Acta Phys. -Chim. Sin.

Table of Contents

Cover and Table of Contents for Vol.30 No. 9
Acta Phys. -Chim. Sin. 2014, 30 (9), 0.

REVIEW

Research Progress in Radiation Effects on Ionic Liquids
WANG Shuo-Jue, AO Yin-Yong, ZHOU Han-Yang, YUAN Li-Yong, PENG Jing, ZHAI Mao-Lin
Ionic liquids (ILs) are regarded as a new generation of green solvents in spent nuclear fuel reprocessing, because of th...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1597-1604. DOI: 10.3866/PKU.WHXB201406271

THERMODYNAMICS, KINETICS, AND STRUCTURAL CHEMISTRY

Hydrogen-Bonding Interactions between Ionic Liquid 1-Ethyl-3-methylimidazolium Trifluoromethanesulfonate and Water
SONG Da-Yong, CHEN Jing
Attenuated total reflectance infrared (ATR-IR) spectroscopy, two- dimensional correlation spectroscopy, and quantum chem...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1605-1610. DOI: 10.3866/PKU.WHXB201407012

Low-Temperature Synthesis of Superconductor Ba_1-xK_xBiO₃
LIU Meng, LI Guo-Bao, WANG Jia-Guo, LIAO Fu-Hui, LIN Jian-Hua
Ba1-xKxBiO3 (BKBO) was synthesized using a topotactic reaction, which involves a conventional solidstate synthesis of pu...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1611-1615. DOI: 10.3866/PKU.WHXB201406201

THEORETICAL AND COMPUTATIONAL CHEMISTRY

Quantitative Structure-Property Relationship Studies on the Adsorption of Aromatic Contaminants by Carbon Nanotubes
LIU Fen, ZOU Jian-Wei, HU Gui-Xiang, JIANG Yong-Jun
Ab initio calculations have been performed for a group of 59 aromatic compounds at the HF/6-31G* level of theory. Electr...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1616-1624. DOI: 10.3866/PKU.WHXB201406182

Molecular Dynamics Simulation Study of Structural and Transport Properties of Methanol-Water Mixture in Carbon Nanotubes
GAO Wen-Xiu, WANG Hong-Lei, LI Shen-Min
Molecular dynamics simulations of a methanol-water mixture (molar ratio 1:1) were performed to determine the differences...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1625-1633. DOI: 10.3866/PKU.WHXB201407031

ELECTROCHEMISTRY AND NEW ENERGY

Pyrazolyl Magnesium Halide/Tetrahydrofuran Solutions for Rechargeable Magnesium Battery Electrolytes
FEILURE Tuerxun, ZULIPIYA Shadike, NULI Yan-Na, YANG Jun, WANG Jiu-Lin
Pyrazolyl magnesium halide/tetrahydrofuran (THF) solutions were obtained by the simple reaction of pyrazole compounds wi...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1634-1640. DOI: 10.3866/PKU.WHXB201407101

Preparation and Electrochemical Performances of Li_1.2Mn_0.54-xNi_0.13Co_0.13Zr_xO₂ Cathode Materials for Lithium-Ion Batteries
REN Xiang-Zhong, LIU Tao, SUN Ling-Na, ZHANG Pei-Xin
To improve the cycling performance of lithium-rich cathode materials, Li1.2Mn0.54Ni0.13Co0.13O2 and Li1.2Mn0.54-xNi0.13C...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1641-1649. DOI: 10.3866/PKU.WHXB201406172

Fe₃O₄/Graphene Composites with a Porous 3D Network Structure Synthesized through Self-Assembly under Electrostatic Interactions as Anode Materials of High-Performance Li-Ion Batteries
LIU Jian-Hua, LIU Bin-Hong, LI Zhou-Peng
Fe3O4/graphene composites with a conductive, porous three-dimensional (3D) graphene network were synthesized through a f...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1650-1658. DOI: 10.3866/PKU.WHXB201406181

