Acta Phys. -Chim. Sin.

Table of Contents

Cover and Table of Contents for Vol.30 No. 4
Acta Phys. -Chim. Sin. 2014, 30 (4), 0.

REVIEW

Progress in the Application of Diazine Compounds in Optoelectronic Functional Materials
MEI Qun-Bo, WENG Jie-Na, TONG Bi-Hai, TIAN Ru-Qiang, JIANG Yuan-Zhi, HUA Qing-Fang, HUANG Wei
As a new and developing field, organic electronics is attracting much attention and has contributed greatly to progress ...
Acta Phys. -Chim. Sin. 2014, 30 (4), 589-607. DOI: 10.3866/PKU.WHXB201402182

THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY

Crystal Fine Structure and Optical Rotatory Angle Study on Spin Superfluidity of Intermolecular N⁺H…O^-Hydrogen Bond Electron Cooper Pairing onto D-, L-, and DL-Valine Optical Lattices
WANG Wen-Qing, ZHANG Yu-Feng, GONG Yan
With a view to understanding the argument of the phase transition mechanisms of D- and Lvaline around 270 K, the tempera...
Acta Phys. -Chim. Sin. 2014, 30 (4), 608-622. DOI: 10.3866/PKU.WHXB201402181

Vibrational Activity Change of Self-Assembled Monolayers upon Chemical Attachment and Nanoscale Block Revealed by Surface Enhanced Raman Spectroscopy
ZHOU Jie, LI Bo-Lin, ZHU Pei-Zhi, LU Xiao-Lin
The origin of weak ambiguous vibrational modes in surface enhanced Raman scattering (SERS), i.e., from the high-order ef...
Acta Phys. -Chim. Sin. 2014, 30 (4), 623-627. DOI: 10.3866/PKU.WHXB201312273

THEORETICAL AND COMPUTATIONAL CHEMISTRY

Comparing Methods for Predicting the Reactive Site of Electrophilic Substitution
FU Rong, LU Tian, CHEN Fei-Wu
Predicting the reactivity of electrophilic substitution at different sites is of theoretical and practical significance,...
Acta Phys. -Chim. Sin. 2014, 30 (4), 628-639. DOI: 10.3866/PKU.WHXB201401211

“External Anchoring Sites” for Noble Metal Nanowires on Deprotonated 1,3-Dipolar Cycloaddition Graphene
CAI Qian, CAI Qiu-Xia, ZHUANG Gui-Lin, ZHONG Xing, WANG Xin-De, LI Xiao-Nian, WANG Jian-Guo
Density functional theory (DFT) calculations were used to study the adsorption of noble metal (Pt) on deprotonated 1,3-d...
Acta Phys. -Chim. Sin. 2014, 30 (4), 640-645. DOI: 10.3866/PKU.WHXB201402131

Dissipative Particle Dynamics Simulation of Multicompartment Micelles Self-Assembled from a Blend of Triblock Copolymers and Diblock Copolymers in an Aqueous Solution
XU Bo-Shen, ZHAO Ying, SHEN Xian-Liang, CONG Yue, YIN Xiu-Mei, WANG Xin-Peng, YUAN Qing, YU Nai-Sen, DONG Bin
A dissipative particle dynamics simulation was performed to study the influence of blending different linear triblock co...
Acta Phys. -Chim. Sin. 2014, 30 (4), 646-653. DOI: 10.3866/PKU.WHXB201402122

Development and Validation of an All-Atom Force Field for the Energetic Materials TATB, RDX and HMX
JIN Zhao, LIU Jian, WANG Li-Li, CAO Feng-Lei, SUN Huai
An all-atom force field was developed and validated for three energetic materials 1,3,5-triamino-2,4,6-trinitrobenzene (...
Acta Phys. -Chim. Sin. 2014, 30 (4), 654-661. DOI: 10.3866/PKU.WHXB201402113

ELECTROCHEMISTRY AND NEW ENERGY

Di-n-alkylphosphinic Acid with a Long Alkyl Chain as a Coadsorbent for Modifying TiO₂ Photoanodes
LI Jing-Zhe, KONG Fan-Tai, WU Guo-Hua, CHEN Wang-Chao, HUANG Yang, FANG Xia-Qin, DAI Song-Yuan
The modification of a TiO2/dye/electrolyte interface can effectively improve the performance of dyesensitized solar cell...
Acta Phys. -Chim. Sin. 2014, 30 (4), 662-668. DOI: 10.3866/PKU.WHXB201401242

