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Acta Phys. -Chim. Sin.
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中文
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1993 Vol. 9, No. 02
Published online: 1993-04-15
Current column
Communication
ARTICLE
Note
Review
Communication
The Establishment of the SET-UP ion-Neutral Reaction and Application
Peng Yue-Xiang; Chen Xin-Guo; Song Fen-Hong; Qiu Lian-Xiong
This paper reports the establishment of the set-up of ion-neutral reaction and the measurement of the rate constant of t...
Acta Phys. -Chim. Sin. 1993, 9 (02), 145-147.
DOI: 10.3866/PKU.WHXB19930201
6517
Abstract/Metrics
2592
PDF(588KB)
Studies on Langmuir-Blodgett Films of Luminescent Rare-Earth Chelates (I)
Qian Dong-Jin; Yang Kong-Zhang
Two series of luminescent rare-earth chelates have been studied spectroscopically, one is(TOPO)_2Eu(β-dik)_3(TOPO=tri-n-...
Acta Phys. -Chim. Sin. 1993, 9 (02), 148-154.
DOI: 10.3866/PKU.WHXB19930202
6710
Abstract/Metrics
3170
PDF(1629KB)
Theoretical Study on the Dynamic Properties and State-Selected rate Constants of the Reaction CH(
4
Σ
-
)+H
2
→CH
2
(
3
B
1
)+H
Liu Ruo-Zhuang; Ma Si-Yu; Li Zong-He
Tbe reaction path (IRC or MEP) of the reaction CH(~4∑~-)+H_2→CH_2(~3B_1)+H has been traced by Fukui's theory and ab init...
Acta Phys. -Chim. Sin. 1993, 9 (02), 155-160.
DOI: 10.3866/PKU.WHXB19930203
6979
Abstract/Metrics
2993
PDF(1163KB)
Non-Linear Elemental Exciton and Electronic Level of C
60
Molecule
Yan Li-Gen; Wang De-Min; Li Ming; Jia Rong-Yi
The electronic states of a C_(60) molecule have been calculated by using the SSH model. The electronic energy spectrum a...
Acta Phys. -Chim. Sin. 1993, 9 (02), 161-164.
DOI: 10.3866/PKU.WHXB19930204
6201
Abstract/Metrics
2729
PDF(741KB)
Electronic Structures and Conductivities of Halogen-Containing Carbon-Sixty C
60
X
Lu Chong-Xian; Kong Jing; Yan Ji-Min
Acta Phys. -Chim. Sin. 1993, 9 (02), 165-169.
DOI: 10.3866/PKU.WHXB19930205
6868
Abstract/Metrics
3063
PDF(870KB)
ARTICLE
Determination of O
1
s
Binding Energies of the Alkaline Earth Oxides and Peroxide
Zhao Liang-Zhong
The O_(1s) binding energy of MgO, CaO, SrO and BaO were determined by means of XPS. Prior to the determination,the sampl...
Acta Phys. -Chim. Sin. 1993, 9 (02), 170-174.
DOI: 10.3866/PKU.WHXB19930206
8590
Abstract/Metrics
3237
PDF(1190KB)
Study on the Polarographic Behaviors of Morin
Li Nan-Qiang; Xu You-Xuan
The electrochemical properties of morin(MOR)over the entire pH range were studied. Four reduction waves were obtained. P...
Acta Phys. -Chim. Sin. 1993, 9 (02), 175-180.
DOI: 10.3866/PKU.WHXB19930207
7249
Abstract/Metrics
3297
PDF(1315KB)
Application of SPE(Solid Polymer Electrolyte) in Electrooxidation of Cinnamyl Alcohol(I)
Chen Zhen
SPE (Solid Polymer Electrolyte) composite electrodes were utilized for the selective oxidation of allyl alcohol to aldeh...
Acta Phys. -Chim. Sin. 1993, 9 (02), 181-186.
DOI: 10.3866/PKU.WHXB19930208
6723
Abstract/Metrics
3242
PDF(1270KB)
Study on Dispersion of V
2
O
5
on Surface of SiO
2
and the Effect of Promoter K
2
SO
4
Zhao Bi-Ying; Wang Qiu-Xia; Tang You-Qi
It has been shown by in situ XRD that V_2O_5 can disperse spontaneously onto the surface of silica gel, but the dispersi...
Acta Phys. -Chim. Sin. 1993, 9 (02), 187-192.
