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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
1989 Vol. 5, No. 01
Published online: 1989-02-15
Current column
Communication
ARTICLE
Note
Communication
Resonance Enhance Multiphoton Ionization Spectra of OCS Molecule in the 277-285 nm Wavelength Region
Zheng Cheng-Fa;Liu yong;Yu Yong;Zheng Qi-Ke
The first observation of the REMPI spectra of OCS molecule in the region of 277—285 nm is reported. The laser source is ...
Acta Phys. -Chim. Sin. 1989, 5 (01), 1-2.
DOI: 10.3866/PKU.WHXB19890101
4583
Abstract/Metrics
2174
PDF(1916KB)
Computer System for Scanning Tunneling Microscope
Bai Chun-Li;Dai Chang-Chun;Huang Gui-Zhen;Chen Zeng-Bo;Liu Jie-San;Fu Heng
The scanning tunneling microscope (STM)is a powerful instrument which provide surface topographic images down to the ato...
Acta Phys. -Chim. Sin. 1989, 5 (01), 3-6.
DOI: 10.3866/PKU.WHXB19890102
5301
Abstract/Metrics
2352
PDF(3029KB)
The Structure and Phase Transition of Li
0.025
Na
0.975
NbO
3
Yang Qing-Chuan;Tang You-Qi;Zhong Wei-Lie;Chen Huan-Chu
Li_(0.025)Na_(0.975)NbO_3 undergoes a ferroelectric-ferroelectric phase transition at 180K (on cooling) or 260 K (on hea...
Acta Phys. -Chim. Sin. 1989, 5 (01), 7-9.
DOI: 10.3866/PKU.WHXB19890103
4329
Abstract/Metrics
2297
PDF(2523KB)
ARTICLE
Analysis of Axially Symmetric Molecular Tumbling and Methyl Internal Rotation Rates of Morphine by
13
C Spin-Lattice Relaxation Time
T
1
Wang Dehua; Levy,George C.
~(13)C relaxation parameters of morphine in solution were measured at 90.1 and 62.9 MHz. An axially symmetric rotational...
Acta Phys. -Chim. Sin. 1989, 5 (01), 10-14.
DOI: 10.3866/PKU.WHXB19890104
4813
Abstract/Metrics
2263
PDF(3676KB)
Theoretical Study on Bonding in the Complex [Co(H
2
O)
4
(NCS)
2
]
·
(18-C-6)
Cai Zhengting;Guan Daren;Deng Conghao;Fan Yuepeng;Zhang Ruiqin
The molecular and crystal structure of the new compound [Co(H_2O)_4(NCS)_2]_2. (18-Crown-6) has been reported in a preio...
Acta Phys. -Chim. Sin. 1989, 5 (01), 15-19.
DOI: 10.3866/PKU.WHXB19890105
4721
Abstract/Metrics
2481
PDF(4217KB)
Study on Synergistic Extracted Complex——The Synthesis, Characterizaton and Crystal Structure of Bis (1-Pnenyl-3-Methyl-4-Trifluoroacetyl-Pyrazolone-5)Mono (1,10-Phenanthroline) Cobalt (II)
Wang Ke-Zhi;Huang Chun-Hui;Weng Shi-Fu;Xu Guang-Xian;Han Yu-Zhen;He Cun-Heng;Zheng Qi-Tai
A synergistic extracted complex of bis-(1-phenyl-3-methyl-4-trifluoroacetylpyrazolone-5) mono (1,10-phenanthroline) eoba...
Acta Phys. -Chim. Sin. 1989, 5 (01), 20-26.
DOI: 10.3866/PKU.WHXB19890106
4512
Abstract/Metrics
2276
PDF(5185KB)
THE CRYSTAL AND ELECTRONIC STRUCTURE OF [Cu
2
(C
6
H
4
(COO) (CONHC
6
H
4
CH
3
))
4
(DMF)
2
]·4DMF
Yu Xiufen; Huang Zhongle; Sun Qionli Cong Aizhen Huang Xin
The title compound is synthesized and crystallized in the monoclinic system; space group P1, a=1.0761(2), b=1.3930(4), c...
Acta Phys. -Chim. Sin. 1989, 5 (01), 27-32.