Preparation and Electrochemical Properties of Functionalized Graphene/Polyaniline Composite Electrode Materials
WANG Li-Li, XING Rui-Guang, ZHANG Bang-Wen, HOU Yuan
Octadecylamine functionalized graphene (ODA-G) was synthesized by the grafting of graphene oxide (GO) with ODA followed ...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1659-1666. DOI: 10.3866/PKU.WHXB201406162

Effects of Surface Modification with Ag/C on Electrochemical Properties of Li[Li_0.2Mn_0.54Ni_0.13Co_0.13]O₂
XUE Qing-Rui, LI Jian-Ling, XU Guo-Feng, HOU Peng-Fei, YAN Gang, DAI Yu, WANG Xin-Dong, GAO Fei
A lithium-rich solid-solution layered cathode material, Li[Li0.2Mn0.54Ni0.13Co0.13]O2, was synthesized using a fast co-p...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1667-1673. DOI: 10.3866/PKU.WHXB201406251

Electrochemical Co-Reduction Extraction of Neodymium in LiCl-KCl-ZnCl₂ Molten Salt System
XUE Yun, ZHOU Zhi-Ping, YAN Yong-De, ZHANG Mi-Lin, LI Xing, JI De-Bin, HAN Wei, ZHANG Meng
This work focused on the electrochemical behavior of Nd(Ⅲ) and the formation of Zn-Nd alloys on Mo electrodes in LiCl-KC...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1674-1680. DOI: 10.3866/PKU.WHXB201407022

Anomalous IR Optical Properties of Monodispersed PtNi Nanoparticles
ZHOU Xin-Wen, DU Juan-Juan, SUN Shi-Gang
Monodispersed PtNi nanoparticles were synthesized by galvanic displacement reaction and chemical reduction. The monodisp...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1681-1687. DOI: 10.3866/PKU.WHXB201406193

SOFT MATTER

Two-Component Supramolecular Organogels Formed from L-Phenylalanine Derivatives and Aliphatic Amines
ZHONG Jin-Lian, PAN Hong, LUO Xu-Zhong, HONG San-Guo, ZHANG Ning, HUANG Jian-Bin
A series of monochain L-phenylalanine derivatives were synthesized. L-Phenylalanine derivatives have no gelation abiliti...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1688-1696. DOI: 10.3866/PKU.WHXB201407041

CATALYSIS AND SURFACE SCIENCE

Photocatalytic Oxidation of Ammonia via an Activated Carbon-Nickel Ferrite Hybrid Catalyst under Visible Light Irradiation
XIAO Bo, LIU Shou-Qing
The nickel atoms in a metal ferrite lattice inhibit photocatalytic activity with hydrogen peroxide. However, activated c...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1697-1705. DOI: 10.3866/PKU.WHXB201407111

Preparation of Fe-Doped Graphitic Carbon Nitride with Enhanced Visible-Light Photocatalytic Activity
JIN Rui-Rui, YOU Ji-Guang, ZHANG Qian, LIU Dan, HU Shao-Zheng, GUI Jian-Zhou
A series of Fe-doped graphitic carbon nitride (g-C3N4) photocatalysts were prepared using ferric nitrate and melamine as...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1706-1712. DOI: 10.3866/PKU.WHXB201406272

Synthesis of Single-Crystalline Cu₃B₂O₆/CuB₂O₄ and Their Photocatalytic Degradation of Methylene Blue under Visible-Light Irradiation
CHEN Ai-Min, BO Ying-Ying, SHAO Chen-Yi, WANG Jing, HU Jun
Single-crystalline Cu3B2O6/CuB2O4 was successfully prepared by a sol-gel method fromcupric nitrate/ cupric acetate and b...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1713-1719. DOI: 10.3866/PKU.WHXB201407011

Facile Synthesis of Graphene-Cobalt Hydroxide Nanocomposite and Application in Degradation of Acid Orange 7
LI Jie-Bing, YI Yu, SHI Peng-Hui, WANG Qian, LI Deng-Xin, ASIF Hussain, YANG Ming
In this study, a cobalt hydroxide-reduced graphene oxide (Co(OH)2/rGO) composite was synthesized by one-step self-assemb...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1720-1726. DOI: 10.3866/PKU.WHXB201407021