Preparation and Electrochemical Performance of 5 V LiNi_0.5Mn_1.5O₄ Cathode Material by the Composite Co-Precipitation Method for High Energy/High Power Lithium Ion Secondary Batteries
ZHU Zhi, QI Lu, LI Wei, LIAO Xi-Ying
This research developed a novel composite co-precipitation method to prepare high performance LiNi0.5Mn1.5O4 based on a ...
Acta Phys. -Chim. Sin. 2014, 30 (4), 669-676. DOI: 10.3866/PKU.WHXB201402102

Synergistic Inhibition Effect of Imidazoline Ammonium Salt and Sodium Dodecyl Sulfate in CO₂ System
ZHANG Chen, ZHAO Jing-Mao
The synergistic inhibition effect of the imidazoline ammonium salt (IAS) and sodium dodecyl sulfate (SDSH) on the corros...
Acta Phys. -Chim. Sin. 2014, 30 (4), 677-685. DOI: 10.3866/PKU.WHXB201402111

Model Simulation and Analysis of Spatiotemporal Dynamics for the Electro-Oxidation of Sulfide on Platinum
YANG Jia-Ping, YU Hui-Yao, HE Yu-Xiu, XIE Jing-Xuan, BI Wen-Yan, GAO Qing-Yu
Based on the reaction mechanism of the electro-oxidation of sulfide on platinum, we propose a simplified model for study...
Acta Phys. -Chim. Sin. 2014, 30 (4), 686-692. DOI: 10.3866/PKU.WHXB201402142

SOFT MATTER

Mixed Cationic and Anionic Surfactant Systems Achieve Ultra-Low Interfacial Tension in the Karamay Oil Field
ZHAO Hai-Na, CHENG Xin-Hao, ZHAO Ou-Di, HUANG Jian-Bin, LIU Chen-Jiang, ZHAO Bo
Based on cationic and anionic surfactant mixed systems, ultra-low interfacial tension was achieved in the Karamay oil fi...
Acta Phys. -Chim. Sin. 2014, 30 (4), 693-698. DOI: 10.3866/PKU.WHXB201402121

Temperature Dependant Mixed Micellization Behavior of a Drug-AOT Mixture in an Aqueous Medium
RUB Malik Abdul, ASIRI Abdullah M, KUMAR Dileep, AZUM Naved, KHAN Farah
The mixed micellization behavior of an amphiphilic antidepressant drug amitriptyline hydrochloride (AMT) in the presence...
Acta Phys. -Chim. Sin. 2014, 30 (4), 699-707. DOI: 10.3866/PKU.WHXB201402112

CATALYSIS AND SURFACE SCIENCE

Synthesis of Quasi-Concave Pt-Ni Nanoalloys via Overgrowth and Their Catalytic Performance towards Methanol Oxidation
WANG Chun, KANG Jian-Xin, WANG Li-Li, CHEN Ting-Wen, LI Jie, ZHANG Dong-Feng, GUO Lin
Quasi-concave Pt-Ni alloy nanostructures were synthesized via a solvothermal method, and were thought to form by epitaxi...
Acta Phys. -Chim. Sin. 2014, 30 (4), 708-714. DOI: 10.3866/PKU.WHXB201401222

Performance of a Metal-Organic Framework MIL-53(Al)-Supported Cobalt Catalyst in the CO Catalytic Oxidation Reaction
TAN Hai-Yan, WU Jin-Ping
Ametal-organic framework (MOF) material MIL-53(Al) (MIL: Materials of Institut Lavoisier) with high thermal stability wa...
Acta Phys. -Chim. Sin. 2014, 30 (4), 715-722. DOI: 10.3866/PKU.WHXB201401221

Effects of Promoter on NiMgAl Catalyst Structure and Performance for Carbon Dioxide Reforming of Methane
GUO Zhang-Long, HUANG Li-Qiong, CHU Wei, LUO Shi-Zhong
Catalysts were prepared by adding different types of promoter (Co, Ir, or Pt) to the supported nickel catalyst NiMgAl sa...
Acta Phys. -Chim. Sin. 2014, 30 (4), 723-728. DOI: 10.3866/PKU.WHXB201402242

Synthesis, Regeneration and Photocatalytic Activity under Visible-Light Irradiation of Ag/Ag₃PO₄/g-C₃N₄ Hybrid Photocatalysts
LIU Jian-Xin, WANG Yun-Fang, WANG Ya-Wen, FAN Cai-Mei
Ag/Ag3PO4/g-C3N4 (g denotes graphitic) was synthesized via an anion-exchange precipitation method, and its photocatalyti...
Acta Phys. -Chim. Sin. 2014, 30 (4), 729-737. DOI: 10.3866/PKU.WHXB201402243

