Acta Phys. -Chim. Sin.

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2010 Vol. 26, No. 04 Published online: 2010-04-07
Current column
Table of Contents
Preface
Communication
THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY
CHEMICAL KINETICS AND MOLECULE DYNAMICS
ELECTROCHEMISTRY
COLLOID AND INTERFACE CHEMISTRY
CATALYSIS AND SURFACE STRUCTURE
PHOTOCHEMISTRY AND SPECTROSCOPY
QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
BIOPHYSICAL CHEMISTRY
PHYSICAL CHEMISTRY OF MATERIALS

Table of Contents

Table of Contents for Vol.26 No. 04
Acta Phys. -Chim. Sin. 2010, 26 (04), 0.

Preface

Preface
GAO Song, WU Kai, MA Yu-Guo
Acta Phys. -Chim. Sin. 2010, 26 (04), 799-800. DOI: 10.3866/PKU.WHXB100ZKPreface

Communication

Raman Characterization of a Highly Folded Individual Serpentine (7,5) Single-Walled Carbon Nanotube
XIE Li-Ming, YU Xue-Chun, FENG Chao-Qun, ZHANG Jin, LIU Zhong-Fan
We carried out Raman characterization of a highly folded individual serpentine (7,5) single-walled carbon nanotube (SWNT...
Acta Phys. -Chim. Sin. 2010, 26 (04), 801-804. DOI: 10.3866/PKU.WHXB20100411

THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY

Controllable Radiolytic Reduction of Cu²⁺ in Aqueous Solution by β-Cyclodextrin
YANG Shi-Guo, CHEN Qing-De, SHI Jian-Feng, SHEN Xing-Hai
We used β-cyclodextrin (β-CD) to control the radiolytic reduction of Cu2+ in aqueous solution at a safe absorb...
Acta Phys. -Chim. Sin. 2010, 26 (04), 805-810. DOI: 10.3866/PKU.WHXB20100407

Solubility Analysis of Americiumin Yuci Groundwater
CHEN Tao, WANG Xiang-Yun, TIAN Wen-Yu, SUN Mao, LI Chun, LIU Xiao-Yu, WANG Lu-Hua, LIU Chun-Li
The solubility of americiumin Yuci groundwater was analyzed using a newly developed geochemical code CHEMSPEC and the in...
Acta Phys. -Chim. Sin. 2010, 26 (04), 811-816. DOI: 10.3866/PKU.WHXB20100114

Phase Transitions and Structures of 5-{[(4’-Pentyloxy-4-biphenylyl)carbonyl]oxy}-1-pentyne
YU Zhen-Qiang, ZHU Cai-Zhen, TIAN Sai, LIU Jian-Hong, LAM Jacky Wing Yip, TANG Ben-Zhong
Phase transitions and structures of the monomer of side-chain liquid crystalline polyacetylene containing biphenyl mesog...
Acta Phys. -Chim. Sin. 2010, 26 (04), 817-821. DOI: 10.3866/PKU.WHXB20100405

CHEMICAL KINETICS AND MOLECULE DYNAMICS

Photolysis Kinetics of 4-(2-(4’-Pyridinyl)ethynyl)benzenic Diazonium Salt and Characterization of Its Self-Assembled Monolayer Film
ZHAO Wei, TONG Bin, ZHI Jun-Ge, PAN Yue-Xiu, SHEN Jin-Bo, SHI Jian-Bing, DONG Yu-Ping
In this paper, the photolysis kinetics of conjugate 4-(2-(4'-pyridinyl)ethynyl)benzene diazonium salt in acetonitrile an...
Acta Phys. -Chim. Sin. 2010, 26 (04), 822-826. DOI: 10.3866/PKU.WHXB201004001

