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Acta Phys. -Chim. Sin.
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中文
Current Issue
1988 Vol. 4, No. 03
Published online: 1988-06-15
Current column
Communication
ARTICLE
Note
Communication
LASER PHOTOFRAGMENTATION OF CH
3
SSCH
3
AT 248 nm
Peng Bo; Cao Jianru*; Wen Ye; Zhong Xian; Zhang Jianming; Gu Haogang; Fang Wanguan; Wu Xiaojun; Zhu Qihe
Photofragmentation of CH_3SSCH_3 at 248nm was studied by using rotatable pulsed molecular beam crossed with excimer lase...
Acta Phys. -Chim. Sin. 1988, 4 (03), 225-228.
DOI: 10.3866/PKU.WHXB19880301
5038
Abstract/Metrics
2319
PDF(1489KB)
THE THERMOSTABILITY OF OXYGEN ATOMS AT DIFFERENT SITES IN THE CRYSTAL LATTICE OF HIGH-
T
C
SUPERCONDUCTOR Ba
2
YCu
3
O
6.92
Zhou Qinwei; Jiang Anren; Xie Quangen; Peng Ying; Liu Dingjiang; Deng Jingfa*
Studies on high-T_c superconductor Ba_2YCu_3O_(6.92) using thermogravimetry, temperature programmed decomposition, oxyge...
Acta Phys. -Chim. Sin. 1988, 4 (03), 229-233.
DOI: 10.3866/PKU.WHXB19880302
4653
Abstract/Metrics
2200
PDF(2007KB)
FORMATION MECHANISM OF HIGH
T
C
SUPERCONDUTING PHASE YBa
2
Cu
3
O
7-
δ
Tang Youqi; Zhang Yufen*; Zheng Xiangmiao; Wei Chengquian; Lin Bingxiong
The Y-Ba-Cu mixed oxide system is obtained when any kinds of materials containing Y, Ba, Cu are heated at 850 ℃. when he...
Acta Phys. -Chim. Sin. 1988, 4 (03), 234-238.
DOI: 10.3866/PKU.WHXB19880303
5168
Abstract/Metrics
2091
PDF(1794KB)
PREPARATION AND STRUCTURAL STUDY OF HIGH
T
C
SUPERCONDUTING PHASE LaBa
2
Cu
3
O
7-
δ
Zhang Yufen*; Zheng Xiangmiao; Zhu Wenjie; Lin Bingxiong; Tang Youqi
A stable orthorhombic superconduting phase LaBa_2Cu_3O_(7-δ), with T_c 82K and Meissner effect 13.6%, has been prepared ...
Acta Phys. -Chim. Sin. 1988, 4 (03), 239-243.
DOI: 10.3866/PKU.WHXB19880304
4428
Abstract/Metrics
2150
PDF(1825KB)
ARTICLE
DYNAMIC
1
H NMR STUDIES OF SOLVENT EFFECT FOR BENZO-AZACROWN-ETHERS IN CDCl
3
SOLUTIONS
Zeng Jingcheng*; Shen Lianfang;
Lu Tianbao; Wu Chengtai
The influences (Dilution Shift Effect) of sample concentration on ~1H NMR spectra and spin-lattice relaxation times in b...
Acta Phys. -Chim. Sin. 1988, 4 (03), 244-249.
DOI: 10.3866/PKU.WHXB19880305
5583
Abstract/Metrics
2484
PDF(2106KB)
NMR STUDY OF THE ADSORPTION OF HYDROCARBONS ON SEVERAL TYPICAL NATIVE CHARCOALS Ⅱ.
1
H NMR Study of Adsorbed Benzene, Cyclohexane,
n
-Pentane and
n
-Hexane
Du Youru*; Shen Lianfang; Kong Yuhua; Hu Aiguo
Adsorption and desorption of benzene, cyclohexane, n-pentane and n-hexane on four native charcoals were measured. The ad...
Acta Phys. -Chim. Sin. 1988, 4 (03), 250-255.
