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Acta Phys. -Chim. Sin.
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中文
Current Issue
1990 Vol. 6, No. 05
Published online: 1990-10-15
Current column
Communication
ARTICLE
Note
Communication
Free Energy Change of the Micellization of Surfactants——An Evidence of Self-Coiling Conformation of the Surfactant HC-Chain
Zhao Guo-Xi; Zhu Bu-Yao
Acta Phys. -Chim. Sin. 1990, 6 (05), 513-516.
DOI: 10.3866/PKU.WHXB19900501
4936
Abstract/Metrics
2600
PDF(2463KB)
Mass Spectrometry and Structure Studies of C
90-150
+
Li Wen-Ying; Zhuang Ma-Zhan; Huang Rong-Bin; Ding Shao-Ping; Zheng Lan-Sun
It was proposed that all carbon clusters with n>30 have geometrically closed cage structures. The mass spectrum of C_(92...
Acta Phys. -Chim. Sin. 1990, 6 (05), 517-518.
DOI: 10.3866/PKU.WHXB19900502
4364
Abstract/Metrics
2298
PDF(1825KB)
Effects of High Valence Cations Doped on the Phase Formation and the Crstal Structure in the Bi(Pb)-Sr-Ca-Cu-O System
Chen Feng-Xiang; Zhu Wen-Jie; Li Neng; Lin Bing-Xiong; Tang You-Qi; Feng Qing-Rong; Wu Ke; Xue Li-Xin; Zhong Shan-Jin; He Jun
The effects of high valence cations M~(n+) (n≥4) doped on the phase formation and the structure stability have been inve...
Acta Phys. -Chim. Sin. 1990, 6 (05), 519-522.
DOI: 10.3866/PKU.WHXB19900503
4755
Abstract/Metrics
2325
PDF(2763KB)
ARTICLE
Electrochemical Reduction of 3-Nitro-Benzoic Acid in DMSO Media
Wu Zhong-Da; Zhao Ming; Jiao Yang-Yang
The electrochemical reduction of 3-nitro-benzoic acid (3-NBA) has been investi-gated on Pt electrode in DMSO media by cy...
Acta Phys. -Chim. Sin. 1990, 6 (05), 523-527.
DOI: 10.3866/PKU.WHXB19900504
5206
Abstract/Metrics
2464
PDF(3406KB)
On The Dielectric Properties of Several Solid Oxide/Water Vapour Systems
Cheng Hu-Min; Wu Ai-Yin; Gu Ti-Ren
The dielectric isotherms and the dielectric absorption curves of MgO, CaO, Ca(OH)_2 and TiO_2 have been measured at freq...
Acta Phys. -Chim. Sin. 1990, 6 (05), 528-533.
DOI: 10.3866/PKU.WHXB19900505
4811
Abstract/Metrics
2603
PDF(5145KB)
The Electronic Energy Transfer Between
12
CO(
A
1
Π
) and
13
CO(
X
1
∑
+
) Studied by Rempi Spectroscopy
He Jin-Bao; Sha Guo-He; Zhang Xiao-Yuan; Bai Ji-Ling; Zhang Cun-Hao
The energy transfer processes between ~(12)CO(A~1Π) and ~(13)CO(X ~1Σ~+) were studied at 77 K by using the technique of ...
Acta Phys. -Chim. Sin. 1990, 6 (05), 534-540.
DOI: 10.3866/PKU.WHXB19900506
4905
Abstract/Metrics
2539
PDF(5612KB)
The Vibrational Spectra and Normal Coordinate Treatment on Lanthanide-Chelate Compounds with Dibenzoylmethane
Zhang Jian-Hua; Liang Ying-Qiu
In this paper, FT-IR and Raman spectra of Lanthanide-Dibenzoylmethanate chelate compounds were reported. A normal coordi...
Acta Phys. -Chim. Sin. 1990, 6 (05), 541-548.
DOI: 10.3866/PKU.WHXB19900507
4825
Abstract/Metrics
2294
PDF(5085KB)
Salting Effect of Polar Organic Compound in Electrolyte Solutions(II) An Application of Pitzer Equations in D2EGPA-Alkali Chloride-H
2
O Systems
Lu Jiu-Fang; Niu Shu-Fang; Li Yi-Gui
In this paper, the Pitzer equation (1973) and Pitzer-Li equation (1983) are used to correlate the activity coefficient d...
