硅纳米结构阵列：光热CO2催化的新兴平台

doi:10.3866/PKU.WHXB202304004

Abstract

Abstract:

Rapid population growth and the demand for energy, which is powered by unrestricted fossil fuel exploitation, have caused severe environmental problems. Thus, it is crucial to effectively exploit alternative clean energy sources. Solar energy, which is a sustainable renewable energy source, provides an effective strategy for mitigating the energy crisis and greenhouse effect without resulting in additional carbon emissions. The concept of converting carbon dioxide (CO₂) into synthetic fuels is a promising solution towards realizing a sustainable carbon-neutral economy. Photocatalysis is a favorable approach for CO₂ conversion, but it has limitations in terms of conversion rates, efficiency, and scalability. Therefore, the novel concept of photothermal catalysis has been proposed based on the photothermal effect of catalysts, which allows for the complete exploitation of the solar spectrum, especially infrared light that is typically wasted during photochemical catalysis. Photothermal catalysis, combining photochemical and photothermal effects, can effectively catalyze chemical reactions under mild conditions. Although various metal structures can serve as the light-absorbing and active centers for photothermal catalysis, they suffer from disadvantages such as insufficient light utilization, high cost, and poor stability. Recently, naturally abundant silicon has emerged as a prospective photothermal catalyst, especially silicon nanostructure arrays, which outperform other conventional silicon materials owing to their excellent light-harvesting ability and efficient catalytic performance. Compared with conventional photothermal catalysts, silicon nanostructure arrays have demonstrated unique catalytic performance advantages in the photothermal CO₂ reduction reaction. As a platform, silicon nanostructure arrays exhibit an excellent light-harvesting ability, high specific surface area, and versatile hybridization possibilities. This review discusses the fundamental concepts and principles related to the theory and applications of photothermal catalytic CO₂ conversion, the functionalities of silicon nanostructure arrays in conventional photothermal CO₂ catalytic reduction, and the recent developments in photothermal CO₂ catalysis using silicon nanostructure arrays. Ultimately, it provides a guide for the development direction of high-performance nanostructure arrays-based photothermal CO₂ catalysts.

Key words: Photothermal catalysis, Silicon nanostructure arrays, CO₂ conversion, Solar fuels

