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Acta Phys. -Chim. Sin.
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中文
Current Issue
1999 Vol. 15, No. 03
Published online: 1999-03-15
Current column
Communication
ARTICLE
Note
Communication
Theoretical Study of Rection of HOCl and HCl on Water Clusters
Xu Si-Chuan, Zhao Xin-Sheng
Acta Phys. -Chim. Sin. 1999, 15 (03), 193-197.
DOI: 10.3866/PKU.WHXB19990301
6791
Abstract/Metrics
2896
PDF(669KB)
Preparation and Structural Characterization of Self-assembled Monolayers from a New Series of Mercapto Contained Azobenzene Derivatives
Li Hai-Ying, Zhang Hao-Li, Zhang Jin, Liu Zhong-Fan
Self Assembled Monolayers(SAMs) of a series of mercapto contained azobenzene derivatives with the structure of CnH2n+1Az...
Acta Phys. -Chim. Sin. 1999, 15 (03), 198-203.
DOI: 10.3866/PKU.WHXB19990302
6432
Abstract/Metrics
3217
PDF(1978KB)
ARTICLE
Ab Initio Calculation on Oxamidato-bridged Binuclear Copper(II) Complex as Structural Unit
Zheng Kang-Cheng, Chen Zhong-Ning, Huang Jia-Duo, Liu Han-Qin
The investigation of the cis-trans conformations and their singlet and triplet electronic configurations of the oxamidat...
Acta Phys. -Chim. Sin. 1999, 15 (03), 204-209.
DOI: 10.3866/PKU.WHXB19990303
6326
Abstract/Metrics
3493
PDF(1681KB)
Solute Diffusion in the Dynamic Network of Gel
Liu Hong-Bin, Ren Yan, Wang Yu-Xin, Wang Shi-Chang, An Ying-Li, Zuo Ju
A study was carried out both theoretically and experimentally on the solute diffusion in gel networks. The emphasi...
Acta Phys. -Chim. Sin. 1999, 15 (03), 210-215.
DOI: 10.3866/PKU.WHXB19990304
6744
Abstract/Metrics
2681
PDF(1888KB)
The Influence of Alcohol on the Aggregation Behavior of DDAHPS Molecules in Water
Shen Qiang, Li Gan-Zuo, Huang Yan-Zhang, Ye Jian-Ping
The influence of alcohol on the aggregation behavior of the zwitterionic surfactant (dodecyldimethylammonium hydroxyl pr...
Acta Phys. -Chim. Sin. 1999, 15 (03), 216-221.
DOI: 10.3866/PKU.WHXB19990305
5456
Abstract/Metrics
3007
PDF(1753KB)
The Photoelectrochemical Properties of Composite Titanium Dioxide and Ferric Oxide Nanocrystalline Electrodes
Wang Yan-qin, Cheng Hu-Min, Ma Ji-Ming
The photoelectrochemical behaviors of the mutual modified nanocrystalline Fe 2O 3 and TiO 2 electrodes prepared by diffe...
Acta Phys. -Chim. Sin. 1999, 15 (03), 222-227.
DOI: 10.3866/PKU.WHXB19990306
6841
Abstract/Metrics
3989
PDF(1868KB)
Thermodynamics of Deoxidation of High Purity Niobium
Liu Sheng-Feng, Lin Jian-Hua, Su Mian-Zeng
Starting niobium samples with different oxygen contents were produced by arc melting and electron beam melting respectiv...
Acta Phys. -Chim. Sin. 1999, 15 (03), 228-233.
DOI: 10.3866/PKU.WHXB19990307
5509
Abstract/Metrics
2896
PDF(1606KB)
Mossbuer Spectroscopic Studies of Fe
2
O
3
-K
2
O-Based Catalysts for Ethylbenzene Dehydrogenation
Zhu Yi-Xiang, Chen Rong-Qin, Feng Lei, Wang Jun
Fe 2O 3 K 2O Catalysts with different content of K 2O and calcined at different temperature were characterized by using ...
Acta Phys. -Chim. Sin. 1999, 15 (03), 234-240.
DOI: 10.3866/PKU.WHXB19990308
5712
Abstract/Metrics
2977
PDF(2121KB)
Synthesis,Structural Characterization and Reaction of the Chiral Clusters
Ding Er-Run, Wu Shu-Lin, Li Qing-Shan, Yin Yuan-Qi
Several chiral clusters RuCoMo(μ-3 S)(CO) 8C 5H 4C(O)R were synthesized by the thermal reaction of the precursor (&mu...
