Loading...
Acta Phys. -Chim. Sin.
Acta Phys. -Chim. Sin.
Home
About Journal
About Journal
Editorial Board
Database Included
Impact Factor
Reader Center
Online First
Special Issue
Most Read
Most Downloaded
Volumn Content
Subject Content
Archive
Email Alert
Author Center
Online Submission
Submission Information
Review Online
Contact Us
中文
Current Issue
2010 Vol. 26, No. 11
Published online: 2010-10-29
Current column
Table of Contents
Invited Aticle
Review
THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY
ELECTROCHEMISTRY
COLLOID AND INTERFACE CHEMISTRY
CATALYSIS AND SURFACE STRUCTURE
PHOTOCHEMISTRY AND SPECTROSCOPY
QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
PHYSICAL CHEMISTRY OF MATERIALS
Table of Contents
Cover and Table of Contents for Vol.26 No. 11
Acta Phys. -Chim. Sin. 2010, 26 (11), 0.
2004
Abstract/Metrics
2135
PDF(4420KB)
Invited Aticle
Simple Chemical Model for Facilitated Transport with an Application to Wyman-Murray Facilitated Diffusion
COLE Christine Lind, QIAN Hong
A simple chemical kinetic model is developed which describes the behavior of small ligands that can bind reversibly with...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2857-2864.
DOI: 10.3866/PKU.WHXB20101129
5078
Abstract/Metrics
Supporting Info
1843
PDF(795KB)
Review
Solution Synthesis Strategies for Hierarchical Nanostructures
ZHANG Dong-Feng, NIU Li-Ya, GUO Lin
The coupling and synergistic effects of the unique structure of multi-level, multi-dimension, and multi- components allo...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2865-2876.
DOI: 10.3866/PKU.WHXB20101104
7585
Abstract/Metrics
3895
PDF(4476KB)
Progress of Investigations on Structures and Interactions of Ionic Liquids by Infrared Spectroscopy and Raman Spectroscopy
ZHANG Li-Qun, LI Hao-Ran
Experimental methods, theoretical calculations as well as computer simulations are the three most often used approaches ...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2877-2889.
DOI: 10.3866/PKU.WHXB20101123
12179
Abstract/Metrics
3773
PDF(1343KB)
THERMODYNAMICS,THERMOCHEMISTRY AND SOLUTION CHEMISTRY
Thermodynamics and Kinetics of Adsorption of Diclofenac on Magnetic Multiwalled Carbon Nanotubes in an Aqueous Solution
XIONG Zhen-Hu, WANG Lu, ZHOU Jian-Guo, LIU Jian-Ming
We investigated the adsorption of diclofenac (an anti-inflammatory drug) in aqueous solutions by magnetic multiwalled ca...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2890-2898.
DOI: 10.3866/PKU.WHXB20101130
8314
Abstract/Metrics
6122
PDF(1697KB)
Thermodynamic Analysis of Low Temperature Methane Wet-Air Reforming in a Microcombustor
RAN Jing-Yu, ZHAO Liu-Jie
We studied the effects of reaction pressure, molar ratios of air to methane and steam to methane on the reforming proces...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2899-2906.
DOI: 10.3866/PKU.WHXB20101121
5541
Abstract/Metrics
1702
PDF(1021KB)
Molecular Simulation of Dilute Polyacrylamide Solutions
LIU Yan-Yan, CHEN Pan-Ke, LUO Jian-Hui, ZHOU Ge, JIANG Bo
Polyacrylamide (PAM) applied to various fields is an important class of linear water-soluble polymers. Therefore, it is ...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2907-2914.
DOI: 10.3866/PKU.WHXB20101110
7365
Abstract/Metrics
2765
PDF(1281KB)
Thermal Decomposition Kinetics of Poly(propylene carbonate maleate)
WU Wei-Kang, WANG Jia-Li, LIU Su-Qin, HUANG Ke-Long, LIU Yan-Fei
The thermal decomposition kinetics of the novel terpolymer, poly(propylene carbonate maleate) (PPCMA), was investigated ...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2915-2919.