Chengcheng Zhang, Zhiyi Wu, Jiahui Shen, Le He, Wei Sun. Silicon Nanostructure Arrays: An Emerging Platform for Photothermal CO₂ Catalysis[J]. Acta Phys. -Chim. Sin. 2024, 40(1), 2304004. doi: 10.3866/PKU.WHXB202304004

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References 127

1	Jiao F. ; Li J. ; Pan X. ; Xiao J. ; Li H. ; Ma H. ; Wei M. ; Pan Y. ; Zhou Z. ; Li M. ; et al Science 2016, 351, 1065. doi: 10.1126/science.aaf1835
2	Wang J. ; Kattel S. ; Hawxhurst C. J. ; Lee J. H. ; Tackett B. M. ; Chang K. ; Rui N. ; Liu C. ; Chen J. G. Angew. Chem. Int. Ed. 2019, 58, 6271. doi: 10.1002/anie.201900781
3	Yuan L. ; Hung S. ; Tang Z. ; Chen H. ; Xiong Y. ; Xu Y. ACS Catal. 2019, 9, 4824. doi: 10.1021/acscatal.9b00862
4	Kondratenko E. V. ; Mul G. ; Baltrusaitis J. ; Larrazábal G. O. ; Pérez-Ramírez J. Energy Environ. Sci. 2013, 6, 3112. doi: 10.1039/C3EE41272E
5	Wang Z. ; Song H. ; Liu H. ; Ye J. Angew. Chem. Int. Ed. 2020, 59, 8016. doi: 10.1002/anie.201907443
6	Shih C. F. ; Zhang T. ; Li J. ; Bai C. Joule 2018, 2, 1925. doi: 10.1016/j.joule.2018.08.016
7	Ding M. ; Flaig R. W. ; Jiang H. ; Yaghi O. M. Chem. Soc. Rev. 2019, 48, 2783. doi: 10.1039/C8CS00829A
8	Jiang C. ; Moniz S. J. A. ; Wang A. ; Zhang T. ; Tang J. Chem. Soc. Rev. 2017, 46, 4645. doi: 10.1039/c6cs00306k
9	Li X. ; Yu J. ; Jaroniec M. ; Chen X. Chem. Rev. 2019, 119, 3962. doi: 10.1021/acs.chemrev.8b00400
10	Han C. ; Li Y. ; Li J. ; Qi M. ; Tang Z. ; Xu Y. Angew. Chem. Int. Ed. 2021, 60, 7962. doi: 10.1002/anie.202015756
11	Li J. ; Yuan L. ; Li S. ; Tang Z. ; Xu Y. J. Mater. Chem. A 2019, 7, 8676. doi: 10.1039/C8TA12427B
12	Fujishima A. ; Honda K. Nature 1972, 238, 37. doi: 10.1038/238037a0
13	Tu W. ; Zhou Y. ; Zou Z. Adv. Mater. 2014, 26, 4607. doi: 10.1002/adma.201400087
14	Ni G. ; Li G. ; Boriskina S. ; Li H. ; Yang W. ; Zhang T. ; Chen G. Nat. Energy 2016, 1, 16126. doi: 10.1038/nenergy.2016.126
15	Elimelech M. ; Phillip W. A. Science 2011, 333, 712. doi: 10.1126/science.1200488
16	Quan Q. ; Xie S. J. ; Wang Y. ; Xu Y. J. Acta Phys. -Chim. Sin. 2017, 33, 2404.
	全泉; 谢顺吉; 王野; 徐艺军; 物理化学学报, 2017, 33, 2404. doi: 10.3866/PKU.WHXB201706263
17	Yuan L. ; Xu Y. Appl. Surf. Sci. 2015, 342, 154. doi: 10.1016/j.apsusc.2015.03.050
18	Meng X. ; Liu L. ; Ouyang S. ; Xu H. ; Wang D. ; Zhao N. ; Ye J. Adv. Mater. 2016, 28, 6781. doi: 10.1002/adma.201600305
19	Buzzetti L. ; Crisenza G. E. M. ; Melchiorre P. Angew. Chem. Int. Ed. 2019, 58, 3730. doi: 10.1002/anie.201809984
20	Tong H. ; Ouyang S. ; Bi Y. ; Umezawa N. ; Oshikiri M. ; Ye J. Adv. Mater. 2012, 24, 229. doi: 10.1002/adma.201102752