ELECTROCHEMISTRY

Preparation of Single-Chamber Solid Oxide Fuel Cell by Co-Pressing and Direct Forming Process
ZONG Wei-Zheng, ZHU Yong-Fa
Co-pressing and direct forming process has been developed for the preparation of a single-chamber solid oxide fuel cell ...
Acta Phys. -Chim. Sin. 2010, 26 (04), 827-832. DOI: 10.3866/PKU.WHXB20100443

Synergistic Effect of a Nonmetal and a Metal on the Electrochemical Properties of a Mg-Based Hydrogen Storage Alloy
YANG Gui-Ling, WANG Chun, YANG Xiao-Min, ZHAO Na, JIAO Xiao-Yan
The surface of an amorphous Mg45Ti3V2Ni50 alloy was modified with Ti, B, and a specific composite TiB by high energy bal...
Acta Phys. -Chim. Sin. 2010, 26 (04), 833-839. DOI: 10.3866/PKU.WHXB20100438

COLLOID AND INTERFACE CHEMISTRY

Application of Fluorescent Probe Technology in Self-Assembly Systems of Amphiphile Aqueous Solutions
ZHAO Li, YAN Yun, HUANG Jian-Bin
In this paper, we review the application of fluorescent probe technology in self-assembly systems of amphiphile aqueous ...
Acta Phys. -Chim. Sin. 2010, 26 (04), 840-849. DOI: 10.3866/PKU.WHXB20100429

Study on the Fine Structure of Polypeptides at Solid-Liquid Interfaces by Scanning Tunneling Microscopy
MAO Xiao-Bo, WANG Chen-Xuan, LIU Lei, MA Xiao-Jing, NIU Lin, YANG Yan-Lian, WANG Chen
In this review, a summary of recent research progress on the assembly structures of amyloid peptides related to protein ...
Acta Phys. -Chim. Sin. 2010, 26 (04), 850-861. DOI: 10.3866/PKU.WHXB20100440

Online Monitoring of the Aggregation and Fusion of DPPC/PAby Static and Dynamic Light Scattering
DENG Lin, LIANG De-Hai
Static and dynamic light scattering were employed to monitor the temperature-induced aggregation and fusion processes of...
Acta Phys. -Chim. Sin. 2010, 26 (04), 862-868. DOI: 10.3866/PKU.WHXB20100422

CATALYSIS AND SURFACE STRUCTURE

Rational Design of Low-Temperature Hydrogenation Catalysts: Theoretical Predictions and Experimental Verification
CHEN Jingguang G, QI Sui-Tao, HUMBERT Michael P, MENNING Carl A, ZHU Yue-Xiang
In this review, we will provide a brief review of our recent theoretical and experimental studies of bimetallic surfaces...
Acta Phys. -Chim. Sin. 2010, 26 (04), 869-876. DOI: 10.3866/PKU.WHXB20100441

Wide Bandgap p-Block Metal Oxides/Hydroxides for Photocatalytic Benzene Degradation
LI Zhao-Hui, LIU Ping, FU Xian-Zhi
Benzene has severe health and environmental consequences because of its high toxicity and carcinogenicity. Although TiO2...
Acta Phys. -Chim. Sin. 2010, 26 (04), 877-884. DOI: 10.3866/PKU.WHXB20100404

Recent Progress in the Removal of Volatile Organic Compounds by Catalytic Combustion
LI Wei-Bin, GONG Hao
Catalytic combustion is one of the most effective techniques for the removal of volatile organic compounds (VOCs). In th...
Acta Phys. -Chim. Sin. 2010, 26 (04), 885-894. DOI: 10.3866/PKU.WHXB20100436

Relationship between the Structures of Metal Oxide Catalysts and Their Properties in Selective Oxidation of Light Alkanes
ZHANG Sheng-Hong, LIU Hai-Chao
It is of great importance to study the selective oxidation of light alkanes on metal oxide catalysts from a fundamental ...
Acta Phys. -Chim. Sin. 2010, 26 (04), 895-907. DOI: 10.3866/PKU.WHXB20100444

