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Acta Phys. -Chim. Sin.
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中文
Current Issue
1991 Vol. 7, No. 02
Published online: 1991-04-15
Current column
ARTICLE
Note
Review
ARTICLE
A Molecular Orbital Study on the Mechanism for Homogenous Gas Phase Pyrolysis of Ethyl Acetamide
Xu Sen; Fu Xiao-Yuan
The homogenous gas phase pyrolysis of ethyl acetamide is studied by MINDO/3 molecular orbital method.The results show th...
Acta Phys. -Chim. Sin. 1991, 7 (02), 129-135.
DOI: 10.3866/PKU.WHXB19910201
5465
Abstract/Metrics
2754
PDF(5219KB)
The Crystal and Molecular Structure of
β
-Cyanoethyl-
α
-Ferrocenylhalogenbenzyl Ethers
Xin Min; Sun Xiao-Lin; Liu Qi-Wang; Hu Yu-Cai
We have reported the structure of β-cyanoethyf-a-ferrocenylfluorobenzyl ether. Present study is concerned with the cryst...
Acta Phys. -Chim. Sin. 1991, 7 (02), 136-139.
DOI: 10.3866/PKU.WHXB19910202
5482
Abstract/Metrics
2371
PDF(3237KB)
The H-F Force Method to Describe the MO'S Bonding Property
Du Qi-Shi; Du Lei
In the present investigation the theory and method to describe the MO's bonding ability with the Hellmann-Feynman electr...
Acta Phys. -Chim. Sin. 1991, 7 (02), 140-145.
DOI: 10.3866/PKU.WHXB19910203
6907
Abstract/Metrics
2831
PDF(4516KB)
Studies of Electropolymerized Polyortho-Aminophenol Film
Zhang Ai-Qiang; Chen Yan-Zhen; Tian Zhao-Wu
OAP can be electropolymerized into an uniform film of active POAP in acid solution. The films formed in different acid s...
Acta Phys. -Chim. Sin. 1991, 7 (02), 146-151.
DOI: 10.3866/PKU.WHXB19910204
5723
Abstract/Metrics
2586
PDF(3628KB)
Electrochemical Investigation of Liquid/Liquid Systems Using Various Organic Solvents
Yu Ze-Mu; Zhao Yu-Guang; Wang Er-Kang
The potential windows of the system water/pure solvent (W/P) and water/solvent mixtures(W/S) have been investigated by c...
Acta Phys. -Chim. Sin. 1991, 7 (02), 152-157.
DOI: 10.3866/PKU.WHXB19910205
6003
Abstract/Metrics
2680
PDF(4746KB)
The Studies of Poly-Ni(II) Film Electrode
Chen Yan-Zhen; Li Rong-Fen; Tian Zhao-Wu
Ni(Ⅱ) ion is complexed by poly-8-hydroxyquinoline, poly-0-aminophenol, poly-0-diaminobenzene and polyaniline as ligands....
Acta Phys. -Chim. Sin. 1991, 7 (02), 158-162.
DOI: 10.3866/PKU.WHXB19910206
5567
Abstract/Metrics
2509
PDF(4144KB)
Biofunctional Electrodes III. Study on Electrochemical Immobilization of Glucose Oxidase
Zheng Zhi-Min; Wu Hui-Huang; Zhou Shao-Min
By electrochemical polymerization of pyrrole in phosphate buffer, glucose oxidase (GOD) was entrapped in polypyrrole mat...
Acta Phys. -Chim. Sin. 1991, 7 (02), 163-168.
DOI: 10.3866/PKU.WHXB19910207
6505
Abstract/Metrics
2898
PDF(4900KB)
Determination of Thermodynamic Properties of Nitromethylaniline Isomers in SE-30 and SE-54 Stationary Phases by Capillary Gas Chromatography
Guan Zhen-Xi; Wang Zheng-Gang; Fu Ruo-Nong
A equation between the thermodynamic properties and the retention values of capillary gas chromatography was proposed. T...
Acta Phys. -Chim. Sin. 1991, 7 (02), 169-173.
DOI: 10.3866/PKU.WHXB19910208
5704
Abstract/Metrics
2430
PDF(4221KB)
Calculation of Energies and Band Structures of Polydiacetylenes
Cao Yang; Wang You-Liang; Chen Bo
In this paper, the total energies and band structures of polydiacetylenes(acetylenic structure and butatrienic structure...