DOI: 10.3866/PKU.WHXB20101028
6640
Abstract/Metrics
1947
PDF(257KB)
ELECTROCHEMISTRY
Mathematical Model and Circuit Realization to Improve Chronoamperometry
CHEN Xu-Hai, CHEN Jing-Hua, PAN Hai-Bo, LI Yu-Rong, DU Min, LIN Xin-Hua
To overcome the disadvantages of chronoamperometry we report a novel electrochemical method where a peak current is quic...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2920-2926.
DOI: 10.3866/PKU.WHXB20101117
5087
Abstract/Metrics
2910
PDF(2237KB)
Preparation and Photoeletrochemical Performance of CdS Quantum Dot Sensitized ZnO Nanorod Array Electrodes
ZHANG Qiao-Bao, FENG Zeng-Fang, HAN Nan-Nan, LIN Ling-Ling, ZHOU Jian-Zhang, LIN Zhong-Hua
We sensitized CdS quantum dots on a ZnO nanorod array electrode by the successive ionic layer adsorption and reaction me...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2927-2934.
DOI: 10.3866/PKU.WHXB20101113
7819
Abstract/Metrics
3015
PDF(2014KB)
Kinetics and Electrochemical Impedance Properties of TiO
2
Nanotube Array Photoelectrode
ZHANG Zhi-Yu, SANG Li-Xia, SUN Biao, ZHANG Xiao-Min, MA Chong-Fang
The 2μm and 650 nm TiO2 nanotube (TNT) arrays were fabricated by sonoelectrochemical anodic oxidation in ethylene gly...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2935-2940.
DOI: 10.3866/PKU.WHXB20101131
5508
Abstract/Metrics
2110
PDF(1346KB)
Evaluation of Metal Corrosion under Defective Coatings by WBE and EIS Technique
ZHANG Wei, WANG Jia, LI Yu-Nan, WANG Wei
We investigated the corrosion of steel under defective coatings in 3.5% (mass fraction) NaCl solution by the wire beamel...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2941-2950.
DOI: 10.3866/PKU.WHXB20101102
5559
Abstract/Metrics
2344
PDF(2976KB)
Improved Capacitive Performance of Polypyrrole Doped with 9,10-Anthraquinone-2-sulfonic Acid Sodium Salt
WAN Qun-Yi, FAN Shuan-Shi, YUE Xian-Jun, LANG Xue-Mei, XU Wen-Dong, LI Jing, FENG Chun-Hua
A polypyrrole(PPy)/9,10-anthraquinone-2-sulfonic acid sodium salt (AQS) composite electrode was prepared by constant-pot...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2951-2956.
DOI: 10.3866/PKU.WHXB20101107
5505
Abstract/Metrics
2198
PDF(2003KB)
Pt/FTO Counter Electrode for Dye-Sensitized Solar Cells Prepared by Sputtering-Displacement
WANG Yao-Qiong, WEI Zi-Dong, CAI Hong-Ying, ZHANG Qian, ZHAO Qiao-Ling
APt/FTOelectrode for dye-sensitized solar cells (DSSC) was prepared by the sputtering (Cu) -displacement (Pt) (SD) metho...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2957-2961.
DOI: 10.3866/PKU.WHXB20101026
6478
Abstract/Metrics
2345
PDF(3362KB)
Preparation and Electrochemical Performance of H
2
Ti
2
O
5
·H
2
O/Cr
2
O
3
Nanotubes as AnodeMaterials for Lithium-Ion Batteries
HE Yong, TANG Zi-Long, ZHANG Zhong-Tai
One problem that limits the rate capabilities of lithium-ion batteries is that despite the small size of the nanocrystal...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2962-2966.
DOI: 10.3866/PKU.WHXB20101101
5078
Abstract/Metrics
2128
PDF(865KB)
Properties of SPES/PWA/SiO
2
Composite Proton Exchange Membranes
GONG Chun-Li, ZHOU Yi, YAN Li-Cheng, WEN Sheng, ZHENG Gen-Wen
Novel sulfonated poly(ether sulfone) (SPES)/phosphotungstic acid (PWA)/silica organic-inorganic composite membranes for ...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2967-2974.
