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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
2003 Vol. 19, No. 07
Published online: 2003-07-15
Current column
Communication
ARTICLE
Note
Review
Communication
Aqueous Two-phase System of Catanionic Surfactant Mixtures Formed by Adding Salts
Chen Li;Xiao Jin-Xin;Ma Ji-Ming
The equimolar mixed system of decyltriethylammonium bromide and sodium decylsulfonate, which was homogeneous solution ev...
2003, 19 (07): 577-579.
DOI: 10.3866/PKU.WHXB20030701
5753
Abstract/Metrics
3622
PDF(1241KB)
ARTICLE
Mechanism for the Reduction of Dichromate in the Polymerization of Aniline
Liao Chuan-Ping;Gu Ming-Yuan
The product of oxidative polymerization of aniline using dichromate as oxidant was proved to be polyaniline/Cr(OH)3 comp...
2003, 19 (07): 580-583.
DOI: 10.3866/PKU.WHXB20030702
8012
Abstract/Metrics
3239
PDF(1387KB)
Kinetics of Dissolution and Transformation of Chloropinnoite in H3BO3 Aqueous Solution
Li Xiao-Ping;Liu Zhi-Hong;Gao Shi-Yang;Hu Man-Cheng;Xia Shu-Ping
The kinetics of dissolution and transformation processes of 2MgO•2B2O3•MgCl2•14H2O in 4.5% H3BO3 aqueo...
2003, 19 (07): 584-587.
DOI: 10.3866/PKU.WHXB20030703
5952
Abstract/Metrics
3018
PDF(1633KB)
The Electrocatalytic Oxidation of Hydrogen Peroxide on Polyaniline Doped with Ferrocenesulfonic Acid
Mu Shao-Lin;Yang Yi-Fei;Tan Zhi-An
Polyaniline(PAnFc) synthesized in a presence of ferrocenesulfonic acid and polyaniline(PAn) synthesized in the absence o...
2003, 19 (07): 588-592.
DOI: 10.3866/PKU.WHXB20030704
6436
Abstract/Metrics
3183
PDF(1345KB)
Effects of Surface State of Nanocrystal PbTiO
3
on Their Dielectric Properties
Ruan Sheng-Ping;Wang Jing;Zhang Li;Yang Dong;Xuan Li
Nanocrystalline PbTiO3 powder was obtained by melting appropriate amount of stearic acid at 70 ℃, into which tetrabutyl ...
2003, 19 (07): 593-596.
DOI: 10.3866/PKU.WHXB20030705
4929
Abstract/Metrics
2935
PDF(1779KB)
Templated Synthesis and Magnetic Properties of Fe-Co-Ni Ternary Alloy Nanowires
Jiang Guo-Wei;Yao Lian-Zeng;Jin Chuan-Gui;He Ting;Lin Qing;Cai Wei-Li;Li Xiao-Guang;Yao Zhen
Highly ordered ternary alloy nanowire arrays have been fabricated within nanochannels of anodic alumina membrane by elec...
2003, 19 (07): 597-600.
DOI: 10.3866/PKU.WHXB20030706
5410
Abstract/Metrics
3377
PDF(1701KB)
Theoretical Calculation of Metastable Zone Width of Monomehypo Solution
Wang Yan;Wang Seng-Qun;Li Jun
Industrial crystallizers have to be operated at the optimum supersaturation which is less than the metastable zone width...
2003, 19 (07): 601-604.
DOI: 10.3866/PKU.WHXB20030707
5640
Abstract/Metrics
2898
PDF(1541KB)
Experimental Measurements of Distribution of Retention Time for Aerosol Particles through Packed Column
Yang Tong-Zai;Chen Yin-Liang;Xiong Wang;Yang Yan-Qiu;Ma Jun;Ye Shi-You;Liu Yi-Nong;Yu Zhong-Jin;Song Tao
Principles of aerosol transport mechanics are widely used to describe the performance of various sampling,filtration and...
2003, 19 (07): 605-609.
DOI: 10.3866/PKU.WHXB20030708
5288
Abstract/Metrics
3437
PDF(1927KB)
Synthesis, Thermostability and Bioactivity of Mixed Ligand Complexes of Lanthanum with Alanine and Imidazoles
Yang Rui;He Shui-Yang;Gu Ai-Ping;Wen Zhen-Yi;Lin Xiang; Wen Hui-Zhong
Two new ternary complexes La(Ala)3Im(ClO4)3•3H2O (La1) and La(Ala)3BenIm(ClO4)3•H2O (La2) of lanthanum perch...
2003, 19 (07): 610-615.
DOI: 10.3866/PKU.WHXB20030709
5808
Abstract/Metrics
3326
PDF(2110KB)
Effect of Strain Rate and Potential on the Propagation of Stress Corrosion Crack
Niu Lin;Zhang Chang-Qiao;Lin Hai-Chao
On the basis of the model of slip-bare metal dissolution-repassivation and crack-tip strain analysis, a theoretical equa...
2003, 19 (07): 616-620.
DOI: 10.3866/PKU.WHXB20030710
5132
Abstract/Metrics
2919
PDF(1601KB)
Preparation and Characterization of SurfaceModified SnO
2
Nanocrystals
Gu Feng-Cai;Zhao Zhu-Xuan;Li Ying-Hui;Men Juan;Yan Ju-Ming;Liu Rui-Xian;Zhang Li-Hua
The surface-modified SnO2 nanocrystals were prepared from SnO2 nanoparticles and silane coupling reagent KH-570 (γ-metha...
2003, 19 (07): 621-625.