21	Ghoussoub M. ; Xia M. ; Duchesne P. N. ; Segal D. ; Ozin G. Energy Environ. Sci. 2019, 12, 1122. doi: 10.1039/C8EE02790K
22	Zhu L. ; Gao M. ; Peh C. K. N. ; Ho G. W. Mater. Horiz. 2018, 5, 323. doi: 10.1039/C7MH01064H
23	Chu S. ; Majumdar A. Nature 2012, 488, 294. doi: 10.1038/nature11475
24	Hong J. ; Xu C. ; Deng B. ; Gao Y. ; Zhu X. ; Zhang X. ; Zhang Y. Adv. Sci. 2022, 9, 2103926. doi: 10.1002/advs.202103926
25	Mateo D. ; Cerrillo J. L. ; Durini S. ; Gascon J. Chem. Soc. Rev. 2020, 50, 2173. doi: 10.1039/d0cs00357c
26	Kho E. T. ; Tan T. H. ; Lovell E. ; Wong R. J. ; Scott J. ; Amal R. Green Energy Environ. 2017, 2, 204. doi: 10.1016/j.gee.2017.06.003
27	Fang S. ; Hu Y. Chem. Soc. Rev. 2022, 51, 3609. doi: 10.1039/D1CS00782C
28	He L. ; Wood T. E. ; Wu B. ; Dong Y. ; Hoch L. B. ; Reyes L. M. ; Wang D. ; Kubel C. ; Qian C. ; Jia J. ; et al ACS Nano 2016, 10, 5578. doi: 10.1021/acsnano.6b02346
29	Zhou J. ; Liu H. ; Wang H. Chin. Chem. Lett. 2023, 34, 107420. doi: 10.1016/j.cclet.2022.04.018
30	Tou M. ; Michalsky R. ; Steinfeld A. Joule 2017, 1, 146. doi: 10.1016/j.joule.2017.07.015
31	Qian C. ; Sun W. ; Hung D. L. H. ; Qiu C. ; Makaremi M. ; Hari Kumar S. G. ; Wan L. ; Ghoussoub M. ; Wood T. E. ; Xia M. ; et al Nat. Catal. 2019, 2, 46. doi: 10.1038/s41929-018-0199-x
32	Lv C. ; Bai X. ; Ning S. ; Song C. ; Guan Q. ; Liu B. ; Li Y. ; Ye J. ACS Nano 2023, 17, 1725. doi: 10.1021/acsnano.2c09025
33	Meng X. ; Wang T. ; Liu L. ; Ouyang S. ; Li P. ; Hu H. ; Kako T. ; Iwai H. ; Tanaka A. ; Ye J. Angew. Chem. Int. Ed. 2014, 53, 11478. doi: 10.1002/anie.201404953
34	Michalsky R. ; Pfromm P. H. ; Steinfeld A. Interface Focus 2015, 5, 20140084. doi: 10.1098/rsfs.2014.0084
35	Heidlage M. G. ; Kezar E. A. ; Snow K. C. ; Pfromrn P. H. Ind. Eng. Chem. Res. 2017, 56, 14014. doi: 10.1021/acs.iecr.7b03173
36	Agrafiotis C. ; von Storch H. ; Roeb M. ; Sattler C. Renew. Sust. Energ. Rev. 2014, 29, 656. doi: 10.1016/j.rser.2013.08.050
37	Gokon N. ; Yamawaki Y. ; Nakazawa D. ; Kodama T. Int. J. Hydrog. Energy 2010, 35, 7441. doi: 10.1016/j.ijhydene.2010.04.040
38	Han K. ; Wang Y. ; Wang S. ; Liu Q. ; Deng Z. ; Wang F. Chem. Eng. J. 2021, 421, 129989. doi: 10.1016/j.cej.2021.129989
39	Zhao J. ; Guo X. ; Shi R. ; Waterhouse G. I. N. ; Zhang X. ; Dai Q. ; Zhang T. Adv. Funct. Mater. 2022, 32, 2204056. doi: 10.1002/adfm.202204056
40	Jia J. ; Wang H. ; Lu Z. ; O'Brien P. G. ; Ghoussoub M. ; Duchesne P. ; Zheng Z. ; Li P. ; Qiao Q. ; Wang L. ; et al Adv. Sci. 2017, 4, 1700252. doi: 10.1002/advs.201700252
41	Liu X. ; Xing C. ; Yang F. ; Liu Z. ; Wang Y. ; Dong T. ; Zhao L. ; Liu H. ; Zhou W. Adv. Energy Mater. 2022, 12, 2201009. doi: 10.1002/aenm.202201009
