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Acta Phys. -Chim. Sin.
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中文
Current Issue
1993 Vol. 9, No. 02
Published online: 1993-04-15
Current column
Communication
ARTICLE
Note
Review
Communication
The Establishment of the SET-UP ion-Neutral Reaction and Application
Peng Yue-Xiang; Chen Xin-Guo; Song Fen-Hong; Qiu Lian-Xiong
This paper reports the establishment of the set-up of ion-neutral reaction and the measurement of the rate constant of t...
Acta Phys. -Chim. Sin. 1993, 9 (02), 145-147.
DOI: 10.3866/PKU.WHXB19930201
5422
Abstract/Metrics
2523
PDF(588KB)
Studies on Langmuir-Blodgett Films of Luminescent Rare-Earth Chelates (I)
Qian Dong-Jin; Yang Kong-Zhang
Two series of luminescent rare-earth chelates have been studied spectroscopically, one is(TOPO)_2Eu(β-dik)_3(TOPO=tri-n-...
Acta Phys. -Chim. Sin. 1993, 9 (02), 148-154.
DOI: 10.3866/PKU.WHXB19930202
5598
Abstract/Metrics
2883
PDF(1629KB)
Theoretical Study on the Dynamic Properties and State-Selected rate Constants of the Reaction CH(
4
Σ
-
)+H
2
→CH
2
(
3
B
1
)+H
Liu Ruo-Zhuang; Ma Si-Yu; Li Zong-He
Tbe reaction path (IRC or MEP) of the reaction CH(~4∑~-)+H_2→CH_2(~3B_1)+H has been traced by Fukui's theory and ab init...
Acta Phys. -Chim. Sin. 1993, 9 (02), 155-160.
DOI: 10.3866/PKU.WHXB19930203
5604
Abstract/Metrics
2682
PDF(1163KB)
Non-Linear Elemental Exciton and Electronic Level of C
60
Molecule
Yan Li-Gen; Wang De-Min; Li Ming; Jia Rong-Yi
The electronic states of a C_(60) molecule have been calculated by using the SSH model. The electronic energy spectrum a...
Acta Phys. -Chim. Sin. 1993, 9 (02), 161-164.
DOI: 10.3866/PKU.WHXB19930204
4833
Abstract/Metrics
2516
PDF(741KB)
Electronic Structures and Conductivities of Halogen-Containing Carbon-Sixty C
60
X
Lu Chong-Xian; Kong Jing; Yan Ji-Min
Acta Phys. -Chim. Sin. 1993, 9 (02), 165-169.
DOI: 10.3866/PKU.WHXB19930205
5550
Abstract/Metrics
2936
PDF(870KB)
ARTICLE
Determination of O
1
s
Binding Energies of the Alkaline Earth Oxides and Peroxide
Zhao Liang-Zhong
The O_(1s) binding energy of MgO, CaO, SrO and BaO were determined by means of XPS. Prior to the determination,the sampl...
Acta Phys. -Chim. Sin. 1993, 9 (02), 170-174.
DOI: 10.3866/PKU.WHXB19930206
7097
Abstract/Metrics
3013
PDF(1190KB)
Study on the Polarographic Behaviors of Morin
Li Nan-Qiang; Xu You-Xuan
The electrochemical properties of morin(MOR)over the entire pH range were studied. Four reduction waves were obtained. P...
Acta Phys. -Chim. Sin. 1993, 9 (02), 175-180.
DOI: 10.3866/PKU.WHXB19930207
5777
Abstract/Metrics
2929
PDF(1315KB)
Application of SPE(Solid Polymer Electrolyte) in Electrooxidation of Cinnamyl Alcohol(I)
Chen Zhen
SPE (Solid Polymer Electrolyte) composite electrodes were utilized for the selective oxidation of allyl alcohol to aldeh...
Acta Phys. -Chim. Sin. 1993, 9 (02), 181-186.
DOI: 10.3866/PKU.WHXB19930208
5438
Abstract/Metrics
2910
PDF(1270KB)
Study on Dispersion of V
2
O
5
on Surface of SiO
2
and the Effect of Promoter K
2
SO
4
Zhao Bi-Ying; Wang Qiu-Xia; Tang You-Qi
It has been shown by in situ XRD that V_2O_5 can disperse spontaneously onto the surface of silica gel, but the dispersi...
Acta Phys. -Chim. Sin. 1993, 9 (02), 187-192.
