极长与极短的铜铜距离-吡唑环三核亚铜配合物亲铜作用本质及发光调控
Extreme Long and Extreme Short Cu-Cu Distances:Nature of Cuprophilicity and Luminescence Modification in Cu (Ⅰ)-based Cyclic Trinuclear Complexes
极长与极短的铜铜距离-吡唑环三核亚铜配合物亲铜作用本质及发光调控 |
| 郑霁,邢立锐,李丹 |
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Extreme Long and Extreme Short Cu-Cu Distances:Nature of Cuprophilicity and Luminescence Modification in Cu (Ⅰ)-based Cyclic Trinuclear Complexes |
| Ji ZHENG,Li-Rui XING,Dan LI |
| 图4 (a)Br-α的分子弯曲，以红色、绿色和蓝色分别显示覆盖在一起的Br-α (100 K)、优化的二聚体及单体的模型；(b)Br-α(100 K)的晶体结构中的二聚体；(c)优化的二聚体结构 |
| Fig 4 (a) Molecular shape curving in Br-α (100 K), shown in red and overlaid with optimized dimer (in green) and monomer (in blue) models. Comparison of dimer packing from (b) crystal structure and (c) optimization |
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