42	Li Z. ; Shi R. ; Zhao J. ; Zhang T. Nano Res. 2021, 14, 4828. doi: 10.1007/s12274-021-3436-6
43	Hao Q. ; Li Z. ; Shi Y. ; Li R. ; Li Y. ; Ouyang S. ; Yuan H. ; Zhang T. Nano Energy 2022, 102, 107723. doi: 10.1016/j.nanoen.2022.107723
44	Shah A. ; Torres P. ; Tscharner R. ; Wyrsch N. ; Keppner H. Science 1999, 285, 692. doi: 10.1126/science.285.5428.692
45	Ballif C. ; Haug F. J. ; Boccard M. ; Verlinden P. J. ; Hahn G. Nat. Rev. Mater. 2022, 7, 597. doi: 10.1038/s41578-022-00423-2
46	Grätzel M. Nature 2001, 414, 338. doi: 10.1038/35104607
47	Zhang D. ; Cai H. ; Su Y. ; Sun W. ; Yang D. ; Ozin G. A. Chem. Catal. 2022, 2, 1893. doi: 10.1016/j.checat.2022.06.001
48	Hou Y. ; Abrams B. L. ; Vesborg P. C. ; Bjorketun M. E. ; Herbst K. ; Bech L. ; Setti A. M. ; Damsgaard C. D. ; Pedersen T. ; Hansen O. ; et al Nat. Mater. 2011, 10, 434. doi: 10.1038/nmat3008
49	Yang J. ; Walczak K. ; Anzenberg E. ; Toma F. M. ; Yuan G. ; Beeman J. ; Schwartzberg A. ; Lin Y. ; Hettick M. ; Javey A. ; et al J. Am. Chem. Soc. 2014, 136, 6191. doi: 10.1021/ja501513t
50	Ali M. ; Zhou F. ; Chen K. ; Kotzur C. ; Xiao C. ; Bourgeois L. ; Zhang X. ; MacFarlane D. R. Nat. Commun. 2016, 7, 11335. doi: 10.1038/ncomms11335
51	Shao M. ; Cheng L. ; Zhang X. ; Ma D. ; Lee S. J. Am. Chem. Soc. 2009, 131, 17738. doi: 10.1021/ja908085c
52	Wang S. ; Zhang D. ; Wang W. ; Zhong J. ; Feng K. ; Wu Z. ; Du B. ; He J. ; Li Z. ; He L. ; et al Nat. Commun. 2022, 13, 5305. doi: 10.1038/s41467-022-33029-x
53	Wang Z. ; Wang J. ; Zhang J. ; Dai K. Acta Phys. -Chim. Sin. 2023, 39, 2209037.
	王中辽; 汪静; 张金锋; 代凯; 物理化学学报, 2023, 39, 2209037. doi: 10.3866/PKU.WHXB202209037
54	Tian L. ; Xin Q. ; Zhao C. ; Xie G. ; Akram M. Z. ; Wang W. ; Ma R. ; Jia X. ; Guo B. ; Gong J. R. Small 2021, 17, 2006530. doi: 10.1002/smll.202006530
55	Liu D. ; Ma J. ; Long R. ; Gao C. ; Xiong Y. Nano Today 2017, 17, 96. doi: 10.1016/j.nantod.2017.10.013
56	Peng K. ; Huang Z. ; Zhu J. Adv. Mater. 2004, 16, 73. doi: 10.1002/adma.200306185
57	Lee S. ; Kim D. ; Lee G. ; Kim G. ; Kwak M. ; Fan R. Biosens. Bioelectron. 2014, 54, 181. doi: 10.1016/j.bios.2013.10.048
58	Seol M. ; Ahn J. ; Choi J. ; Choi S. ; Choi Y. Nano Lett. 2012, 12, 5603. doi: 10.1021/nl3026955
59	Peng K. ; Lee S. Adv. Mater. 2011, 23, 198. doi: 10.1002/adma.201002410
60	Fan G. ; Zhu H. ; Wang K. ; Wei J. ; Li X. ; Shu Q. ; Guo N. ; Wu D. ACS Appl. Mater. Interfaces 2011, 3, 721. doi: 10.1021/am1010354
61	Tsormpatzoglou A. ; Tassis D. ; Dimitriadis C. ; Dózsa L. ; Galkin N. ; Goroshko D. ; Polyarnyi V. ; Chusovitin E. J. Appl. Phys. 2006, 100, 074313. doi: 10.1063/1.2357642