DOI: 10.3866/PKU.WHXB19930209
5682
Abstract/Metrics
2869
PDF(1461KB)
Preparation,Pillarinc Structure and Thermal Stability of Hydroxy-Fe-Al Pillared Clays Containing Mixed-Metal Complexes(I)
Zhao Dong-Yuan; Yang Ya-Shu; Guo Xie-Xian; Wang Guo-Jia
A series of Hydroxy-Fe-Al Pillared Clays (FeAl-PILC) containing mixed-metal complexes with various Fe/Al ratios were pre...
Acta Phys. -Chim. Sin. 1993, 9 (02), 193-199.
DOI: 10.3866/PKU.WHXB19930210
6719
Abstract/Metrics
2635
PDF(1530KB)
Study on the Property of Orientation Distribution Function for Uniaxially two-Dimensional Condensed Phases
Zhang Yun-Hong; Tian Yong-Chi; Liang Ying-Qiu
In this paper, the property of orientation distribution function composed of second and fourth legendre polynomials was ...
Acta Phys. -Chim. Sin. 1993, 9 (02), 200-205.
DOI: 10.3866/PKU.WHXB19930211
5412
Abstract/Metrics
2939
PDF(1184KB)
The Catalytic Oxidation of Co Over Ba
2-
x
Sr
x
YCu
3
O
7-
a
Deng Jing-Fa; Peng Ying; Jiang An-Ren; Wang Zhi-Hong
High temperature oxide superconducters Ba_(2-x)Sr_xYCu_3O_(7-a) (x=0, 0.25, 0.50, 0.75, 1.0, 1.25) was prepared using hi...
Acta Phys. -Chim. Sin. 1993, 9 (02), 206-210.
DOI: 10.3866/PKU.WHXB19930212
6113
Abstract/Metrics
2682
PDF(967KB)
AES Chemical Shift and Application on Surface Chemistry
Zhu Yong-Fa
The relationship of AES chemical shift with clement valence and electronegativity is discussed. It has also offered Auge...
Acta Phys. -Chim. Sin. 1993, 9 (02), 211-217.
DOI: 10.3866/PKU.WHXB19930213
6149
Abstract/Metrics
4256
PDF(1768KB)
Studies on the Oscillation of
m
-C
6
H
4
(OH)
2
-KBrO
3
-H
2
SO
4
System
Gao Zhi-Di; Liu Jun-Li; Han De-Gang; Shen Shi-Gang; Wang An-Zhou
The oscillations of m-C_6H_4(OH)_2-KBrO_3-H_2SO_4 (system A) as well as m-C_6H_4(OH)_2-KBrO_3-H_2SO_4-MnSO_4(system B) h...
Acta Phys. -Chim. Sin. 1993, 9 (02), 218-223.
DOI: 10.3866/PKU.WHXB19930214
6199
Abstract/Metrics
2918
PDF(1171KB)
The Viscosity Behaviour of SEP Block Copolymer Solution During its Micellization
Zhou Wei-Ping; He Zhi-Duan; Zhang Hao; Zhang Hai-Bo
The viscosities of polystyrene-b-poly (ethylene/propylene) diblock copolymer in mixed solvent of n-octane and benzene we...
Acta Phys. -Chim. Sin. 1993, 9 (02), 224-228.
DOI: 10.3866/PKU.WHXB19930215
5920
Abstract/Metrics
2749
PDF(989KB)
Note
Effect of the Length of Alkane Skeleton on the Thermodynamic Function of Microemulsion with Nonionic Surfactant
Hao Ce; Sun Zhi-Gang; Chen Zong-Qi; Shi Cai-Yun
This paper reported the studies on the microemulsion of TritonX-100, hexanol, Water and alkane system. △G_(s→i)~0, the v...
Acta Phys. -Chim. Sin. 1993, 9 (02), 229-232.
DOI: 10.3866/PKU.WHXB19930216
6234
Abstract/Metrics
2685
PDF(718KB)
Studying on Stability of Emulsion Liquid Membrane with Moving Single Drop Method
Zhang He-Zhe; Bai Guang-Yue; Wang Yue-Jie; Yang Zhong
We detailed the stability of ELM with glutamic acid dialkyl esters as surfactants by moving single drop method. It is a ...
Acta Phys. -Chim. Sin. 1993, 9 (02), 233-237.
DOI: 10.3866/PKU.WHXB19930217
5738
Abstract/Metrics
2761
PDF(944KB)
A Study on UV and Visible Fluorescence Produced by Irmpd of Trimethyl Phosphite
Lu Qing-Zheng; Tao Li; Yu Shu-Qin; Kong Fan-Ao
IR multi-photon dissociation (IRMPD) of trimethyl phosphite has been carried out by a TEA CO_2 laser. The fluorescence s...