Acta Phys. -Chim. Sin. 1991, 7 (02), 174-177.
DOI: 10.3866/PKU.WHXB19910209
5383
Abstract/Metrics
2685
PDF(3558KB)
The Steady State Electrochemical Behavior of Microdisk Electrodes
Liu Xiao-Ping; Lu Jun-Tao; Cha Quan-Xing
In this work, expressions for the steady state voltammetric curve of a microdisk electrode are derived by using "uniform...
Acta Phys. -Chim. Sin. 1991, 7 (02), 178-183.
DOI: 10.3866/PKU.WHXB19910210
5710
Abstract/Metrics
2572
PDF(4220KB)
Note
Study on the Briggs-Rauscher Type Oscillatary System Using Diacetone Alcohol as Organic Compound and Cerium (III) as Catalyst
Gong Hui-Hao; Wang Shou-Xiang; Xu Hai-Han
The oscillatary behavior of diacetone alcohol(DA)-KIO_3-H_2O_2-H_2SO_4-Ce~(3+) system has been studied.The system may os...
Acta Phys. -Chim. Sin. 1991, 7 (02), 184-190.
DOI: 10.3866/PKU.WHXB19910211
6120
Abstract/Metrics
2662
PDF(5285KB)
Crystal Structure and Molecular Mechanics Calculations of the Addition Product of Acetylacetone and Methyl 1-Naphthoate, C
17
H
18
O
4
Hu Sheng-Zhi; Chen Ming-Dan; Liu Xiao-Yun; Zhou Yuan-Lang
The structure of the product from the [2+2] photocycloaddition of acetylacetone to methyl 1-naphthoate was determined by...
Acta Phys. -Chim. Sin. 1991, 7 (02), 191-195.
DOI: 10.3866/PKU.WHXB19910212
6227
Abstract/Metrics
2631
PDF(3348KB)
Crystal Structure and Molecular Mechanics Calculations of the Photodimerization Product of Acetylacetone, C
10
H
16
O
4
Hu Sheng-Zhi; Huang Ming-Sheng; Cheng Xian-En; Zhou Yuan-Lang
The structure of the product from photodimerization in non-polar solvent of acetylacetone, C_(10)H_(16)O_4, Mr=200.2, wa...
Acta Phys. -Chim. Sin. 1991, 7 (02), 196-201.
DOI: 10.3866/PKU.WHXB19910213
5884
Abstract/Metrics
2651
PDF(3673KB)
A Fractal Study on the Dspersing Processes on the Surface
Guo Guo-Lin; Chen Yue-Hua; Tang You-Qi
The concept of fractal was applied to interpret the surface of porous solids and the processes proceeded on them. The fr...
Acta Phys. -Chim. Sin. 1991, 7 (02), 202-206.
DOI: 10.3866/PKU.WHXB19910214
4639
Abstract/Metrics
2441
PDF(3725KB)
Energy Transfer Processes in Reaction Between Metastable Atoms Ar,He and Ne with CCl
4
and CBr
4
Guo Jing-Zhong; Gu Yue-Zhu; Liu Chuan-Pu; Yin Yong-Jia; Cao De-Zhao; Liao Chang-Huan
In this paper we used the flowing-afterglow technique to study the energy transfer processes in the reaction of metastab...
Acta Phys. -Chim. Sin. 1991, 7 (02), 207-210.
DOI: 10.3866/PKU.WHXB19910215
6052
Abstract/Metrics
2942
PDF(2946KB)
Study on the Structure Defect of Electrodeposited Tin Using Positron Annihilation Lifetime Spectroscopy
Guo Jing-Zhong; Gu Yue-Shu; Liu Chuan-Pu; Li Bao-Zhong; Yin Yong-Jia; Cai Ji-Ye; Cao De-Zhao
The excited fragments CH(A), CH(B), CH(C) etc. were produced by the bombardment of He(2~3S) with CH_nX_(4-n)(X=Cl, Br, I...
Acta Phys. -Chim. Sin. 1991, 7 (02), 211-214.