62	Du S. ; Bian X. ; Zhao Y. ; Shi R. ; Zhang T. Chem. Res. Chin. Univ. 2022, 38, 723. doi: 10.1007/s40242-022-2039-4
63	Zhao Y. ; Gao W. ; Li S. ; Williams G. R. ; Mahadi A. H. ; Ma D. Joule 2019, 3, 920. doi: 10.1016/j.joule.2019.03.003
64	Li Y. ; Li R. ; Li Z. ; Xu Y. ; Yuan H. ; Ouyang S. ; Zhang T. Solar RRL 2022, 6, 2200493. doi: 10.1002/solr.202200493
65	Feng N. ; Lin H. ; Song H. ; Yang L. ; Tang D. ; Deng F. ; Ye J. Nat. Commun. 2021, 12, 4652. doi: 10.1038/s41467-021-24912-0
66	Li S. ; Qi M. ; Fan Y. ; Yang Y. ; Anpo M. ; Yamada Y. M. A. ; Tang Z. ; Xu Y. Appl. Catal. B-Environ. 2021, 292, 120157. doi: 10.1016/j.apcatb.2021.120157
67	Lu K. ; Li Y. ; Zhang F. ; Qi M. ; Chen X. ; Tang Z. ; Yamada Y. M. A. ; Anpo M. ; Conte M. ; Xu Y. Nat. Commun. 2020, 11, 5181. doi: 10.1038/s41467-020-18944-1
68	Tong Y. ; Song L. ; Ning S. ; Ouyang S. ; Ye J. Appl. Catal. B- Environ. 2021, 298, 120551. doi: 10.1016/j.apcatb.2021.120551
69	Gao M. ; Zhang T. ; Ho G. W. Nano Res. 2022, 15, 9985. doi: 10.1007/s12274-022-4795-3
70	Mateo D. ; Cerrillo J. L. ; Durini S. ; Gascon J. Chem. Soc. Rev. 2021, 50, 2173. doi: 10.1039/d0cs00357c
71	Song C. ; Wang Z. ; Yin Z. ; Xiao D. ; Ma D. Chem. Catal. 2022, 2, 52. doi: 10.1016/j.checat.2021.10.005
72	Zhang F. ; Li Y. ; Qi M. ; Yamada Y. M. A. ; Anpo M. ; Tang Z. ; Xu Y. Chem Catal. 2021, 1, 272. doi: 10.1016/j.checat.2021.01.003
73	Iglesias Juez A. ; Coronado J. M. Chem 2018, 4, 1490. doi: 10.1016/j.chempr.2018.06.015
74	Wang S. ; Tountas A. A. ; Pan W. ; Zhao J. ; He L. ; Sun W. ; Yang D. ; Ozin G. A. Small 2021, 17, 2007025. doi: 10.1002/smll.202007025
75	Wu Z. ; Li C. ; Li Z. ; Feng K. ; Cai M. ; Zhang D. ; Wang S. ; Chu M. ; Zhang C. ; Shen J. ; et al ACS Nano 2021, 15, 5696. doi: 10.1021/acsnano.1c00990
76	Cai M. ; Wu Z. ; Li Z. ; Wang L. ; Sun W. ; Tountas A. A. ; Li C. ; Wang S. ; Feng K. ; Xu A. ; et al Nat. Energy 2021, 6, 807. doi: 10.1038/s41560-021-00867-w
77	Ning S. ; Sun Y. ; Ouyang S. ; Qi Y. ; Ye J. Appl. Catal. B-Environ. 2022, 310, 121063. doi: 10.1016/j.apcatb.2022.121063
78	Mao C. ; Li H. ; Gu H. ; Wang J. ; Zou Y. ; Qi G. ; Xu J. ; Deng F. ; Shen W. ; Li J. ; et al Chem 2019, 5, 2702. doi: 10.1016/j.chempr.2019.07.021
79	Li Y. ; Guan Q. ; Huang G. ; Yuan D. ; Xie F. ; Li K. ; Zhang Z. ; San X. ; Ye J. Adv. Energy Mater. 2022, 12, 2202459. doi: 10.1002/aenm.202202459
80	Zhou S. ; Shang L. ; Zhao Y. ; Shi R. ; Waterhouse G. I. N. ; Huang Y. ; Zheng L. ; Zhang T. Adv. Mater. 2019, 31, 1900509. doi: 10.1002/adma.201900509