Ionic Liquid and Water: Making Nanoparticle Catalysis More Efficient and Greener
YUAN Xiao, LOU Shu-Jie, KOU Yuan
Transition metal nanoparticles (MNP) stabilized in green solvents, i.e., ionic liquids (ILs) and water, have great poten...
Acta Phys. -Chim. Sin. 2010, 26 (04), 908-914. DOI: 10.3866/PKU.WHXB20100433

Hydrothermal Preparation and Photocatalytic Activity of Chlorine Doped Titanium Dioxide Supported on SiO₂
DEDG Pei-Chang, HU Jie-Zhen, WANG Hai-Zeng, SUN Bao-Wei
A chlorine doped titaniumdioxide photocatalyst was synthesized by a hydrothermal process using silica gel as a carrier, ...
Acta Phys. -Chim. Sin. 2010, 26 (04), 915-920. DOI: 10.3866/PKU.WHXB20100428

Surface Modification of Mg-Al Hydrotalcite Mixed Oxides with Potassium
ZHANG Ye-Xin, SU Qing-Yun, WANG Zhong-Peng, GAO Xi-Yan, ZHANG Zhao-Liang
The surface modification of Mg-Al hydrotalcite mixed oxides (MgAlO) with K was investigated using X-ray powder diffracti...
Acta Phys. -Chim. Sin. 2010, 26 (04), 921-926. DOI: 10.3866/PKU.WHXB20100446

Phase Transfer Catalytic Activity of Immobilized Dibenzo-18-Crown-6 for Butyl Benzoate Synthesis
WANG Shi-Wei, GAO Bao-Jiao, GAO Xue-Chao, WANG Ling
Dibenzo-18-crown-6 (DBC) was immobilized on cross-linked polyvinyl alcohol (CPVA) microspheres to prepare the triphase-t...
Acta Phys. -Chim. Sin. 2010, 26 (04), 927-932. DOI: 10.3866/PKU.WHXB20100430

Self-Assemblies of Oxovanadium Phthalocyanine Molecules and Nanoclusters on Highly Oriented Pyrolytic Graphite
WANG Yong-Feng, ZHANG Xin-Ran, YE Ying-Chun, LIANG De-Jian, WANG Yuan, WU Kai
Self-assembled monolayer (SAM) of oxovanadium phthalocyanine (VOPc), an organic semiconductor compound, was prepared at ...
Acta Phys. -Chim. Sin. 2010, 26 (04), 933-938. DOI: 10.3866/PKU.WHXB20100419

Synthesis of Asymmetrical Organic Carbonates Catalyzed by Metal Organic Frameworks
ZHOU Yin-Xi, LIANG Shu-Guang, SONG Jin-Liang, WU Tian-Bin, HU Su-Qin, LIU Hui-Zhen, JIANG Tao, HAN Bu-Xing
Metal organic frameworks (MOFs) are a new class of materials that are formed by the copolymerization of organic ligands ...
Acta Phys. -Chim. Sin. 2010, 26 (04), 939-945. DOI: 10.3866/PKU.WHXB20100406

PHOTOCHEMISTRY AND SPECTROSCOPY

Spectral Stability of Polyfluorene-Based Semiconductors
LIANG Jing, QIAN Yan, XIE Ling-Hai, SHI Nai-En, CHEN Shu-Fen, DENG Xian-Yu, HUANG Wei
The physical and chemical properties of organic semiconductors play key roles in the performance of optoelectronic devic...
Acta Phys. -Chim. Sin. 2010, 26 (04), 946-963. DOI: 10.3866/PKU.WHXB20100415

Low Frequency Spectrumof Ionic Liquid [bmim][PF₆] Studied by Femtosecond Optically Heterodyne-Detected Optical Kerr Effect Spectroscopy and Low Frequency Raman Spectroscopy
WANG Wei, LV Rong, YU An-Chi
The low frequency vibrational spectrum that reflects the intermolecular interaction of an imidazolium cation ionic liqui...
Acta Phys. -Chim. Sin. 2010, 26 (04), 964-970. DOI: 10.3866/PKU.WHXB20100418