DOI: 10.3866/PKU.WHXB19880306
6292
Abstract/Metrics
2431
PDF(2097KB)
THE REACTION CHANNELS AND FRAGMENT ENERGY DISTRIBUTIONS OF THE LASER PHOTOFRAGMENTATION OF C
2
H
5
I
Cao Jianru*; Wen Ye; Zhang Jianming; Qu Haogang; Zhong Xian; Fang Wanquan; Wu Xiaojun; Zhu Qihe
The translational and internal energy distributions of the photofragments for the processes C_2H_5I→C_2H_5+I~*(~2p_(1/2)...
Acta Phys. -Chim. Sin. 1988, 4 (03), 256-261.
DOI: 10.3866/PKU.WHXB19880307
4581
Abstract/Metrics
2240
PDF(2303KB)
STUDIED ON THE SYNTHESIS OF ETHANOL FROM CO HYDROGENATION WITH THE TRANSIENT RESPONSE TECHNIQUE——ADSORPTIVE CHARACTERISTICS OF H
2
AND CO ON THE MODIFIED Rh/Al
2
O
3
CATALYSTS
Lu Yun; Liu Danchu*; Zheng Shengan
Quadrupole mass spectrometer was used in the transient response technique as an analytical tool. With this technique the...
Acta Phys. -Chim. Sin. 1988, 4 (03), 262-266.
DOI: 10.3866/PKU.WHXB19880308
4624
Abstract/Metrics
2469
PDF(1870KB)
THE STUDY OF STRUCTURE AND PHASE CONTENT IN NiO/
α
-Al
2
O
3
CATALYST BY EXAFS
Chen Zhixue;
Zhao Yaqin; Lu Kunquan*
The structure and phase content in industrial catalyst NiO/α-Al_2O_3 before and after reaction were studied by EXAFS. Pa...
Acta Phys. -Chim. Sin. 1988, 4 (03), 267-272.
DOI: 10.3866/PKU.WHXB19880309
4597
Abstract/Metrics
2168
PDF(2152KB)
POWDER MICROELECTRODE Ⅱ. IRREVERSIBLE ELECTROCHEMICAL REACTIONS
Li Changming*; Zha Quanxing
The behaviors of powder microelectrodes for irreversible reduction of oxygen and thionyl chloride were studied. The post...
Acta Phys. -Chim. Sin. 1988, 4 (03), 273-278.
DOI: 10.3866/PKU.WHXB19880310
5406
Abstract/Metrics
2510
PDF(2154KB)
A STUDY ON THE SOLVATION OF Na
+
IN BINARY MIXTURE OF SOLVENTS BY Na-23 NMR (Ⅱ)
Huang Yining; Li Zhifen*; Liu Ruilin
~(23)Na~+ chemical shifts of NaBPh_4 in mixed solvents of CH_3OH-CH_3COCH_3, CH_3OH-CH_3CN, DMSO-DMF, DMSO-HCONH_2 were ...
Acta Phys. -Chim. Sin. 1988, 4 (03), 279-284.
DOI: 10.3866/PKU.WHXB19880311
4537
Abstract/Metrics
2356
PDF(2050KB)
SOLUBILITIES OF HYDROGEN IN ACETONEWATER MIXED SOLVENTS
Song Hang; Liu Guojie; Hu Ying*
An improved apparatus for precisely measuring the gas solubilities in mixed solvents was reported. The apparatus can als...
Acta Phys. -Chim. Sin. 1988, 4 (03), 285-289.
DOI: 10.3866/PKU.WHXB19880312
6509
Abstract/Metrics
2508
PDF(1890KB)
INVESTIGATION OF SURFACTANTS ADSORPTION ON LOW-ENERGY SOLID SURFACE Ⅱ. BY THE ADHESION TENSION METHOD——THE ADSORPTION OF HYDROCARBON AND FLUOROCARBON SURFACTANTS
Zhu Buyao*; Xiang Yan
The adhesion tensions of surfactant solution/solid interface hare been measured by Wilhelmy method. The adsorptions of s...
Acta Phys. -Chim. Sin. 1988, 4 (03), 290-295.
DOI: 10.3866/PKU.WHXB19880313
5004
Abstract/Metrics
2399
PDF(1953KB)
REACTIVE SCATTERING CALCULATIONS OF COLLINEAR TRIATOMIC SYSTEMS IN HYPERSPHERICAL COORDINATES BY FIRST-ORDER MAGNUS NUMERICAL PROPAGATION METHOD
Sun Qiyan; Wu Dayong*; Lou Nanquan
Hyperspherical coordinates are employed in describing collinear triatomic reactive scattering. Close-coupling differenti...