81	Wu D. ; Deng K. ; Hu B. ; Lu Q. ; Liu G. ; Hong X. ChemCatChem 2019, 11, 1598. doi: 10.1002/cctc.201802081
82	Ge H. ; Kuwahara Y. ; Kusu K. ; Bian Z. F. ; Yamashita H. Appl. Catal. B-Environ. 2022, 317, 121734. doi: 10.1016/j.apcatb.2022.121734
83	Wei W. ; Wei Z. ; Li R. ; Li Z. ; Shi R. ; Ouyang S. ; Qi Y. ; Philips D. L. ; Yuan H. Nat. Commun. 2022, 13, 3199. doi: 10.1038/s41467-022-30958-5
84	Qi Y. ; Song L. ; Ouyang S. ; Liang X. ; Ning S. ; Zhang Q. ; Ye J. Adv. Mater. 2020, 32, 1903915. doi: 10.1002/adma.201903915
85	Wang L. ; Dong Y. ; Yan T. ; Hu Z. ; Jelle A. A. ; Meira D. M. ; Duchesne P. N. ; Loh J. Y. Y. ; Qiu C. ; Storey E. E. ; et al Nat. Commun. 2020, 11, 2432. doi: 10.1038/s41467-020-16336-z
86	Zhu Z. ; Hu X. ; An X. ; Xiao M. ; Zhang L. ; Li C. ; He L. Chem. Asian J. 2022, 17, 202200993. doi: 10.1002/asia.202200993
87	Zhu Z. ; Feng K. ; Li C. ; Tang R. ; Xiao M. ; Song R. ; Yang D. ; Yan B. ; He L. Adv. Mater. 2022, 34, 2108727. doi: 10.1002/adma.202108727
88	Yuan H. C. ; Yost V. E. ; Page M. R. ; Stradins P. ; Meier D. L. ; Branz H. M. Appl. Phys. Lett. 2009, 95 doi: 10.1063/1.3231438
89	Wang S. ; Wang C. ; Pan W. ; Sun W. ; Yang D. Solar RRL 2021, 5, 2000392. doi: 10.1002/solr.202100596
90	Putwa S. ; Curtis I. S. ; Dasog M. iScience 2023, 26, 106317. doi: 10.1016/j.isci.2023.106317
91	Beri D. Mater. Adv. 2023, doi: 10.1039/D2MA00984F
92	Sun W. ; Qian C. ; Chen K. ; Ozin G. ChemNanoMat 2016, 2, 847. doi: 10.1002/cnma.201600151
93	Sun W. ; Yan X. ; Qian C. ; Duchesne P. N. ; Kumar S. G. H. ; Ozin G. A. Faraday Discuss. 2020, 222, 424. doi: 10.1039/C9FD00104B
94	Battaglia C. ; Cuevas A. ; De Wolf S. Energy Environ. Sci. 2016, 9, 1552. doi: 10.1039/c5ee03380b
95	Boettcher S. W. ; Spurgeon J. M. ; Putnam M. C. ; Warren E. L. ; Turner-Evans D. B. ; Kelzenberg M. D. ; Maiolo J. R. ; Atwater H. A. ; Lewis N. S. Science 2010, 327, 185. doi: 10.1126/science.1180783
96	Oh I. ; Kye J. ; Hwang S. Nano Lett. 2012, 12, 298. doi: 10.1021/nl203564s
97	Liu D. ; Li L. ; Gao Y. ; Wang C. ; Jiang J. ; Xiong Y. Angew. Chem. Int. Ed. 2015, 54, 2980. doi: 10.1002/anie.201411200
98	Yan X. ; Sun W. ; Fan L. ; Duchesne P. N. ; Wang W. ; Kubel C. ; Wang D. ; Kumar S. G. H. ; Li Y. F. ; Tavasoli A. ; et al Nat. Commun. 2019, 10, 2608. doi: 10.1038/s41467-019-10464-x
99	Su Y. ; Wang S. ; Ji L. ; Zhang C. ; Cai H. ; Zhang H. ; Sun W. Nanoscale 2023, 15, 154. doi: 10.1039/D2NR05140K
100	Priolo F. ; Gregorkiewicz T. ; Galli M. ; Krauss T. F. Nat. Nanotechnol. 2014, 9, 19. doi: 10.1038/nnano.2013.271