DOI: 10.3866/PKU.WHXB20101124
5794
Abstract/Metrics
2674
PDF(1169KB)
Highly Stable Solid Alkaline ElectrolyteMembranes fromPoly(vinyl alcohol)/Poly(vinyl pyrrolidone) Based on Chemical Cross-Linking
FU Jing, QIAO Jin-Li, MA Jian-Xin
The stability of alkaline electrolyte membranes is recognized as a key factor that affects their electrochemical applica...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2975-2981.
DOI: 10.3866/PKU.WHXB20101014
6316
Abstract/Metrics
2131
PDF(1535KB)
COLLOID AND INTERFACE CHEMISTRY
Effect of Hydrophobically Modified Polyacrylamide on Interfacial Dilational Rheological Properties of Crude Oil Components
ZONG Hua, WANG Lei, FANG Hong-Bo, MAO Lei-Ting, WANG Yu-Hui, ZHANG Lu, ZHAO Sui, YU Jia-Yong
The effect of hydrophobically modified polyacrylamide (HMPAM) on the dilational rheological properties of interfacial fi...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2982-2988.
DOI: 10.3866/PKU.WHXB20101105
5869
Abstract/Metrics
2097
PDF(312KB)
Effect of Hierarchical Architecture of Super-Hydrophobic Surface on the Condensed Drop's Final State
LIU Tian-Qing, SUN Wei, SUN Xiang-Yu, AI Hong-Ru
The interface free energy of a local condensate from the growth and combination of numerous initial condensation nuclei ...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2989-2996.
DOI: 10.3866/PKU.WHXB20101025
7317
Abstract/Metrics
2010
PDF(3342KB)
Interactions between
N
-Alkyl-
N
,
N
-di(2-hydroxyethyl)-
N
-methylammonium Bromide and Bovine Serum Albumin
SHAO Shuang, HU Xiao-Huan, YOU Jin-Zong, LEI Qun-Fang
Interactions between a series of N-alkyl-N,N-di(2-hydroxyethyl)-N-methylammonium bromides with alkyl chain from dodecyl ...
Acta Phys. -Chim. Sin. 2010, 26 (11), 2997-3001.
DOI: 10.3866/PKU.WHXB20101008
5749
Abstract/Metrics
2040
PDF(743KB)
CATALYSIS AND SURFACE STRUCTURE
Cataluminescence Performance on Catalysts of Graphene Supported Platinum
WU Xiao-Qin, ZONG Rui-Long, MU Hao-Jie, ZHU Yong-Fa
Platinum nanoparticles supported by graphene were prepared by the colloid deposition process. The effects of particle si...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3002-3008.
DOI: 10.3866/PKU.WHXB20101010
6488
Abstract/Metrics
3509
PDF(1991KB)
Deactivation of MnO
x
-CeO
x
/ACF Catalysts for Low-Temperature NH
3
-SCR in the Presence of SO
2
SHEN Bo-Xiong, LIU Ting
The low-temperature selective catalytic reduction of NO with NH3 (NH3-SCR) over MnOx-CeOx/ACF (activated carbon fiber) m...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3009-3016.
DOI: 10.3866/PKU.WHXB20101120
4868
Abstract/Metrics
2349
PDF(1038KB)
Carbon Deposition on a Toluene Disproportionation and Transalkylation Catalyst
MENG Gen, KONG De-Jin, QI Xiao-Lan, XU Zhong-Qiang
The nature of carbon deposition on a toluene disproportionation and transalkylation catalyst was characterized using the...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3017-3022.