Acta Phys. -Chim. Sin. 1988, 4 (03), 296-300.
DOI: 10.3866/PKU.WHXB19880314
4928
Abstract/Metrics
2228
PDF(1660KB)
FTIR STUDY ON HYDROGEN SPILLOVER IN THE BENZENE HYDROGENATION SYSTEM
Dong Qingnian*; Shan Yafeng; Xiao Youxie; Yang Lixin; Zhong Bin
Hydrogen spillover has been studied by means of benzene hydrogenation reaction on Al_2O_3. The spillover hydrogen is pro...
Acta Phys. -Chim. Sin. 1988, 4 (03), 301-306.
DOI: 10.3866/PKU.WHXB19880315
5430
Abstract/Metrics
2217
PDF(2305KB)
STUDIES ON THE REACTION BETWEEN TETRALIN AND COUMARIN Ⅱ. THE FURTHER APPROACH TO KINETICS AND MECHANISM
Huang Chaoran; Yang Huixing*; Han Degang
This paper is concerned with the kinetics and mechanism for the reaction between tetralin and coumarin. Second order rea...
Acta Phys. -Chim. Sin. 1988, 4 (03), 307-313.
DOI: 10.3866/PKU.WHXB19880316
4374
Abstract/Metrics
2186
PDF(2035KB)
THE STUDIES OF CORRELATIONS BETWEEN THE PHOTOVOLTAIC EFFECT AND THE MOLECULAR STRUCTURE OF DYES IN ORGANIC CELLS
Tian He*; Huang Songyu; Zhou Changshou
A number of cyanine dyes and squarylium dyes have been investigeted. The relations between the photovoltaic effect and t...
Acta Phys. -Chim. Sin. 1988, 4 (03), 314-319.
DOI: 10.3866/PKU.WHXB19880317
4707
Abstract/Metrics
2289
PDF(2062KB)
Note
IVESTIGATION OF THE PSEUDO-BINARY SYSTEM Li
2
WO
4
-MgWO
4
Fu Zhengmin*; Li Wenxiu; Liu Yongqing; Li Junfang
The phase diagram of a pseudo-binary system Li_2WO_4-MgWO_4 has been investigated by means of DTA and X-ray powder diffr...
Acta Phys. -Chim. Sin. 1988, 4 (03), 320-324.
DOI: 10.3866/PKU.WHXB19880318
4924
Abstract/Metrics
2013
PDF(1690KB)
DISCUSSION ON THE T-V PROCESS IN CN RADICAL WITH HIGH TRANSLATION ENERGY (1.5 eV)
Li Xuechu*;
W.M.Jackson
The vibrational distributions of CNX~2Σ~+ have been obtained in photolysis of BrCN at 193 nm. An obvious increase of v″=...
Acta Phys. -Chim. Sin. 1988, 4 (03), 325-328.
DOI: 10.3866/PKU.WHXB19880319
5082
Abstract/Metrics
2011
PDF(1775KB)
A STUDY OF VAPOR-LIQUID EQUILIBRIUM FOR THE TERNARY SYSTEM Li
2
SO
4
-C
2
H
5
OH-H
2
O AT PLATEAU ATOMSPHERE
Pan Huanqian*; Xia Shuping; Qao Shiyang
In this paper, a lernary system of Li_2SO_4-C_2H_5OH-H_2O, saturated with salt, was studied. The modified Rose still was...
Acta Phys. -Chim. Sin. 1988, 4 (03), 329-331.
DOI: 10.3866/PKU.WHXB19880320
4430
Abstract/Metrics
2073
PDF(1103KB)
STUDIES ON KINETICS OF REDUCTION OF IRON (Ⅲ) OXIDES
Wang Wenxiang*; Xu Jie; Ma Fuqin
The kinetic behavior of reduction for iron (III) oxides was studied by means of TG-DTA thermal analyzer under temperatur...
Acta Phys. -Chim. Sin. 1988, 4 (03), 332-336.
DOI: 10.3866/PKU.WHXB19880321
5067
Abstract/Metrics
2814
PDF(1723KB)