Acta Phys. -Chim. Sin. 1999, 15 (03), 241-246.
DOI: 10.3866/PKU.WHXB19990309
6037
Abstract/Metrics
2851
PDF(1531KB)
Mechanism of Reaction HNCO+OH->H
2
O+NCO
Shi Tu-Jin, Li Zong-He, Liu Ruo-Zhuang
The mechanism of the reaction HNCO +OH→H2 O +NCO has been studied by using ab initio MO method(at UMP4/6 31G** leve...
Acta Phys. -Chim. Sin. 1999, 15 (03), 247-252.
DOI: 10.3866/PKU.WHXB19990310
8549
Abstract/Metrics
2882
PDF(1453KB)
Rapid-Mixing Stopped-Flow Studies of lron Porphrin Enzyme-Mimic Systems
Xia Chun-Gu, Li Zhen, Wei Chi-Li, Li Shu-Ben
The reactions of different iron porphrin complexes Fe Ⅲ(TPP)Cl [tetraphenylporphinatoiron(III) chloride],Fe Ⅲ(TMOPP)Cl [...
Acta Phys. -Chim. Sin. 1999, 15 (03), 253-258.
DOI: 10.3866/PKU.WHXB19990311
6481
Abstract/Metrics
2850
PDF(1656KB)
Note
UV Photolysis of Oxalyl Chloride and 2,3-butanedione Studied by Time-resolved FTIR
Li Qiang, Li Hong-Zhi, Kong Fan-Ao
The photodissociation of oxalyl chloride and 2,3 butanedione at 193nm and 248nm have been studied by Time resolved FTIR ...
Acta Phys. -Chim. Sin. 1999, 15 (03), 259-264.
DOI: 10.3866/PKU.WHXB19990312
7626
Abstract/Metrics
3152
PDF(1655KB)
Determinstion of Standard Transfer Entropies of RbCl from H
2
O to Mixtures of H
2
O-DMF
Li Lin-Wei, Chu De-Ying, Liu Rui-Lin
The standard electromotive forces of the reversible cells consisted of the Corning monovalent general cation selective e...
Acta Phys. -Chim. Sin. 1999, 15 (03), 265-268.
DOI: 10.3866/PKU.WHXB19990313
5909
Abstract/Metrics
2590
PDF(1460KB)
Thermodynamical and Electrochemical Properties of CTAB/C
n
H
2n+1
OH/H
2
O
Guo Rong, Shen Ming, Liu Tian-Qing
Distribution coefficient K of C n H 2 n +1 OH between micellar phase and water phase in CTAB/C n OH/H 2O O/W system incr...
Acta Phys. -Chim. Sin. 1999, 15 (03), 269-273.
DOI: 10.3866/PKU.WHXB19990314
6210
Abstract/Metrics
3277
PDF(1587KB)
Microcalorimetric and Nonequlibrium Thermodynamic Studies on the Gemination and Growth of Seeds
Zhou Pei-Jiang, Hu Yun-Chu, Ling Xing-Yuan, Yang Feng, Song Zhao-Hua, Qu Song-Sheng, Zhu Ying-Guo
The thermograms of the germination and growth of rice and tree seeds were determined and studied by using a newly ...
Acta Phys. -Chim. Sin. 1999, 15 (03), 274-278.
DOI: 10.3866/PKU.WHXB19990315
5101
Abstract/Metrics
2788
PDF(447KB)
Raman Study of the Electrochromic V
2
O
5
Films
Guan Zi-Sheng, Yang Yong-An, Ma Ying, Yao Jian-Nian
The amorphous V 2O 5 films prepared by vacuum evaporation are unstable and easily dissolved by electrolyte during the el...
Acta Phys. -Chim. Sin. 1999, 15 (03), 279-283.
DOI: 10.3866/PKU.WHXB19990316
5740
Abstract/Metrics
2692
PDF(1736KB)
Alternative Copolymerization of CO and Ethylene Catalyzed by Palladium(II)
Luo He-Kuan, Li Da-Gang
With high presure in situ 1H NMR technique, the alternative copolymerization of CO with ethylene catalyzed by Pd(Ⅱ)-DPPP...
Acta Phys. -Chim. Sin. 1999, 15 (03), 284-288.
DOI: 10.3866/PKU.WHXB19990317
5936
Abstract/Metrics
3052
PDF(1422KB)