DOI: 10.3866/PKU.WHXB19910216
5683
Abstract/Metrics
1763
PDF(753KB)
STUDY ON THE STRUCTURE DEFECT OF ELECTRODEPOSITED TIN USING POSITRON ANNIHILATION LIFETIME SPECTROSCOPY
Yao Shi-Bing; Liu Zan-Jin; Zhou Shao-Min; Fang Jiang-Ling
The structure defect of electrodeposited tin was investigated by means of positron annihilation lifetime spectroscopy. I...
Acta Phys. -Chim. Sin. 1991, 7 (02), 215-218.
DOI: 10.3866/PKU.WHXB19910217
4579
Abstract/Metrics
1607
PDF(674KB)
Investigation of Fast Atom Bombardment Mass Spectrometry of Arenediazonium Salts/Mechanism of Their Quasi-Molecular Ions
Bian Ze-Liang; Zhang Qi-Yuan; Sun Xiang-Yu; Zhao Yao-Xing
Fast atom bombardment mass spectra of a series of arenediazonium salts with various substituents complexed with 18-crown...
Acta Phys. -Chim. Sin. 1991, 7 (02), 219-222.
DOI: 10.3866/PKU.WHXB19910218
5461
Abstract/Metrics
1957
PDF(770KB)
Crystal and Molecular Structures and MS Analyse of
β
-Carboxylethyl (or α-methylethyl) Germanium Trichlorides
Shangguan Guo-Qiang; Zhang Shu-Gong; Jin Zhong-Sheng; Liu Shu-Ying; Ni Jia-Zuan
This paper reports the results of the crystal and molecular structures, CI-MS and FAB-MS analyse of Cl_3GeCH_2CH_2COOH a...
Acta Phys. -Chim. Sin. 1991, 7 (02), 223-226.
DOI: 10.3866/PKU.WHXB19910219
5734
Abstract/Metrics
2768
PDF(2937KB)
Study of the Chlorination Reaction of Li
2
CO
3
with NH
4
Cl
Zhang Ying-Shan; Zhao Min-Shou; Tang Ding-Xiang
The chlorination reaction of Li_2CO_3 with NH_4Cl has been studied in detail by a series of thermal analysis methods. Wh...
Acta Phys. -Chim. Sin. 1991, 7 (02), 227-230.
DOI: 10.3866/PKU.WHXB19910220
5837
Abstract/Metrics
2921
PDF(2905KB)
Theoretical Study on the Rearrangement of H
2
NOH to H
3
NO
Han Yun-Zhu; Zhu De-Zhong; Zhao Cheng-Da
The isomerization reaction of hydroxylamine H_2NOH rearrangement to ammonia oxide H_3NO was investigated by ab initio MO...
Acta Phys. -Chim. Sin. 1991, 7 (02), 231-233.
DOI: 10.3866/PKU.WHXB19910221
5613
Abstract/Metrics
2906
PDF(2322KB)
Studies of XPS Satellite Peaks and its Valence Band Spectra of the Pyridoygen Complexes of Rare Earth Decahydro-Decaborate
Wang Dian-Xun; Li Er-Cheng; Xu Guang-Zhi; Zhang Lun
XPS inner shell. satellite peaks and its valence band spectra of the pyridoxygen complexes of rare earth decahydrodecabo...
Acta Phys. -Chim. Sin. 1991, 7 (02), 234-237.
DOI: 10.3866/PKU.WHXB19910222
6603
Abstract/Metrics
2907
PDF(2687KB)
A Study of Photoelectrochemical Properties of Thin Film of Chromium Tetra-2,3-Pyridinoporphyrazine
Yang Mai-Zhi; Marc DE Backer
Photocurrent spectra and photoluminescence measurements of the electrode covered by a thin film of chromium tetra-2,3-py...
Acta Phys. -Chim. Sin. 1991, 7 (02), 238-241.
DOI: 10.3866/PKU.WHXB19910223
5372
Abstract/Metrics
3154
PDF(3378KB)
An
Ab initio
Study of Penetrating and Screening Effects
Pan Dao-Ai; Liao Meng-Sheng; Sun Wan-Chang; Gao Jian-Nan; Shi Qing-Nian
On basis of ab initio quantum chemical calculations formulas for calculating screening constants σ_(ji) and orbital radi...
Acta Phys. -Chim. Sin. 1991, 7 (02), 242-245.
DOI: 10.3866/PKU.WHXB19910224
6370
Abstract/Metrics
3130
PDF(2996KB)