Acta Phys. -Chim. Sin. 1993, 9 (02), 238-241.
DOI: 10.3866/PKU.WHXB19930218
5120
Abstract/Metrics
2701
PDF(824KB)
Application of Pervaporation Membrane to Catalytic Esterification Reaction
Gao Zi; Yue Ying-Hong; Li Wen-Jun
Studies on pervaporation separation of alcohol/water mixture and pervaporation-aided catalytic esterification reaction h...
Acta Phys. -Chim. Sin. 1993, 9 (02), 242-246.
DOI: 10.3866/PKU.WHXB19930219
6830
Abstract/Metrics
3027
PDF(1005KB)
Quenching Rate Constants for Metastable Molecule CS(
α
3
П
)
Wang Hai-Qing; Gu Yue-Shu; Guo Jing-Zhong; Liu Chuan-Pu; Yin Yong-Jia; Cao De-Zhao
The metastable molecule CS(a~3Π) has been obtained, by the energy transfer reaction of He(2~3S) with CS_2 in a discharge...
Acta Phys. -Chim. Sin. 1993, 9 (02), 247-251.
DOI: 10.3866/PKU.WHXB19930220
5260
Abstract/Metrics
2637
PDF(1020KB)
Electronic Structure and Chemical Bond of Complex La(NO
3
)
3
·
bipy
·
2H
2
O
·
(B-15-C-5)
Dong Nan; Zhu Long-Guan; Wu Nian-Ci
The electronic structure and chemical bonds in La(NO_3)_3·bipy·2H_2O·(B-15-C-5) has been studied by INDO method. The res...
Acta Phys. -Chim. Sin. 1993, 9 (02), 252-255.
DOI: 10.3866/PKU.WHXB19930221
5750
Abstract/Metrics
2528
PDF(785KB)
Investigation on the Structure of Electronic Energy Bands of Polydiacetylenes
Zhang Qi-Yuan; Yan Ji-Min; Zhang Da-Ren
The influences of the side phenyls (PHs) on the electronic energy band-structure of polydiaeetylenes have been studied b...
Acta Phys. -Chim. Sin. 1993, 9 (02), 256-262.
DOI: 10.3866/PKU.WHXB19930222
5531
Abstract/Metrics
3248
PDF(1455KB)
Determination of the Activity Coefficients of TBP in
n
-Cetane by Cryoscopic Method
Chen Jin-Bang
The activity coefficients of TBP in n-cetane have been determined by cryoscopic method. This method is simpler, more rap...
Acta Phys. -Chim. Sin. 1993, 9 (02), 263-267.
DOI: 10.3866/PKU.WHXB19930223
5590
Abstract/Metrics
2902
PDF(929KB)
Study on the Ferrocene-Containing Ploynuculi Metal Complexes Quenching Luminescence of
*
[Cr(bpy)
3
]
3+
Xia Xu-Bing; Duan Chun-Ying; Zhu Long-Gen; Cao Hong; You Jing-Jing
Ferrocene-containing ploynuclear metal complexes M(Fe-C(CH_3)=N N=CSSR)_2 (M=Ni~(2+), Cu~(2+), Zn~(2+), Pd~(2+), Co~(2+)...
Acta Phys. -Chim. Sin. 1993, 9 (02), 268-272.
DOI: 10.3866/PKU.WHXB19930224
5331
Abstract/Metrics
3057
PDF(1049KB)
Spontaneous Oscillation of Electrical Potential Across Liquid Membrane
Wang Shou-Xiang; Qiu Zhi-Xin; Chen Sen; Gong Jian-Ping
An artificial membrane consisting of pricramic acid in nitrobenzene was used as an oil phase imposed between two aqueous...
Acta Phys. -Chim. Sin. 1993, 9 (02), 273-276.
DOI: 10.3866/PKU.WHXB19930225
4782
Abstract/Metrics
2692
PDF(755KB)
Photoelectrochemical Polymerization of Conducting Polymer Monomers
Chen Yan-Zhen; Gu Zhi-Jun; Tian Zhong-Qun
The photoelectrochemical polymerization process: monomer first polymerizes into low polymer and then the low polymer may...
Acta Phys. -Chim. Sin. 1993, 9 (02), 277-280.
DOI: 10.3866/PKU.WHXB19930226
5836
Abstract/Metrics
2847
PDF(800KB)