Synthesis of Micro-Sized MEL-Type Zeolite Aggregates
CHEN Hong-Li, ZHU Shu-Yan, HE Jian-Qin, WANG Yi-Meng
Hierarchical micro-sized zeolite aggregates with the MEL structure were prepared hydrothermally froma tetrabutylammonium...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1727-1735. DOI: 10.3866/PKU.WHXB201407081

Selective Oxidation of Ethane to Aldehydes over Potassium-Promoted SBA-15-Supported Molybdenum Oxide Catalysts
LI Jian-Mei, LIU Jian, REN Li-Wei, LIU Qing-Long, ZHAO Zhen, WEI Yue-Chang, DUAN Ai-Jun, JIANG Gui-Yuan
Potassium-modified SBA-15-supported molybdenum oxide catalysts were prepared using a twostep impregnation method. The ph...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1736-1744. DOI: 10.3866/PKU.WHXB201407091

Effect of Trace Amounts of Li Doping on Performance of Co/AC Catalysts for Syntheses of Mixed Linear α-Alcohols
DONG Wen-Da, ZHU He-Jun, DING Yun-Jie, PEI Yan-Peng, DU Hong, WANG Tao
15CoxLi/AC catalysts promoted by different trace amounts of Li doping were prepared by incipientwetness impregnation. Th...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1745-1751. DOI: 10.3866/PKU.WHXB201405301

PHOTOCHEMISTRY AND RADIATION CHEMISTRY

Fluorescent Emissions (1800 nm) of LiLuF₄ Single Crystals Doped with Various Tm³⁺ Concentrations
LI Shan-Shan, XIA Hai-Ping, FU Li, DONG Yan-Ming, ZHANG Jia-Zhong, GU Xue-Mei, ZHANG Jian-Li, WANG Dong-Jie, JIANG Hao-Chuan, CHEN Bao-Jiu
LiLuF4 single crystals doped with molar fractions of 0.45%, 0.90%, 1.63%, and 3.25% (x, molar fraction) Tm3+ ions were f...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1752-1757. DOI: 10.3866/PKU.WHXB201406183

Influence of Different Pyramidal Structural Morphologies of Crystalline Silicon Wafers for Surface Passivation and Heterojunction Solar Cells
WANG Li-Guo, ZHANG Xiao-Dan, WANG Feng-You, WANG Ning, JIANG Yuan-Jian, HAO Qiu-Yan, XU Sheng-Zhi, WEI Chang-Chun, ZHAO Ying
Silicon heterojunction (SHJ) solar cells consisting of a hydrogenated amorphous silicon (a-Si:H) film deposited on a cry...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1758-1763. DOI: 10.3866/PKU.WHXB201406301

PHYSICAL CHEMISTRY OF MATERIALS

Effects of Pore-Size Range and Composition of Polysaccharide Gels on Flow Behaviors and Selective Sorting of Single-Walled Carbon Nanotubes
YANG Peng, TAN Fu-Rui, ZHANG Jing, JIN He-Hua, LI Hong-Bo, LIU Chun-Hua, LI Qing-Wen
We used gel-column chromatography to show the effects of the pore-size range and chemical composition of porous polysacc...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1764-1770. DOI: 10.3866/PKU.WHXB201407032

Wavelength-Interrogated Surface Plasmon Resonance Sensor Based on Au-Ag Alloy Film
ZHANG Zhe, LIU Jie, LU Dan-Feng, QI Zhi-Mei
An Au-Ag alloy film surface plasmon resonance (SPR) sensor was studied experimentally and theoretically. SPR chips were ...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1771-1777. DOI: 10.3866/PKU.WHXB201407071

Preparation of Nitrogen-Doped Graphene and Its Electrocatalytic Activity for Oxygen Reduction Reaction
PENG San, GUO Hui-Lin, KANG Xiao-Feng
Nitrogen-doped graphene (NG) was prepared by chemical reduction of graphene oxide (GO) using dimethyl ketoxime (DMKO) as...
Acta Phys. -Chim. Sin. 2014, 30 (9), 1778-1786. DOI: 10.3866/PKU.WHXB201407112