Synthesis and Helical Conformation of New Optically Active Liquid Crystalline Polythiophene Containing Cyanoterphenyl Mesogen Pendant
CHEN Lie, CHEN Yi-Wang, YAO Kai, ZHOU Wei-Hua, LI Fan, NIE Hua-Rong
A novel liquid crystalline (LC) polythiophene bearing cyanoterphenyl mesogenic pendants with a long flexible spacer {&md...
Acta Phys. -Chim. Sin. 2010, 26 (04), 971-980. DOI: 10.3866/PKU.WHXB20100409

Radiation-Induced Changes of Phase Behavior and Fluorescence Properties of the Ionic Liquids [C₄mim][PF₆] and [C₄mim][NTf₂]
YUAN Li-Yong, PENG Jing, LI Jiu-Qiang, ZHAI Mao-Lin
The application of room-temperature ionic liquids (RTILs) to the separation of high level radioactive nuclides from wast...
Acta Phys. -Chim. Sin. 2010, 26 (04), 981-987. DOI: 10.3866/PKU.WHXB20100423

Radiation Stability and Analysis of Radiolysis Product of 1-Octanol
YU Chu-Hong, ZHANG Jia-Wei, DAI Jing, PENG Jing, LI Jiu-Qiang, ZHAI Mao-Lin
1-Octanol is a promising solvent for the extraction of high-level radioactive waste from nuclear fuel reprocessing and a...
Acta Phys. -Chim. Sin. 2010, 26 (04), 988-992. DOI: 10.3866/PKU.WHXB20100434

Synthesis and Luminescence Properties of Soluble Spirobifluorene-Based Conjugated Polymers
ZHANG Cheng, XU Yu, XU Yi, OUYANG Mi, MA Chun-An
Spirobifluorene (SPF)-based soluble copolymers containing different chain lengths of alkoxy-benzene units in the main ch...
Acta Phys. -Chim. Sin. 2010, 26 (04), 993-998. DOI: 10.3866/PKU.WHXB20100403

QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY

Understanding and Predicting Thiolated Gold Nanoclusters from First Principles
JIANG De-En
This is an exciting time for studying thiolated gold nanoclusters. Single crystal structures of Au102(SR)44 and Au25(SR)...
Acta Phys. -Chim. Sin. 2010, 26 (04), 999-1016. DOI: 10.3866/PKU.WHXB20100414

The GW Method: Basic Principles, Latest Developments and Its Applications for d-and f-Electron Systems
JIANG Hong
The many-body perturbation theory based on the Green's function provides a rigorous conceptual framework to describe gro...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1017-1033. DOI: 10.3866/PKU.WHXB20100413

Coorperativity between Metals, Ligands and Solvent: a DFT Study on the Mechanism of a Dizinc Complex-Mediated Phosphodiester Cleavage
FAN Yu-Bo, GAO Yi-Qin
Density functional theory (DFT)-Tao-Perdew-Staroverov-Scuseria (TPSS) functional calculations on dizinc complex-mediated...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1034-1042. DOI: 10.3866/PKU.WHXB20100447

Comparative Study of Two Integration Methods for Solvation Effect Calculation
DONG Bo, CHEN Fei-Wu, WEI Mei-Ju
The parallelism and convergence of the approximate and analytical integration methods on solvation effect calculation we...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1043-1050. DOI: 10.3866/PKU.WHXB20100432

Electronic Structures and Spectroscopic Properties of Group-14 Metalloles MPh₆ (M=Si, Ge, Sn)
DENG Chun-Mei, NIU Ying-Li, PENG Qian, SHUAI Zhi-Gang
Group-14 metalloles possess interesting optical properties and are promising molecules for light-emitting materials. We ...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1051-1058. DOI: 10.3866/PKU.WHXB20100420