DOI: 10.3866/PKU.WHXB19890107
4137
Abstract/Metrics
2097
PDF(2286KB)
Investigation of Microstructure at Iron Tetraphenylporphyrin Modified Glassy Carbon Electroed by XPS
Hu Gang;Xu Li-Juan;Yu Ya-Li;Dong Shao-Jun
Microstructure of the glassy carbon surface modified with iron tetraphenyfporphyrin (FeTPP) by heat treatment has been s...
Acta Phys. -Chim. Sin. 1989, 5 (01), 33-37.
DOI: 10.3866/PKU.WHXB19890108
4797
Abstract/Metrics
2290
PDF(4217KB)
Role of Carriers in the Selective Hydrogenation of Cyclopentadiene Over Supported Palladium Catalysts
Zhang Shu-Lin;Xu Jun;Liao Shi-Jian;Yu Dao-Rong;Zhang Yi-Ping
Several supported palladium catalysts were prepared and thier effects on the kinetic behaviors in the selective hydrogen...
Acta Phys. -Chim. Sin. 1989, 5 (01), 38-43.
DOI: 10.3866/PKU.WHXB19890109
5171
Abstract/Metrics
2324
PDF(4655KB)
Study of the Effects of Stirring on Belousov-Zhabotinskii Osciliating Reaction and its Mechanism
Li Jing;Li Ru-Sheng
The effects of stirring on the oscillations of the ferrion-catalyzed and ceriumcatalyzed B-Z reactions are investigated ...
Acta Phys. -Chim. Sin. 1989, 5 (01), 44-49.
DOI: 10.3866/PKU.WHXB19890110
4285
Abstract/Metrics
2384
PDF(5270KB)
The Band Structures and Electric Properties of the Chargetransfer Complexes 1-N-Methyl-Cinnoline TCNQ
2
and 2-N-Methyl-Cinnoline TCNQ
2
Qian Min-Xie;Shi Yan-Yang;Fu Heng;Tang You-Qi;Xu Xiao-Jie
The band structures of two isomeric complexes 1-N-Mci TCNQ_2 and 2-N-Mci TCNQ_2 are calculated with the tight-binding ap...
Acta Phys. -Chim. Sin. 1989, 5 (01), 50-55.
DOI: 10.3866/PKU.WHXB19890111
4468
Abstract/Metrics
2169
PDF(4159KB)
A Molecular Mechanics Study of Steric Effect of Substituents on Extraction of Metals by Acidic Phosphorus Esters
Li Shu-Sen;Yuan Cheng-Ye
The molecular mechanics calculations (Allinger's MM2 program) was used to study the steric effect of substituents on ext...
Acta Phys. -Chim. Sin. 1989, 5 (01), 56-61.
DOI: 10.3866/PKU.WHXB19890112
4915
Abstract/Metrics
2229
PDF(4883KB)
Thermodynamic Study of the Phase Transitions of the Mesogen H
p
BAB and the Homologous Trend of the Melting Entropies
Wang Bang-Ning;Tan Fu
The phase transitions of N-(p-n-heptyloxybenzylidene)-p'-aminobenzonitrile (H_pBAB) were studied at various rates within...
Acta Phys. -Chim. Sin. 1989, 5 (01), 62-66.
DOI: 10.3866/PKU.WHXB19890113
4278
Abstract/Metrics
2203
PDF(4487KB)
Infrared Laser Induced SF
6
Interaction with Silicon and Tungstun Surfaces
He Zhi-Fang;Jin Zhong-Kao;Qin Qi-Zong
TEA CO_2 laser induced Si-SF_6 and W-SF_8 interactions have been studied and the surface reaction yields have been deter...
Acta Phys. -Chim. Sin. 1989, 5 (01), 67-71.
DOI: 10.3866/PKU.WHXB19890114
4902
Abstract/Metrics
2179
PDF(4062KB)
Studies on the Vapor-Liquid Equilibrium and Properties of Physical Chemistry in Liquid Phase for the Ternary System Li
2
SO
4
-EtOH-H
2
O at 25℃
Pan Huan-Quan;Xia Shu-Ping;Gao Shi-Yang
In this paper, the solubilities, viscosities, densities and vapor-liquid equilibrium were studied for the ternary system...