101	O'Brien P. G. ; Sandhel A. ; Wood T. E. ; Jelle A. A. ; Hoch L. B. ; Perovic D. D. ; Mims C. A. ; Ozin G. A. Adv. Sci. 2014, 1, 1400001. doi: 10.1002/advs.201400001
102	Hoch L. B. ; O'Brien P. G. ; Jelle A. ; Sandhel A. ; Perovic D. D. ; Mims C. A. ; Ozin G. A. ACS Nano 2016, 10, 9017. doi: 10.1021/acsnano.6b05416
103	Zhang D. ; Lv K. ; Li C. ; Fang Y. ; Wang S. ; Chen Z. ; Wu Z. ; Guan W. ; Lou D. ; Sun W. ; et al Solar RRL 2020, 5, 2000387. doi: 10.1002/solr.202000387
104	Shen X. ; Li C. ; Wu Z. ; Tang R. ; Shen J. ; Chu M. ; Xu A. ; Zhang B. ; He L. ; Zhang X. Nanoscale 2022, 14, 11568. doi: 10.1039/d2nr02680e
105	Chen J. ; Loso E. ; Ebrahim N. ; Ozin G. A. J. Am. Chem. Soc. 2008, 130, 5420. doi: 10.1021/ja800288f
106	Curti M. ; Schneider J. ; Bahnemann D. W. ; Mendive C. B. J. Phys. Chem. Lett. 2015, 6, 3903. doi: 10.1021/acs.jpclett.5b01353
107	Jelle A. A. ; Ghuman K. K. ; O'Brien P. G. ; Hmadeh M. ; Sandhel A. ; Perovic D. D. ; Singh C. V. ; Mims C. A. ; Ozin G. A. Adv. Energy Mater. 2018, 8, 1702277. doi: 10.1002/aenm.201702277
108	O'Brien P. G. ; Ghuman K. K. ; Jelle A. A. ; Sandhel A. ; Wood T. E. ; Loh J. Y. Y. ; Jia J. ; Perovic D. ; Singh C. V. ; Kherani N. P. ; et al Energy Environ. Sci. 2018, 11, 3443. doi: 10.1039/c8ee02347f
109	Feng K. ; Wang S. ; Zhang D. ; Wang L. ; Yu Y. ; Feng K. ; Li Z. ; Zhu Z. ; Li C. ; Cai M. ; et al Adv. Mater. 2020, 32, e2000014. doi: 10.1002/adma.202000014
110	Fang Y. ; Lv K. ; Li Z. ; Kong N. ; Wang S. ; Xu A. B. ; Wu Z. ; Jiang F. ; Li C. ; Ozin G. A. ; et al Adv. Sci. 2020, 7, 2000310. doi: 10.1002/advs.202000310
111	Tiwari D. ; Dunn S. J. Mater. Sci. 2009, 44, 5063. doi: 10.1007/s10853
112	Thompson T. L. ; Yates J. T. Jr. Chem. Rev. 2006, 106, 4428. doi: 10.1021/cr050172k
113	Ge H. ; Kuwahara Y. ; Yamashita H. Chem. Commun. 2022, doi: 10.1039/D2CC02658A
114	Chen Y. ; Qi M. ; Li Y. ; Tang Z. ; Wang T. ; Gong J. ; Xu Y. Cell Rep. Phys. Sci. 2021, 2, 100371. doi: 10.1016/j.xcrp.2021.100371
115	Chiritescu C. ; Cahill D. G. ; Nguyen N. ; Johnson D. ; Bodapati A. ; Keblinski P. ; Zschack P. Science 2007, 315, 351. doi: 10.1126/science.1136494
116	Wang J. ; Xie F. ; Cao X. ; An S. ; Zhou W. ; Tang L. ; Chen K. Sci. Rep. 2017, 7, 1. doi: 10.1038/srep41418
117	Wu Z. ; Shen J. ; Li C. ; Zhang C. ; Feng K. ; Wang Z. ; Wang X. ; Meira D. M. ; Cai M. ; Zhang D. ACS Nano 2022, 17, 1550. doi: 10.1021/acsnano.2c10707
118	Wu Z. ; Shen J. ; Li C. ; Zhang C. ; Wu C. ; Li Z. ; An X. ; He L. Chemistry 2023, 5, 492. doi: 10.3390/chemistry5010036
119	Wang S. ; Feng K. ; Zhang D. ; Yang D. ; Xiao M. ; Zhang C. ; He L. ; Yan B. ; Ozin G. A. ; Sun W. Adv. Sci. 2022, 9, 2104972. doi: 10.1002/advs.202104972