DOI: 10.3866/PKU.WHXB19930209
6961
Abstract/Metrics
3115
PDF(1461KB)
Preparation,Pillarinc Structure and Thermal Stability of Hydroxy-Fe-Al Pillared Clays Containing Mixed-Metal Complexes(I)
Zhao Dong-Yuan; Yang Ya-Shu; Guo Xie-Xian; Wang Guo-Jia
A series of Hydroxy-Fe-Al Pillared Clays (FeAl-PILC) containing mixed-metal complexes with various Fe/Al ratios were pre...
Acta Phys. -Chim. Sin. 1993, 9 (02), 193-199.
DOI: 10.3866/PKU.WHXB19930210
8005
Abstract/Metrics
2754
PDF(1530KB)
Study on the Property of Orientation Distribution Function for Uniaxially two-Dimensional Condensed Phases
Zhang Yun-Hong; Tian Yong-Chi; Liang Ying-Qiu
In this paper, the property of orientation distribution function composed of second and fourth legendre polynomials was ...
Acta Phys. -Chim. Sin. 1993, 9 (02), 200-205.
DOI: 10.3866/PKU.WHXB19930211
6847
Abstract/Metrics
3113
PDF(1184KB)
The Catalytic Oxidation of Co Over Ba
2-
x
Sr
x
YCu
3
O
7-
a
Deng Jing-Fa; Peng Ying; Jiang An-Ren; Wang Zhi-Hong
High temperature oxide superconducters Ba_(2-x)Sr_xYCu_3O_(7-a) (x=0, 0.25, 0.50, 0.75, 1.0, 1.25) was prepared using hi...
Acta Phys. -Chim. Sin. 1993, 9 (02), 206-210.
DOI: 10.3866/PKU.WHXB19930212
7476
Abstract/Metrics
2803
PDF(967KB)
AES Chemical Shift and Application on Surface Chemistry
Zhu Yong-Fa
The relationship of AES chemical shift with clement valence and electronegativity is discussed. It has also offered Auge...
Acta Phys. -Chim. Sin. 1993, 9 (02), 211-217.
DOI: 10.3866/PKU.WHXB19930213
7848
Abstract/Metrics
4664
PDF(1768KB)
Studies on the Oscillation of
m
-C
6
H
4
(OH)
2
-KBrO
3
-H
2
SO
4
System
Gao Zhi-Di; Liu Jun-Li; Han De-Gang; Shen Shi-Gang; Wang An-Zhou
The oscillations of m-C_6H_4(OH)_2-KBrO_3-H_2SO_4 (system A) as well as m-C_6H_4(OH)_2-KBrO_3-H_2SO_4-MnSO_4(system B) h...
Acta Phys. -Chim. Sin. 1993, 9 (02), 218-223.
DOI: 10.3866/PKU.WHXB19930214
7715
Abstract/Metrics
3016
PDF(1171KB)
The Viscosity Behaviour of SEP Block Copolymer Solution During its Micellization
Zhou Wei-Ping; He Zhi-Duan; Zhang Hao; Zhang Hai-Bo
The viscosities of polystyrene-b-poly (ethylene/propylene) diblock copolymer in mixed solvent of n-octane and benzene we...
Acta Phys. -Chim. Sin. 1993, 9 (02), 224-228.
DOI: 10.3866/PKU.WHXB19930215
7116
Abstract/Metrics
2972
PDF(989KB)
Note
Effect of the Length of Alkane Skeleton on the Thermodynamic Function of Microemulsion with Nonionic Surfactant
Hao Ce; Sun Zhi-Gang; Chen Zong-Qi; Shi Cai-Yun
This paper reported the studies on the microemulsion of TritonX-100, hexanol, Water and alkane system. △G_(s→i)~0, the v...
Acta Phys. -Chim. Sin. 1993, 9 (02), 229-232.
DOI: 10.3866/PKU.WHXB19930216
7319
Abstract/Metrics
2765
PDF(718KB)
Studying on Stability of Emulsion Liquid Membrane with Moving Single Drop Method
Zhang He-Zhe; Bai Guang-Yue; Wang Yue-Jie; Yang Zhong
We detailed the stability of ELM with glutamic acid dialkyl esters as surfactants by moving single drop method. It is a ...
Acta Phys. -Chim. Sin. 1993, 9 (02), 233-237.
DOI: 10.3866/PKU.WHXB19930217
6884
Abstract/Metrics
3028
PDF(944KB)
A Study on UV and Visible Fluorescence Produced by Irmpd of Trimethyl Phosphite
Lu Qing-Zheng; Tao Li; Yu Shu-Qin; Kong Fan-Ao
IR multi-photon dissociation (IRMPD) of trimethyl phosphite has been carried out by a TEA CO_2 laser. The fluorescence s...