PHOTOCHEMISTRY AND RADIATION CHEMISTRY

Influence of Non-Thermal Plasma Discharge Mode and Reactor Structure on Ammonia Decomposition to Hydrogen
ZHAO Yue, WANG Li, ZHANG Jia-Liang, GUO Hong-Chen
At ambient pressure, the effect of plasma discharge mode and reactor structure on ammonia decomposition to hydrogen was ...
Acta Phys. -Chim. Sin. 2014, 30 (4), 738-744. DOI: 10.3866/PKU.WHXB201402141

Twofold Influence of Nitro Substituent on Aromatic Ring for Photoluminescence Properties of Benzoic Acid-Functionalized Polystyrene and Eu(Ⅲ) Complexes
XU Ze-Qing, GAO Bao-Jiao, HOU Xiao-Dong
Nitrobenzoic acid (NBA) was bound to the side chains of polystyrene (PS) to give nitrobenzoic acidfunctionalized polysty...
Acta Phys. -Chim. Sin. 2014, 30 (4), 745-752. DOI: 10.3866/PKU.WHXB201402101

PHYSICAL CHEMISTRY OF MATERIALS

Modification of Microvoid Defects in Polyacrylonitrile-Based Carbon Fibers by a Liquid Oligomer of Acrylonitrile
CHAI Xiao-Yan, ZHU Cai-Zhen, HE Chuan-Xin, ZHANG Guang-Zhao, LIU Jian-Hong
The strength of industrial carbon fibers (CFs) is far lower than their theoretical strength because of defects in the mi...
Acta Phys. -Chim. Sin. 2014, 30 (4), 753-760. DOI: 10.3866/PKU.WHXB201401241

Photocatalytic Degradation of Gas-Phase Toluene over CuO Loaded BiVO₄ Hollow Nanospheres under Visible-light Irradiation
ZHAO Wei-Rong, ZENG Wan-Yun, XI Hai-Ping, YU Xian-Xian
The sol-gel method was used for the synthesis of BiVO4 hollow nanospheres by employing carbon spheres as a hard template...
Acta Phys. -Chim. Sin. 2014, 30 (4), 761-767. DOI: 10.3866/PKU.WHXB201402132

Effects of Annealing on the Magnetic Properties of [NiFe/Cu/Co/Cu]_n Multilayer Nanowire Arrays
ZHANG Wei-Guo, MA Xiao-Long, XU Yan, YAO Su-Wei, WANG Hong-Zhi
Highly ordered [NiFe/Cu/Co/Cu]n multilayer nanowire arrays were successfully prepared by a combination of electrodeposit...
Acta Phys. -Chim. Sin. 2014, 30 (4), 768-772. DOI: 10.3866/PKU.WHXB201402114

Preparation and Up-Conversion Photoluminescence Properties of GdAlO₃：Er³⁺, Yb³⁺ Phosphors
DENG Tao-Li, YAN Shi-Run, HU Jian-Guo
GdAlO3:Er3+,Yb3+ phosphor was prepared by coprecipitation, sol-gel, and solid-state reaction methods, respectively. The ...
Acta Phys. -Chim. Sin. 2014, 30 (4), 773-780. DOI: 10.3866/PKU.WHXB201402201

Preparation, Characterization and Gas Sensing Mechanism of ZnO-Doped SnO₂ Nanofibers
TANG Wei, WANG Jing, YAO Peng-Jun, DU Hai-Ying, SUN Yan-Hui
SnO2 nanofibers were fabricated by electrospinning, using SnCl2 ·2H2O as the raw material. The influences of ZnO ...
Acta Phys. -Chim. Sin. 2014, 30 (4), 781-788. DOI: 10.3866/PKU.WHXB201402191

Preparation of Polyethylenimine-Functionalized Silica Nanotubes and Their Application for CO₂ Adsorption
YAO Man-Li, DONG Yan-Yan, XIE Jing, JIA Ai-Ping, XIE Guan-Qun, HU Geng-Shen, LUO Meng-Fei
Mesoporous ethane-silica nanotubes (E-SNTs) were synthesized using P123 as a template and 1,2-bis(trimethoxysilyl)ethane...
Acta Phys. -Chim. Sin. 2014, 30 (4), 789-796. DOI: 10.3866/PKU.WHXB201402123