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Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
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中文
Current Issue
1985 Vol. 1, No. 03
Published online: 1985-06-15
Current column
Communication
ARTICLE
Note
Communication
MOLECULAR MACHANICS STUDY ON THE CONFORMATION OF 4,4'-DIBENZOYLBIPHENYL
Bai Chunli; Fu Heng; Tang Youqi
The conformations of title compound in the crystal and in the isolated state have been calculated by means of QCFF/PI+MC...
1985, 1 (03): 205-206.
DOI: 10.3866/PKU.WHXB19850301
4264
Abstract/Metrics
1770
PDF(715KB)
THE MOLECULAR AND CRYSTAL STRUCTURES OF 5-METHYL-5-
P
-FLUOROBENZOYLPROPYLBARBITURIC ACID AND 5-ETHYL-5-
P
-FLUOROBENZOYLPROPYL-BARBITURIC ACID
Xu Xiaojie; Jin Sheng; Han Yuzhen; Tang Youqi
The three dimensional X-ray data were collected by Nicolet R3 four circle diffractometer. Compound(Ⅰ)crystallized in mon...
1985, 1 (03): 207-210.
DOI: 10.3866/PKU.WHXB19850302
4170
Abstract/Metrics
1720
PDF(1176KB)
DISTRIBUTION OF PHOTOFRAGMENTATION PRODUCTS OF CH
3
I
Zhu Qihe; Huang Shouling; et. al.
The photofragmentation of CH_3I at 249 nm has been investigated by means of our crossed laser-molecular beam apparatus w...
1985, 1 (03): 211-212.
DOI: 10.3866/PKU.WHXB19850303
3893
Abstract/Metrics
1754
PDF(700KB)
STUDIES ON THERMODYNAMIC PROPERTIES OFBINARY SYSTEMS CONTAINING ALCOHOLS
Ⅱ. EXCESS ENTHALPIES OF C
1
TO C
5
NORMAL ALCOHOLS+1,4-DIOXANE
Chao Jianping; Dai Ming
The molar execess enthalpies of C_1 to C_5 normal alcohols with 1,4-dioxane have been measured with a Picker flow microc...
1985, 1 (03): 213-214.
DOI: 10.3866/PKU.WHXB19850304
3649
Abstract/Metrics
1793
PDF(845KB)
ARTICLE
STUDIES ON DEFECT OF Ni ELECTRODEPOSITS BY MEANS OF POSITRON ANNIHILATION LIFETIME SPECTROSCOPY
Yao Shibing; Chen Rongqin; Fang Jianlin; Chen Binyi; Zhong Chanxing; Zhou Shaomin
Nickel, electrodeposited from twelve typical plating baths, were investigated by positron annihilation lifetime spectros...
1985, 1 (03): 215-221.
DOI: 10.3866/PKU.WHXB19850305
4205
Abstract/Metrics
1865
PDF(2132KB)
STUDY ON THE EXTRACTION OF MOLYBDENUM AND SURFACE STATE FOR MoO
3
SUPPORTED ON THE SURFACE OF γ-Al
2
O
3
, TiO
2
AND SiO
2
Gui Linlin; Zhong Bianxiao; Tang Youqi
MoO_3/γ-Al_2O_3, MoO_3/TiO_2 and MoO_3/SiO_2 samples prepared by impregnation method have been studied by various techni...
1985, 1 (03): 222-231.
DOI: 10.3866/PKU.WHXB19850306
4425
Abstract/Metrics
2083
PDF(3276KB)
ELECTROCHEMICAL REDUCTION OF h
5
-CYCLOPENTADIENYL-h
4
-CYCLOBUTADIENE-NICKEL-CATIONS, Ni(h
5
-C
5
R
5
)(h
4
-C
4
R
4
′)
+
Ding Tingzhen; Ulrich Koelle
Electrochemical reduction of nickel sandwich complex-cations Ni(h~5-C_5eR_5) (h~4-C_4R'_4)~+, where R=H, CH_3; R'=CH_3, ...
1985, 1 (03): 232-238.