DOI: 10.3866/PKU.WHXB20101118
6540
Abstract/Metrics
1901
PDF(1056KB)
Dynamic Performance of CO
2
Adsorption with Amine-Modified SBA-16
SHI Jing-Jin, LIU Ya-Min, CHEN Jie, ZHANG Yu, SHI Yao
Novel CO2 adsorbents for CO2 removal were prepared by introducing tetraethylenepentamine (TEPA) into SBA-16 type mesopor...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3023-3029.
DOI: 10.3866/PKU.WHXB20101109
5871
Abstract/Metrics
2096
PDF(1349KB)
PHOTOCHEMISTRY AND SPECTROSCOPY
XPS Study of the Thickness Nanosize Effect for Ultrathin SiO
2
on Si Substrate
ZHAO Zhi-Juan, LIU Fen, ZHAO Liang-Zhong
X-ray photoelectron spectroscopy (XPS) was used to record the Si 2p and valence band spectra for a series of ultrathin S...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3030-3034.
DOI: 10.3866/PKU.WHXB20101111
6265
Abstract/Metrics
1867
PDF(201KB)
Effect ofWater Ligation on the Redox Potential and Infrared Spectra of Chlorophyll-
a
HU Qiong, WANG Guo-Ying, OU Jia-Ming, WANG Rui-Li
In the reaction center of photosystem I the accessory electron transfer cofactors are two monomeric chlorophyll-a molecu...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3035-3040.
DOI: 10.3866/PKU.WHXB20101116
6586
Abstract/Metrics
1966
PDF(704KB)
QUANTUM CHEMISTRY AND COMPUTATION CHEMISTRY
Molecular Dynamics Simulation of Corrosive Medium Diffusion in Corrosion Inhibitor Membrane
QIAO Gui-Min, REN Zhen-Jia, ZHANG Jun, HU Song-Qing, YAN You-Guo, TI Yang
The corrosion inhibition mechanism of four 1-R1-2-undecyl-imidazoline inhibitors (R1: CH2COOH (A), CH2CH2OH (B), CH2CH2N...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3041-3046.
DOI: 10.3866/PKU.WHXB20101020
5921
Abstract/Metrics
2313
PDF(1573KB)
Adsorption Behavior of NO on Cu
3
Pt(111) Surface
XIE Xiu-Juan, CHEN Wen-Kai, SUN Bao-Zhen, GUO Xin, ZHANG Yong-Fan
The adsorption behavior of NOonto a Cu3Pt (111) surface was studied using a periodic slab model and the PW91 generalized...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3047-3051.
DOI: 10.3866/PKU.WHXB20101122
6855
Abstract/Metrics
2064
PDF(1308KB)
Electronic Structure and Optical Properties of the Novel Nonlinear LiAsSe
2
Crystal
NI Bi-Lian, ZHOU He-Gen, JIANG Jun-Quan, LI Yi, ZHANG Yong-Fan
We used density functional theory based on the pseudo-potential plane wave basis set to investigate the electronic struc...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3052-3060.
DOI: 10.3866/PKU.WHXB20101115
5844
Abstract/Metrics
2301
PDF(2296KB)
Geometric and Electronic Structures of Hexanuclear Binary Ta/Rh Mixed Clusters
CAO Fei, TAN Kai, LIN Meng-Hai
Density functional theory (DFT) was employed to investigate the geometric and electronic properties of a series of hexan...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3061-3066.
DOI: 10.3866/PKU.WHXB20101112
5451
Abstract/Metrics
1882
PDF(3987KB)
Effects of CH
3
OH and NH
3
on the Hydrolytic Deamination Mechanismof Adenine
LIU Hai-Ying, MENG Fan-Cui, LI Ping, DING Shi-Liang
The effects of CH3OH and NH3 on the hydrolytic deamination mechanism of adenine were studied by density functional theor...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3067-3072.
DOI: 10.3866/PKU.WHXB20101106
5113
Abstract/Metrics
1635
PDF(1146KB)
PHYSICAL CHEMISTRY OF MATERIALS
Synthesis and Nonlinear Optical Properties of Fluorinated Polyimides Containing Benzothiazole
HE Man, ZHOU Yu-Ming, MIAO Jun-Liang, LIU Cheng, FANG Cheng, CUI Yi-Ping, ZHANG Tong
Hetarylazo chromophores were incorporated into fluorinated polyimide matrices to prepare novel nonlinear optical (NLO) s...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3073-3079.