Semiconductor Properties of Perylene Diimide Derivatives
CAI Xue, QI Dong-Dong, ZHANG Yue-Xing, BIAN Yong-Zhong, JIANG Jian-Zhuang
Density functional theory (DFT) calculations were carried out to study the charge transfer properties of N,N'-bisperylen...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1059-1064. DOI: 10.3866/PKU.WHXB20100421

QSAR of Macrolactone Derivatives with Herbicidal Activity
DUAN Hong-Xia, WANG Rui-Gang, ZHANG Jian-Jun, DONG Yan-Hong, LIANG Xiao-Mei, WU Jing-Ping, WANG Dao-Quan
We studied the quantitative structure-activity relationships (QSAR) of macrolactone derivatives. Statistical results fro...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1065-1074. DOI: 10.3866/PKU.WHXB20100435

Photoelectric Properties of 9,9’-Spirobifluorene
ZHANG Cheng, YAN Yan, CHEN Li-Tao, MA Chun-An
9,9'-Spirobifluorene oligomers ((SBF)n(n=1-4)) were fully optimized using density functional theory (DFT) at the B3LYP/6...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1075-1081. DOI: 10.3866/PKU.WHXB20100402

BIOPHYSICAL CHEMISTRY

Investigation of Interaction of Small Natural Product Molecules and Human Telomeric G-Quadruplex and Thermal Stabilities of the Complexes by Electrospray Ionization Mass Spectrometry
HE Xiang-Wei, LONG Hai-Tao, YUAN Gu, Xu Xiao-Jie, ZHOU Ya-Wei
Electrospray ionization mass spectrometry (ESI-MS) was used to investigate the non-covalent interaction of human telomer...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1082-1086. DOI: 10.3866/PKU.WHXB20100416

Maximum Entropy Method for Analyses of Fluorescence Correlation Spectra of Oligonucleotide Intra-Chain Collision
YIN Yan-Dong, ZHOU Xiao-Xue, ZHAO Xin-Sheng
It has been a challenge to accurately extract dynamic information from experimental fluorescence correlation spectroscop...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1087-1092. DOI: 10.3866/PKU.WHXB20100408

Substrate Binding and Homo-Dimerization of SARS 3CL Proteinase are Mutual Allosteric Effectors
WEI Ping, LI Chun-Mei, ZHOU Lu, LIU Ying, LAI Lu-Hua
The 3C-like proteinase (3CLpro) of severe acute respiratory syndrome (SARS) coronavirus has been proposed to be a key ta...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1093-1098. DOI: 10.3866/PKU.WHXB20100449

Single Molecule Fluorescence Resonance Energy Transfer and Ensemble Biophysical Characterization of a G-quadruplex Formed in the Promoter of Human Myocyte Enhancer Factor 2D
ZHOU Wen-Hua, YING Li-Ming
DNA G-quadruplexes (G4s) are believed to be involved in many biological processes, including the gene expression regulat...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1099-1106. DOI: 10.3866/PKU.WHXB20100439

Interaction of Nickel(II) with Yeast Alcohol Dehydrogenase
YIN Guo-Wei, WEI Wei, XU Jia, LI Zhi-Fen, WANG Bao-Huai, DU Wei-Hong
The binding mode of metal ions with proteins is usually different in different systems. Yeast alcohol dehydrogenase (YAD...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1107-1112. DOI: 10.3866/PKU.WHXB20100410

Adsorptive Immobilization of Four Proteases on Different Molecular Sieves
LIU Ping, XING Guo-Wen, LI Xuan-Wen, YE Yun-Hua
The immobilization of four different proteases on a series of molecular sieves, including microporous HY, NaY, NH4Y, MCM...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1113-1118. DOI: 10.3866/PKU.WHXB20100448