DOI: 10.3866/PKU.WHXB19850307
4497
Abstract/Metrics
1938
PDF(2197KB)
STUDY OF A NEW OSCILLATION SYSTEM
I. INVESTIGATION OF THE OSCILLATORY PHENOMENA OF THE DISSOLVED GAS BY THE QUADRIPOLE MASS-SPECTROMETER
Li Shengping; Yuan Wei; Liu Dianqiu
A new oscillatory system has been investigated by the quadripole mass-spectrometer. It is recognized that nature of this...
1985, 1 (03): 239-248.
DOI: 10.3866/PKU.WHXB19850308
3871
Abstract/Metrics
1882
PDF(2717KB)
KINETICS AND MECHANISM OF THERMOLYSIS OF TETRALIN
Yang Xiaolin; Yang Huixing; Han Degang
The kinetics and mechanism of the thermolysis of tetralin, commonly used as a hydrogen donor in coal liquefaction, was s...
1985, 1 (03): 249-257.
DOI: 10.3866/PKU.WHXB19850309
4530
Abstract/Metrics
1855
PDF(2307KB)
STUDIES ON THERMOKINETICS
Ⅲ. THERMOKINETICS OF THE SAPONIFICATION OF THE ETHYL ESTERS OF NORMAL ALIPHATIC ACIDS
Zeng Xiancheng; Qin Ziming
On the theoritical basis of thermokinetics proposed in previous articles, the thermokinetics for saponification of the e...
1985, 1 (03): 258-264.
DOI: 10.3866/PKU.WHXB19850310
4137
Abstract/Metrics
2131
PDF(2026KB)
EVALUATION OF FLUORESCENCE LIFETIME OF ZINC PHTHALOCYANINES BY NON-TRANSIENT EXPERIMENTS
Shen Tao; Yuan Zhenli; Xu Huijun
A series of zinc phthalocyanines was synthesized. Their redox potentials, E_(ox) and E_R were measured by means of cycli...
1985, 1 (03): 265-269.
DOI: 10.3866/PKU.WHXB19850311
4136
Abstract/Metrics
1975
PDF(1658KB)
CATALYTIC ACTION OF MOLYBDOVANADOPHOSPHORIC ACIDS IN DIRECT HYDROXYLATION OF BENZENE——AN EXAMINATION OF THE MECHANISM OF H
2
O
2
ACTIVATION
Xu Bo; Wu Yue
The catalytic behavior of H_(3+n)PMo(12-n)V_nO_(40) (abbreviated to HPA-n hereafter) +H_2O_2 system in the direct hydrox...
1985, 1 (03): 270-280.
DOI: 10.3866/PKU.WHXB19850312
3997
Abstract/Metrics
1863
PDF(3211KB)
A STUDY OF THE INTERACTION BETWEEN MoO
3
AND SnO
2
Niu Chunming; Yen Qijie; Chen Yi
MoO_3-SnO_2 catalysts prepared by precipitation, impregnation and high temperature calcination of the relevant mixtures ...
1985, 1 (03): 281-288.
DOI: 10.3866/PKU.WHXB19850313
4225
Abstract/Metrics
2075
PDF(2450KB)
Note
THE CRYSTAL AND MOLECULAR STRUCTURE OF TETRAHYDROTHIAZOLE-2-THIONE COPPER COMPLEX
Zhao Baoguang; Lin Xiuyun; Ye Yunhua
The crystal of tetrahydrothiazole-2-thione belongs to triongal system, space group R3c. There are six molecules in a uni...
1985, 1 (03): 289-292.
DOI: 10.3866/PKU.WHXB19850314
3879
Abstract/Metrics
1864
PDF(1137KB)
EXCESS VOLUMES OF MIXING OF BENZENE AND TOLUENE WITH SOME POLAR SOLVENTS AT 293.15 K
Gong Hua; Chen Wufeng; Chou Yuping; Chen Mingzhi; Zheng Guokang
The excess volumes of ten binary systems namely benzene +2-butanone, +acetonitrile, +acrylonitrile, +ethyl acetate, +met...
1985, 1 (03): 293-298.
DOI: 10.3866/PKU.WHXB19850315
5158
Abstract/Metrics
1830
PDF(1656KB)