DOI: 10.3866/PKU.WHXB20101127
4839
Abstract/Metrics
1790
PDF(1024KB)
Purification of Multiwalled Carbon Nanotubes and Characterization of Their Oxygen-Containing Surface Groups
ZHOU Jin-Mei, LI Hai-Yan, LIN Guo-Dong, ZHANG Hong-Bin
We conveniently removed the Ni-MgO catalyst components from an as-grown multiwalled carbon nanotube (CNT) using an aqueo...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3080-3086.
DOI: 10.3866/PKU.WHXB20101108
6325
Abstract/Metrics
2695
PDF(961KB)
Preparation and Characterization of One-Dimensional TiO
2
Nanowire Films on a Flexible Stainless Steel Substrate
WU Tao, TAO Jie, DENG Jie, TANG Yu-Xin, ZHU Hong, GAO Peng
We synthesized a one dimensional (1D) TiO2 nanowire with a large aspect ratio on non-Ti substrate in NaOH aqueous soluti...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3087-3094.
DOI: 10.3866/PKU.WHXB20101103
5693
Abstract/Metrics
2805
PDF(5380KB)
Synthesis, Formation Mechanism and Surface-Enhanced Raman Scattering Properties of Silver Tangled Nanowires and Dendritic Structures
WU Xin-Zhou, PEI Mei-Shan, WANG Lu-Yan, LI Xiao-Nan, TAO Xu-Tang
Silver tangled nanowires and dendritic structures were readily synthesized in high yield by reducing silver nitrate with...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3095-3100.
DOI: 10.3866/PKU.WHXB20101132
6123
Abstract/Metrics
2619
PDF(5769KB)
Preparation and Triethylamine Sensing Properties of Ce-Doped In
2
O
3
Nanofibers
WANG Jin-Xing, YU Lian-Xiang, WANG Hao-Ming, RUAN Sheng-Ping, LI Jia-Jing, WU Feng-Qing
Ce-doped In2O3 nanofibers were synthesized by a simple and effective electrospinning method. The morphology and crystal ...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3101-3105.
DOI: 10.3866/PKU.WHXB20101126
5701
Abstract/Metrics
2210
PDF(1230KB)
Fabrication of Al
2
O
3
Nanoparticles by Cathodic Plasma Electrolysis
LI Zhao-Hu, ZHANG Zhi-Kun, GUO Deng-Zhu
We used aluminum as the cathodic material and an aqueous solution of 3 mol·L-1 NH4NO3 as the electrolyte in our w...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3106-3112.
DOI: 10.3866/PKU.WHXB20101114
4926
Abstract/Metrics
2291
PDF(1133KB)
Synthesis, Characterization and Surface Functionalization of Novel Spindle-Like α-Fe
2
O
3
Nanocrystals
ZHAN Yong-Gong, CHEN Qi-Yuan, YIN Zhou-Lan, LI Li-Li, CAI Bing-Xin
We synthesized novel α-Fe2O3 nanocrystals (NFO-1) with single crystalline structure. In our synthetic strategy, th...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3113-3119.
DOI: 10.3866/PKU.WHXB20101119
5260
Abstract/Metrics
Supporting Info
1991
PDF(1756KB)
Magnetite Sub-Microspheres with Controlled Diameter and Magnetic Properties Synthesized by the Citrate-Assisted Polyol Process
YAN Gong-Qin, WANG Wei, SUN Zhi-Gang, GUAN Jian-Guo
Monodispersed superparamagnetic magnetite (Fe3O4) sub-microspheres with controlled grain sizes and diameters were obtain...
Acta Phys. -Chim. Sin. 2010, 26 (11), 3120-3126.
DOI: 10.3866/PKU.WHXB20101027
4890
Abstract/Metrics
2480
PDF(2661KB)