Acta Phys. -Chim. Sin. 1990, 6 (05), 549-555.
DOI: 10.3866/PKU.WHXB19900508
4840
Abstract/Metrics
2411
PDF(4734KB)
Synthesis and Crystal Structure of Nickel (II) Complex with BIS-Schiff Bases From Picoli-naldehyde N-Oxide and 1,2-Propanediamine
Zhou Zhong-Yuan; Yin Zhan-Feng; Zang Yan; Wang Guo-Xiong; Zeng Cheng; Dai An-Bang
A new nickel (II) complex with bis-schiff bases from picolinaldehyde N-oxide and 1,2-propanediamine, [Ni (piopn) (H_2O)_...
Acta Phys. -Chim. Sin. 1990, 6 (05), 556-561.
DOI: 10.3866/PKU.WHXB19900509
5300
Abstract/Metrics
2366
PDF(3788KB)
Structural Prediction on the Anti-lipolytic Polypeptide of Ginseng
Zhang Fu-Gui; Zhu Min-Hui; Wang Da-Wei; Zhang Jin; Zhang Hong-Ying
In this paper, the structure of the anti-lipolytic 14 peptides of Ginseng was studied. Based on the primary structure, t...
Acta Phys. -Chim. Sin. 1990, 6 (05), 562-567.
DOI: 10.3866/PKU.WHXB19900510
5110
Abstract/Metrics
2403
PDF(4858KB)
Statistical Mechanical Treatment of Absorbed Monolayer at Electrode/Solution Interface I. The Inner-layer Differential Capacity for Mercury Electrode in Non-aqueous Solution
Su Wen-Duan; Zhou Xiao-Lin
A model of dipole orientation distribution for solvate layer at electrode/solution interface was suggested, and based on...
Acta Phys. -Chim. Sin. 1990, 6 (05), 568-574.
DOI: 10.3866/PKU.WHXB19900511
4564
Abstract/Metrics
2432
PDF(4920KB)
Statistical Mechanical Treatment of Absorbed Monolayer at Electrode/Solution Interface II. The Inner-Layer Differential Capacity of Hg/Aqueous Solution Interface
Su Wen-Duan; Zhou Xiao-Lin
Based on the model presented in part I of this work, the inner capacity depen-dence on surface charge was estimated for ...
Acta Phys. -Chim. Sin. 1990, 6 (05), 575-579.
DOI: 10.3866/PKU.WHXB19900512
4421
Abstract/Metrics
2336
PDF(3329KB)
Coordination Field Analysis of the Fluorescence Spectra of Eu
3+
and Tb
3+
Doped in LnOX Matrixes
Yang Pin; Li Si-Dian; Wang Yue-Kui
Based on Double Sphere Coordination Point Charge Field (DSCPCF) model, the coordination field perturbation energy levels...
Acta Phys. -Chim. Sin. 1990, 6 (05), 580-588.
DOI: 10.3866/PKU.WHXB19900513
5328
Abstract/Metrics
2521
PDF(6769KB)
A Study on DC-Conductivity of Potassium Acid Phthalate (KAP) Single Crystals
Shi Zi-Kang; Liang Gui-Jin
Based on the study of DC-conductivity of KAP gingle crystal along three axial directions, the conductivity mechnism have...
Acta Phys. -Chim. Sin. 1990, 6 (05), 589-593.
DOI: 10.3866/PKU.WHXB19900514
4821
Abstract/Metrics
2295
PDF(4220KB)
Study of Kinetics and Mechanism for The Reaction Between Molybdenum(v) Tetraphenylporphyrine (Mo
v
O(TPP)Cl) and Dimethyl Sulfoxide (DMSO)
Yang Hui-Xing; Cui Xiao-Li; Lu Qun; Han De-Gang
The kinetics of the reaction of MovO(TPP)Cl and DMSO has been studied with a stopped-flow spectrophotometer. The results...
Acta Phys. -Chim. Sin. 1990, 6 (05), 594-600.
DOI: 10.3866/PKU.WHXB19900515
4427
Abstract/Metrics
2510
PDF(5224KB)
Note
Photophysical Research on Organic Compounds
Chen Feng-Qi; Yu Qun; Guo Yan; Fan Mei-Gong
The transient processes of pyrene (Py) have been studied by measuring fluores-cence lifetime and nanosecond time-resolve...
Acta Phys. -Chim. Sin. 1990, 6 (05), 601-604.