Acta Phys. -Chim. Sin. 1993, 9 (02), 238-241.
DOI: 10.3866/PKU.WHXB19930218
6310
Abstract/Metrics
2827
PDF(824KB)
Application of Pervaporation Membrane to Catalytic Esterification Reaction
Gao Zi; Yue Ying-Hong; Li Wen-Jun
Studies on pervaporation separation of alcohol/water mixture and pervaporation-aided catalytic esterification reaction h...
Acta Phys. -Chim. Sin. 1993, 9 (02), 242-246.
DOI: 10.3866/PKU.WHXB19930219
8053
Abstract/Metrics
3088
PDF(1005KB)
Quenching Rate Constants for Metastable Molecule CS(
α
3
П
)
Wang Hai-Qing; Gu Yue-Shu; Guo Jing-Zhong; Liu Chuan-Pu; Yin Yong-Jia; Cao De-Zhao
The metastable molecule CS(a~3Π) has been obtained, by the energy transfer reaction of He(2~3S) with CS_2 in a discharge...
Acta Phys. -Chim. Sin. 1993, 9 (02), 247-251.
DOI: 10.3866/PKU.WHXB19930220
6506
Abstract/Metrics
2771
PDF(1020KB)
Electronic Structure and Chemical Bond of Complex La(NO
3
)
3
·
bipy
·
2H
2
O
·
(B-15-C-5)
Dong Nan; Zhu Long-Guan; Wu Nian-Ci
The electronic structure and chemical bonds in La(NO_3)_3·bipy·2H_2O·(B-15-C-5) has been studied by INDO method. The res...
Acta Phys. -Chim. Sin. 1993, 9 (02), 252-255.
DOI: 10.3866/PKU.WHXB19930221
7127
Abstract/Metrics
2581
PDF(785KB)
Investigation on the Structure of Electronic Energy Bands of Polydiacetylenes
Zhang Qi-Yuan; Yan Ji-Min; Zhang Da-Ren
The influences of the side phenyls (PHs) on the electronic energy band-structure of polydiaeetylenes have been studied b...
Acta Phys. -Chim. Sin. 1993, 9 (02), 256-262.
DOI: 10.3866/PKU.WHXB19930222
6716
Abstract/Metrics
3468
PDF(1455KB)
Determination of the Activity Coefficients of TBP in
n
-Cetane by Cryoscopic Method
Chen Jin-Bang
The activity coefficients of TBP in n-cetane have been determined by cryoscopic method. This method is simpler, more rap...
Acta Phys. -Chim. Sin. 1993, 9 (02), 263-267.
DOI: 10.3866/PKU.WHXB19930223
6776
Abstract/Metrics
3045
PDF(929KB)
Study on the Ferrocene-Containing Ploynuculi Metal Complexes Quenching Luminescence of
*
[Cr(bpy)
3
]
3+
Xia Xu-Bing; Duan Chun-Ying; Zhu Long-Gen; Cao Hong; You Jing-Jing
Ferrocene-containing ploynuclear metal complexes M(Fe-C(CH_3)=N N=CSSR)_2 (M=Ni~(2+), Cu~(2+), Zn~(2+), Pd~(2+), Co~(2+)...
Acta Phys. -Chim. Sin. 1993, 9 (02), 268-272.
DOI: 10.3866/PKU.WHXB19930224
6523
Abstract/Metrics
3390
PDF(1049KB)
Spontaneous Oscillation of Electrical Potential Across Liquid Membrane
Wang Shou-Xiang; Qiu Zhi-Xin; Chen Sen; Gong Jian-Ping
An artificial membrane consisting of pricramic acid in nitrobenzene was used as an oil phase imposed between two aqueous...
Acta Phys. -Chim. Sin. 1993, 9 (02), 273-276.
DOI: 10.3866/PKU.WHXB19930225
5907
Abstract/Metrics
2962
PDF(755KB)
Photoelectrochemical Polymerization of Conducting Polymer Monomers
Chen Yan-Zhen; Gu Zhi-Jun; Tian Zhong-Qun
The photoelectrochemical polymerization process: monomer first polymerizes into low polymer and then the low polymer may...
Acta Phys. -Chim. Sin. 1993, 9 (02), 277-280.
DOI: 10.3866/PKU.WHXB19930226
7051
Abstract/Metrics
2980
PDF(800KB)