Acta Phys. -Chim. Sin. 1989, 5 (01), 72-75.
DOI: 10.3866/PKU.WHXB19890115
4836
Abstract/Metrics
2174
PDF(3161KB)
Sestem Trial and Error Method for Crystal Structure Determination
Hou Yong-Geng;Chen Zhi-Fang;Fu Heng
The system trial and error method (STEM) for crystal structure determination is a systematical method. It is different f...
Acta Phys. -Chim. Sin. 1989, 5 (01), 76-80.
DOI: 10.3866/PKU.WHXB19890116
5152
Abstract/Metrics
2140
PDF(4232KB)
Theory of Kinetics and Equilibrium of Ion Exchange-Adsorption and Mechanism of Extracting Uranium From Sea-Water with Titanic Gel
Ai Hong-Tao;Chen Song;Tao Zu-Yi;Lin Zi-Huang
An isothermal equation for ion exchange-adsorption is derived by mass action law. The equation can be used to sum up emp...
Acta Phys. -Chim. Sin. 1989, 5 (01), 81-86.
DOI: 10.3866/PKU.WHXB19890117
5415
Abstract/Metrics
2508
PDF(5032KB)
Note
Dispersion of Metallic Nickel on the ZSM-5 Zeolites
Xiao Shu-Yong;Meng Zhong-Yue
The morphology, size distribution and crystallography of supported nickel on ZSM-5 zeolites have been studied by electro...
Acta Phys. -Chim. Sin. 1989, 5 (01), 87-90.
DOI: 10.3866/PKU.WHXB19890118
4632
Abstract/Metrics
2316
PDF(3185KB)
Studies of FT-IR-PAS Spectra of Polyphenylene Sulfide
Zhang Gui-Zhong;Li Zeng-Fa;Zhang Guang-Yin;Zeng Han-Min
This paper presented the Mid-IR photoacoustic spectra of polyphenylene sulfide (PPS) which was first measured by us and ...
Acta Phys. -Chim. Sin. 1989, 5 (01), 91-94.
DOI: 10.3866/PKU.WHXB19890119
5536
Abstract/Metrics
2722
PDF(2508KB)
Studies on Thermochemistry of Porphyrins III.The Stndard Energies of Combustion and Standard Enthalpies of Formation of Tetranitrophenylporphyrin and Tetrapyridinylporphyrin
Gu Chun-Gang;Wu Ding-Quan;Qu Song-Sheng
Using a precision static oxygen-bomb calorimeter, the standard energies of combustion at 298.15K of tetra-(p-nitrophenyl...
Acta Phys. -Chim. Sin. 1989, 5 (01), 95-98.
DOI: 10.3866/PKU.WHXB19890120
4764
Abstract/Metrics
2336
PDF(3233KB)
Adsorption Thermodynamics of Microporous Aluminophosphate AlPO
4
-11
Yan Ai-Zhen;Zhou Li-Rong;Xu Qin-Hua
The adsorption properties of molecules with different polarizabilities, benzene, cyclohexane, n-hexane and water, on alu...
Acta Phys. -Chim. Sin. 1989, 5 (01), 99-102.
DOI: 10.3866/PKU.WHXB19890121
3678
Abstract/Metrics
2307
PDF(3404KB)
Studies on the Mechanism of Mg Electrodeposition in DMF
Zhang Wen-Zhi;Xu Da-Feng;Wu Xi-Zun
The characteristics of Mg electrodeposition on Pt in DMF have been investigated by means of cyclic voltammetry and rotat...
Acta Phys. -Chim. Sin. 1989, 5 (01), 103-106.
DOI: 10.3866/PKU.WHXB19890122
4224
Abstract/Metrics
2562
PDF(2922KB)
How to Specify Origin and Enantiamorph with General Reflections
Hou Yong-Kang;Fu Heng
For non-centrosymmetric crystal structures, it is usually uses as many specila refletions as possible to define origin a...
Acta Phys. -Chim. Sin. 1989, 5 (01), 107-109.
DOI: 10.3866/PKU.WHXB19890123
4412
Abstract/Metrics
2230
PDF(2494KB)