DOI: 10.3866/PKU.WHXB19900516
5061
Abstract/Metrics
2753
PDF(3393KB)
The Velocity Autocorrelation Function and the Spectral Density of LiCl Calculated by Molecular Dynamics Method
Xu Hua; Shao Jun; Tang Zheng-Quan
The velocity autocorrelation function and the spectral density of LiCL melt and LiCL glass have been calculated based on...
Acta Phys. -Chim. Sin. 1990, 6 (05), 605-608.
DOI: 10.3866/PKU.WHXB19900517
4869
Abstract/Metrics
2404
PDF(2517KB)
Study on the Oscillating Reaction in Glucose-BrO
-
3
-Mn
2+
-H
2
SO
4
-Acetone System
Li He-Xing; Liu Min; Wang Shou-Xiang; Xu Hai-Han; Fu Chu-Jin
A new oscillating system of glucose(Glu)-BrO_3~--acetone(Act)-H_2SO_4-Mn~(2+) has been reported. In this homogeneous Bel...
Acta Phys. -Chim. Sin. 1990, 6 (05), 609-612.
DOI: 10.3866/PKU.WHXB19900518
4370
Abstract/Metrics
2481
PDF(2928KB)
The Electrochemical and Magnetic Properties of Poly-
o
-Methylaniline
Mu Shao-Lin; Sun Dong-Hao; Shi Yu-Jun
The changes in potentials and pH values of the solution gave rise to variations of colour and electronic absorption spec...
Acta Phys. -Chim. Sin. 1990, 6 (05), 613-617.
DOI: 10.3866/PKU.WHXB19900519
4502
Abstract/Metrics
2488
PDF(3705KB)
Properties and Electronic Structures of Cluster [Mo
4
O
4
Cl
2
(
μ
3
-O)
2
(
o
-CH
3
C
6
H
4
COO)
6
]
Guo Chun-Xiao; Huang Chun-Jun; Sun Chun-Ting; Zhang Heng-Bin; Liu Xiao-Xun; Yang Fan; Dong Gang
UV spectra, IR spectra, Electronic oxidation-reduction properties and XPS spectrum of the tetramolybdenum cluster Mo_4O_...
Acta Phys. -Chim. Sin. 1990, 6 (05), 618-621.
DOI: 10.3866/PKU.WHXB19900520
4774
Abstract/Metrics
2410
PDF(3091KB)
Research on the Waterproof Gas-Diffusion Electrode of Tungsten Carbide
Ma Chun-An; Yang Zu-Wang; Zhou Yun-Hong; Zha Quan-Xing
A gas-diffusion electrode of WC was made by active WC powder, PTFE with some additives. The influences of the electro-ca...
Acta Phys. -Chim. Sin. 1990, 6 (05), 622-628.
DOI: 10.3866/PKU.WHXB19900521
4892
Abstract/Metrics
2831
PDF(5630KB)
XPS Insvestigation of Hydrogen Bond in Hydroxyapatite
Zhou Jian-Lue; Chen Shu-Zi; Zuo Chang-Ming; Ji Xiao-Jiang
Several calcium orthophosphates (tricalcium phosphate, monocalcium dihydropho-sphate, dicalcium hydrophosphate, and hydr...
Acta Phys. -Chim. Sin. 1990, 6 (05), 629-632.
DOI: 10.3866/PKU.WHXB19900522
6943
Abstract/Metrics
2989
PDF(3323KB)
The Activity Coefficients and Osmotic Coefficients of Sodium Tungstate in Aqueous Solution
Wu Ding-Quan; Xu Zheng-Liang; Qu Song-Sheng
The activity coefficients and osmotic coefficients of Na_2WO_4 aqueous solution in the concentration range of 0.3--2.5 m...
Acta Phys. -Chim. Sin. 1990, 6 (05), 633-637.
DOI: 10.3866/PKU.WHXB19900523
5044
Abstract/Metrics
2356
PDF(2991KB)
A Study of the Transient Ring Currents of the Rrde As
n
-InP Disc Irradiated with a Light Step
Qian Dao-Sun; Cai Dong-Chen; Shen Tian-Jing
The transient ring currents of the RRDE n-InP semiconductor disk-gold ring irradiated with a light step from dark to 25 ...
Acta Phys. -Chim. Sin. 1990, 6 (05), 638-640.
DOI: 10.3866/PKU.WHXB19900524
4337
Abstract/Metrics
2248
PDF(2247KB)