极长与极短的铜铜距离-吡唑环三核亚铜配合物亲铜作用本质及发光调控
Extreme Long and Extreme Short Cu-Cu Distances:Nature of Cuprophilicity and Luminescence Modification in Cu (Ⅰ)-based Cyclic Trinuclear Complexes
极长与极短的铜铜距离-吡唑环三核亚铜配合物亲铜作用本质及发光调控 |
| 郑霁,邢立锐,李丹 |
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Extreme Long and Extreme Short Cu-Cu Distances:Nature of Cuprophilicity and Luminescence Modification in Cu (Ⅰ)-based Cyclic Trinuclear Complexes |
| Ji ZHENG,Li-Rui XING,Dan LI |
| 图3 (a)十四核配合物的晶体在不同温度及不同激发波长的紫外灯下的发光照片、(b)290 nm激发下的发射光谱(箭头表示最大发射波长处的强度变化)及(c)工作曲线 |
| Fig 3 (a) Visual temperature monitor of the tetradecanuclear complex under UV lamp with different λex; (b) temperature-varied emission spectra excited at 290 nm (Arrows indicate the intensity changes at λemmax); (c) Working curves |
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