DOI: 10.3866/PKU.WHXB20030711
6316
Abstract/Metrics
3428
PDF(1900KB)
Quantum Study on the Reaction Mechanism of CH
3
(
2
A
′) Radicals with Ozone Reaction
Li Lai-Cai;Tian An-Min
The geometries of reactants, transition states, intermediates and products on the reaction of CH3(2A′)+O3 have been opti...
2003, 19 (07): 626-629.
DOI: 10.3866/PKU.WHXB20030712
5133
Abstract/Metrics
2980
PDF(1120KB)
Study on Electrodeposition of Er-Bi Alloy Films in Organic Bath
Li Gao-Ren;Tong Ye-Xiang;Liu Guan-Kun
Cyclic voltammetry and potentiostatic electrolysis were used to investigate the preparation of Er-Bi alloy films in LiCl...
2003, 19 (07): 630-634.
DOI: 10.3866/PKU.WHXB20030713
5398
Abstract/Metrics
3026
PDF(1679KB)
The Photoelectrochemical Properties of Four Hemicyanine Derivatives on Nanocrystalline TiO
2
Electrode
Yao Qiao-Hong;Shan Lu;Li Fu-You;Yin Dong-Dong;Huang Chun-Hui
Four hemicyanine derivatives, (E)-N-(4-sulfobutyl)-4-[2-(4-N, N-dimethylamino- phenyl) ethenyl] pyridinium(P1), (E)-N-(4...
2003, 19 (07): 635-640.
DOI: 10.3866/PKU.WHXB20030714
5259
Abstract/Metrics
3190
PDF(1794KB)
A Study of Interface Diffusion and Reaction of Ti/ZrN
2
/Si Film
Wang Li;Yin Mu-Sheng;Zhu Yong-Fa
Ti/ZrN2 multiplayer was deposited on silicon wafer using DC magnetron sputtering method. Interface diffusion and chemica...
2003, 19 (07): 641-646.
DOI: 10.3866/PKU.WHXB20030715
5133
Abstract/Metrics
3190
PDF(1592KB)
The Preparation and Electrochemistry of the Modified Electrodes by the Nano Silver-Zirconium Phosphate Composite Film
Wang Yan-Ling;Zhang Guo-Rong
A novel composite material consisting of nano-colloidal silver and zirconium phosphate was synthesized and applied for t...
2003, 19 (07): 647-650.
DOI: 10.3866/PKU.WHXB20030716
5385
Abstract/Metrics
3291
PDF(1871KB)
Note
Structure and Thermodynamic Properties of UO
2
, UC
2
and UCO
Wang Hong-Yan;Chen Chang-An;Sun Ying;Zhu Zheng-He
The structure parameters and some thermodynamic functions for UO2, UC2, UCO are calculated using ab initio method. The v...
2003, 19 (07): 651-653.
DOI: 10.3866/PKU.WHXB20030717
5542
Abstract/Metrics
3222
PDF(1050KB)
Sulfonated Poly (phthalazinone ether sulfone ketone) Catalyst with High Thermal Stability
An Zeng-Jian;Zhou Peng;Jian Xi-Gao;Cai Tian-Xi
A new solid acid resin catalyst with high thermal stability——sulfonated poly (phthalazinone ether sulfone ketone) (S-PPE...
2003, 19 (07): 654-656.
DOI: 10.3866/PKU.WHXB20030718
5474
Abstract/Metrics
2928
PDF(1269KB)
Surface Modification of PAn Particles
Wei Jian-Hong;Shi Jing;Guan Jian-Guo;Yuan Run-Zhang
By using modified sol-gel method, BaTiO3 nano-films were coated on the surface of polyaniline particles. The structure a...
2003, 19 (07): 657-660.
DOI: 10.3866/PKU.WHXB20030719
5270
Abstract/Metrics
3552
PDF(1595KB)
Dissociation of Methane in Intense Femtosecond Laser Field
Tang Xiao-Ping;Wang Su-Fan;Gao Li-Rong;Wang Cao;Kong Fan-Ao
Methane molecules were irradiated by a laser beam in the intensity range of 7.6 ×1013~1.4×1014 W•cm-2 (800 nm, 160...
2003, 19 (07): 661-665.
DOI: 10.3866/PKU.WHXB20030720
5591
Abstract/Metrics
3174
PDF(1578KB)
Supported Catalyst LaCoO
3
/
γ
-Al
2
O
3
Prepared by Impregnating under Ultrasound
Liang Xin-Yi;Zhang Li-Ming;Ding Hong-Yuan;Qin Yong-Ning
The supported catalyst LaCoO3/γ-Al2O3 was prepared by ultrasound during the impregnating preparation steps and the effe...
2003, 19 (07): 666-669.
DOI: 10.3866/PKU.WHXB20030721
5573
Abstract/Metrics
3225
PDF(1280KB)
Emission Behavior of Non-Planar Intra-Molecular Conjugated Charge Transfer Compounds
Zhou Li-Li;Jiang Yong-Cai;Ju Wei-Gang;Zhang Xiao-Hong;Wu Shi-Kang
Two kinds of intra-molecular conjugated charge transfer compounds 2,3-dicyano-5,7-bis[2-[4-dimethylamino-phenyl]ethenyl]...
2003, 19 (07): 670-674.
DOI: 10.3866/PKU.WHXB20030722
5456
Abstract/Metrics
3168
PDF(1578KB)
Review
1
H NMR Studies of Surfactants in Aqueous Solutions
Mao Shi-Zhen;Du You-Ru
Surfactant is a substance that lowers the surface tension of the medium in which it is dissolved. They form oriented col...
2003, 19 (07): 675-680.
DOI: 10.3866/PKU.WHXB20030723
6493
Abstract/Metrics
7000
PDF(586KB)