Electrochemical DNA Biosensor with a Polyamide Probe
CAO Rui-Guo, ZHU Bin, LIU Wei, LI Jing-Jian, XU Dong-Sheng
The base pair stack within a DNA duplex can transport charge over long distances. The π-stacked base pairs provide an...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1119-1123. DOI: 10.3866/PKU.WHXB20100427

PHYSICAL CHEMISTRY OF MATERIALS

Progress in Discotic Liquid Crystalline Materials
CHEN Shu-Sen, LI Tian, ZHAO Da-Hui
Discotic liquid crystal (LC) molecules readily form columnar supramolecular structures. Because of molecular mobility in...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1124-1134. DOI: 10.3866/PKU.WHXB20100412

A Novel Path to Patterning Based on the Static Breath Figure Technique
LI Lei, ZHONG Ya-Wen, CHEN Cai-Kang, LI Jian
The breath figure technique is one of the most promising strategies for the fabrication of large-sized patterns containi...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1135-1142. DOI: 10.3866/PKU.WHXB20100424

Preparations and Catalytic Applications of High Surface Area Silicon Carbide
GUO Xiang-Yun, JIN Guo-Qiang, WANG Ying-Yong
We discuss recent developments in the preparation methods of high surface area silicon carbide, such as templated synthe...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1143-1150. DOI: 10.3866/PKU.WHXB20100426

Facile Fabrication of the Crossed Nanotube-Graphene Junctions
GAN Lin, LIU Song, LI Dan-Na, GU Hang, CAO Yang, SHEN Qian, WANG Zhen-Xing, WANG Qing, GUO Xue-Feng
In this study, a nondestructive method to mass produce crossed nanotube-graphene junctions through twice polymer-mediate...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1151-1156. DOI: 10.3866/PKU.WHXB20100417

Effect ofMolecular Structure on the Surface Morphology of Ultrathin Films by Competing Crystallization and Dewetting Processes
YUAN Wei-Zhong, ZHANG Feng-Bo, YUAN Jin-Ying, XIE Xu-Ming, HONG Xiao-Yin
Star-branched poly(ε-caprolactone) (PCL) including hexa-armed star-shaped PCL (HPCL), dendritic PCL (DPCL), and ...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1157-1163. DOI: 10.3866/PKU.WHXB20100431

Synthesis and Characterization of a Polyquinoline Derivative Thin Film with a Low Dielectric Constant
ZHAO Xiong-Yan
We prepared a novel plasma polyquinoline derivative thin film, plasma-polymerized 3-cyanoquinoline (PP3QCN). Fourier tra...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1164-1170. DOI: 10.3866/PKU.WHXB20100425

Preparation of High Specific Surface Area Nano-Alumina by Vacuum Freeze Drying
LIU Xiang-Zhi, PIAO Ling-Yu, MAO Li-Juan, HAO Shi-Jie, YANG Lei, JU Si-Ting
Nano-alumina powders were prepared by vacuum freeze drying combined with reverse microemulsion method. The reverse micro...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1171-1176. DOI: 10.3866/PKU.WHXB20100445

Preparation and Optical Properties of Triangular Silver Nanoplates by a Dual-Reduction Method
LAI Wen-Zhong, ZHAO Wei, YANG Rong, LI Xing-Guo
Triangular silver nanoplates were successfully prepared by a water-bath heating method. NaBH4 and sodium citrate were bo...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1177-1183. DOI: 10.3866/PKU.WHXB20100437

Synthesis and Photoluminescence of Iridium(III) Diazine Complex Modified with a Carbazyl Group
YU Xiao-Hang, GE Guo-Ping, ZHANG Guo-Lin, GUO Hai-Qing
We designed and synthesized a new pyrazine derivative containing the carbazyl moiety, 2,3-di(4-(9-carbazylmethyl)phenyl)...
Acta Phys. -Chim. Sin. 2010, 26 (04), 1184-1190. DOI: 10.3866/PKU.WHXB20100442