:10.3866/PKU.WHXB201601294

Abstract

Abstract:

An Ag-coated polyimide (PI) nanorod array was prepared by sputtering Ag film on a PI nanorod array fabricated using oxygen plasma etching. The method is a facile way to fabricate a surface-enhanced Raman scattering (SERS) substrate with high sensitivity and a tunable structure. The diameter and density of the Agcoated nanorods and the gap between them could be tuned by changing the oxygen plasma etching time and Ag film thickness. Nile Blue (NB) was used as a probe molecule to investigate the SERS enhancement of this Ag nanostructure. The SERS peak intensity varied with the plasma etching time and Ag film thickness. The largest sensitivity was obtained with 30 s of oxygen plasma etching and 70 nm of sputtering Ag film. The SERS substrate also exhibited excellent signal reproducibility.

Key words: Nanorod array, Surface-enhanced Raman scattering, Plasma etching, Field-enhancement factor

Xiang-Xiang FAN,Xiu-Li HE,Jian-Ping LI,Xiao-Guang GAO,Jian JIA,Zhi-Mei QI. Fabrication and Surface-Enhanced Raman Scattering Properties of an Ag-Coated Polyimide Nanorod Array[J]. Acta Phys. -Chim. Sin. 2016, 32(4), 1036-1042. doi: 10.3866/PKU.WHXB201601294

References

1	Alvarez-Puebla R. A. ; Agarwal A. ; Manna P. ; Khanal B. P. ; Aldeanueva-Potel P. ; Carbó-Argibay E. ; Pazos-Pérez N. ; Vigderman L. ; Zubarev E. R. ; Kotov N. A. ; Liz-Marzán L. M. Proc. Natl. Acad. Sci. U. S. A 2011, 108, 8157.
2	Zong S. F. ; Wang Z. Y. ; Yang J. ; Wang C. L. ; Xu S. H. ; Cui Y. P. Talanta 2012, 97, 368.
3	Ko H. ; Tsukruk V. V. Small 2008, 4 (1980)
4	He D. ; Hu B. ; Yao Q. F. ; Wang K. ; Yu S. H. ACS Nano 2009, 3, 3993.
5	Zhang X. L. ; Zhang J. ; Ren W. J. ; Lai C. H. ; Zhou H. J. Spectrosc. Spec. Anal 2015, 35, 1567.
5	张晓雷; 张洁; 任文杰; 赖春红; 周海军. 光谱学与光谱分析, 2015, 35, 1567.
6	Lu G. ; Li H. ; Liusman C. ; Yin Z. Y. ; Wu S. X. ; Zhang H. Chem. Sci 2011, 2, 1817.
7	Pincella F. ; Song Y. ; Ochiai T. ; Isozaki K. ; Sakamoto K. ; Miki K. Chem. Phys. Lett 2014, 605
8	Tian C. ; Ding C. ; Liu S. ; Yang S. ; Song X. ; Ding B. ; Li Z. ; Fang J. ACS Nano 2011, 5 (9442)
9	Long K. L. ; Du D. Y. ; Luo X. G. ; Zhao W.W. ; Wu Z. T. ; Si L. F. ; Qiu T. Appl. Surf. Sci 2014, 311, 666.
10	Xia Y. Y. ; Wang J. M. Mater. Chem. Phys 2011, 125, 267.
11	Wang J. ; Huang L. Q. ; Zhai L. P. ; Yuan L. ; Zhao L. H. ; Zhang W.W. ; Shan D. Z. ; Hao A.W. ; Feng X. H. ; Zhu J. Appl. Surf. Sci 2012, 261, 605.
12	Zhu Y. Q. ; Li M. Q. ; Yu D. Y. ; Yang L. B. Talanta 2014, 128, 117.
13	Wang J. P. ; Yang L. ; Liu B. H. ; Jiang H. H. ; Liu R. Y. ; Yang J.W. ; Han G. M. ; Mei Q. S. ; Zhang Z. P. Anal. Chem 2014, 86, 3338.
14	Ngo Y. H. ; Then W. L. ; Shen W. ; Garnier G. J. Colloid Interface Sci 2013, 409, 59.
15	Zhang W.Y. ; Xiao X. Z. ; Lv C. ; Zhao J. ; Wang G. ; Gu X. ; Zhang R. ; Xu B. B. ; Zhang D. D. ; Zhang Y. L. ; Sun H. B. Macromol. Res 2013, 21, 306.
16	Fathima S. J. H. ; Paul J. ; Valiyaveettil S. Small 2010, 6, 2443.
17	Zhu H. ; Du M. L. ; Zhang M. ; Wang P. ; Bao S. Y. ; Zou M. L. ; Fu Y. Q. ; Yao J. M. Biosens. Bioelectron 2014, 54, 91.
18	Tan Y.W. ; Zang X. N. ; Gu J. J. ; Liu D. X. ; Zhu S. M. ; Su H. L. ; Feng C. L. ; Liu Q. L. ; Lau W. M. ; Moon W. J. ; Zhang D. Langmuir 2011, 27, 11742.
19	Hatab N. A. A. ; Oran J. M. ; Sepaniak M. J. ACS Nano 2008, 2, 377.
20	Chen J. H. ; Li Y. Y. ; Huang K. ; Wang P. X. ; He L. L. ; Carter K. R. ; Nugen S. R. ACS Appl. Mater. Interfaces 2015, 7, 22106.
21	Li Z. B. ; Meng G.W. ; Huang Q. ; Hu X. Y. ; He X. ; Tang H. B. ; Wang Z.W. ; Li F. D. Small 2015, 11 (5452)
22	Kang G. ; Matikainen A. ; Stenberg P. ; Färm E. ; Li P. ; Ritala M. ; Vahimaa P. ; Honkanen S. ; Tan X. ACS Appl. Mater. Interfaces 2015, 7, 11453.
23	Maznichenko D. ; Venkatakrishnan K. ; Tan B. J. Phys. Chem. C 2013, 117, 578.
24	McKee K. J. ; Meyer M.W. ; Smith E. A. Anal. Chem 2012, 84, 4300.
25	Wohlfart E. ; Fernández-Blázquez J. P. ; Knoche E. ; Bello A. ; Pérez E. ; Arzt E. ; Campo A. Macromolecules 2010, 43, 9908.
26	Liu D. L. ; Zhao Q. ; Lu D. F. ; Qi Z. M. Chem. J. Chin. Univ 2014, 35, 2207.
26	刘德龙; 赵乔; 逯丹凤; 祁志美. 高等学校化学学报, 2014, 35, 2207.
27	Zhao H. ; Fu H. G. ; Tian C. G. ; Ren Z. Y. ; Yuan M. M. Chem. J. Chin. Univ 2011, 32, 2387.
27	赵红; 付宏刚; 田春贵; 任志宇; 袁明明. 高等学校化学学报, 2011, 32, 2387.

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Fabrication and Surface-Enhanced Raman Scattering Properties of an Ag-Coated Polyimide Nanorod Array

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