黑色微弧氧化膜的制备及其表征

doi:10.3866/PKU.WHXB201606071

Abstract

Abstract:

Black micro-arc oxide film layers were prepared on AZ40M magnesium alloy substrates by twostep micro-arc oxidation in a phosphate electrolyte with ferric citrate. The morphologies and compositions of these films were characterized by scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) to provide details regarding the film formation mechanism. The results showed that the main component of the oxide films was magnesium oxide, with various iron compounds also being present, including ferroferric oxide, ferrous oxide, and metallic iron. These results indicate that the formation of black film can be attributed to the precipitation of these species during the oxidation of iron ions by ferric citrate in the electrolyte.

Key words: Micro-arc oxidation, Phosphate, Magnesium alloy, Formation mechanism, Black oxidation film

Jing-Ying BAI,Si-Zhen LI,Da-Jiang ZHENG,Li-Gong ZHANG,Li FENG,Qing-Xin CUI,Jing-Run WANG,Wen-Wu JIANG,Chang-Jian LIN. Preparation and Characterization of Black Micro-Arc Oxidation Films[J]. Acta Phys. -Chim. Sin. 2016, 32(9), 2271-2279. doi: 10.3866/PKU.WHXB201606071

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Preparation and Characterization of Black Micro-Arc Oxidation Films

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