120	Kattel S. ; Liu P. ; Chen J. G. J. Am. Chem. Soc. 2017, 139, 9739. doi: 10.1021/jacs.7b05362
121	Song Q. ; He G. ; Fei H. Acta Phys. -Chim. Sin. 2023, 39, 2212038.
	宋千伟; 何观朝; 费慧龙; 物理化学学报, 2023, 39, 2212038. doi: 10.3866/PKU.WHXB202212038
122	Li Y. ; Yang T. ; Qiu S. ; Lin W. ; Yan J. ; Fan S. ; Zhou Q. Chem. Eng. J. 2020, 389, 124382. doi: 10.1016/j.cej.2020.124382
123	Lei Y. ; Yang F. ; Xie H. ; Lei Y. ; Liu X. ; Si Y. ; Wang H. J. Mater. Chem. A 2020, 8, 20629. doi: 10.1039/D0TA06022D
124	Zhang Y. ; He S. ; Guo W. ; Hu Y. ; Huang J. ; Mulcahy J. R. ; Wei W. D. Chem. Rev. 2018, 118, 2927. doi: 10.1021/acs.chemrev.7b00430
125	Linic S. ; Chavez S. ; Elias R. Nat. Mater. 2021, 20, 916. doi: 10.1038/s41563-020-00858-4
126	Li R. ; Li Y. ; Li Z. ; Wei W. ; Hao Q. ; Shi Y. ; Ouyang S. ; Yuan H. ; Zhang T. ACS Catal. 2022, 12, 5316. doi: 10.1021/acscatal.2c00926
127	Sun W. ; Cao X. Chem. Catal. 2022, 2, 215. doi: 10.1016/j.checat.2022.01.017

Catalyst	Light source	H₂ : CO₂	R_CO2 (mol∙g_cat ⁻¹∙h⁻¹)	Reference
Ru/SiNW	300 W Xe light (0.32 W∙cm⁻²)	4 : 1	1.1 × 10⁻⁴	101
In₂O_3−x(OH)_y/SiNW	300 W Xe light (2.0 W∙cm⁻²)	1 : 1	2.2 × 10⁻⁵	102
SNAs@Co	300 W Xe light (2.5 W∙cm⁻²)	1 : 1	4.3 × 10⁻¹	103
SiNCs@Co	300 W Xe light (2.5 W∙cm⁻²)	1 : 1	1.78	104
ncRuO₂/i-Si-o	300 W Xe light (2.2 W∙cm⁻²)	4 : 1	4.4 × 10⁻³	107
Ru/i-Si-o	300 W Xe light (2.5 W∙cm⁻²)	4 : 1	2.8 × 10⁻³	108
Co@SiO₂-array	300 W Xe light (2.4 W∙cm⁻²)	1 : 1	4.1 × 10⁻²	109
Co-PS@SiO₂	300 W Xe light (2.5 W∙cm⁻²)	1 : 1	0.60	110

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Silicon Nanostructure Arrays: An Emerging Platform for Photothermal CO₂ Catalysis

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Silicon Nanostructure Arrays: An Emerging Platform for Photothermal CO₂ Catalysis