溶胶-凝胶法设计与制备金属及合金纳米材料的研究进展

王庆庆,王锦玲,姜胜祥,李平云

Recent Progress in Sol-Gel Method for Designing and Preparing Metallic and Alloy Nanocrystals

Qingqing WANG,Jinling WANG,Shengxiang JIANG,Pingyun LI

表1 溶胶-凝胶法制备的金属材料

Table 1 Metallic nanocrystals being prepared by Sol-gel method.

Metallic material Solvent Chelating agent Calcination atmosphere Calcination Temperature/℃ Crystal structure Reference Ni N, N-imethylformamide L-isoleucine Ar 300-750 FCC, HCP 11 Ni Distilled water Citric acid Ar 400 FCC 12 Ni Distilled water Citric acid Ar or N2 300 FCC 13 Ni Ethylene glycol Citric acid H2 600 FCC 14 Ni Deionized water Citric acid, EDTA etc. N2 350-550 FCC, HCP 20 Ni Deionized water Gelatin N2 350-550 FCC, HCP 21 Ni Deionized water Citric acid N2 350-550 FCC 22 Ni Deionized water Acrylamide N2 350-550 FCC 23 Ni Deionized water Lactic acid N2 350-550 FCC, HCP 24 Ni Ethanol, Isopropanol,Pentanol etc. Citric acid N2 350-550 FCC, HCP 25 Ni Ethanol Citric acid Air 400 FCC 26 Ni Ethanol, Acetone,N-propanol Citric acid, Tartaric acid N2 350-550 FCC, HCP 27 Ni Ethanol Citric acid N2 350-550 FCC, HCP 28 Ni Deionized water Citric acid, EDTA N2 350-550 FCC 29 Ni Deionized water Citric acid Ar 300-400 FCC, HCP 31 Ni Deionized water Citric acid Ar 320-900 FCC, HCP 32 Ni Deionized water Citric acid Ar 320-900 FCC, HCP 33 Ni Deionized water Glycine Air Ignite FCC 43 Ni Deionized water Hexamethylenetetramine Air Ignite FCC 44 Ni Deionized water Glycine Ar 650 FCC 45 Ni Deionized water Glycine Air Ignite FCC 46 Ni Deionized water Glycine Air Ignite FCC 47 Ni Deionized water 2-methoxymethanol Air Ignite FCC 48 Ni Deionized water Glycine Air 400 FCC 49 Ni Deionized water Glycine Air 400 FCC 50 Ni Deionized water Glycine Air Ignite FCC 51 Co Deionized water Citric acid Ar 300 FCC 13 Co Deionized water Citric acid, EDTA etc. N2 600-800 FCC 21 Co Deionized water Hexamethylenetetramine Air 500-590 FCC 52 Cu Deionized water Citric acid Ar 300 FCC 13 Cu Deionized water Starch, EDTA etc. N2 350-550 FCC 20 Cu Deionized water Gelatin N2 350-550 FCC 21 Cu Deionized water Glycine Ar 600 FCC 45 Cu Deionized water Glycine Air Ignite FCC 50 Cu Deionized water Hexamethylenetetramine Air Ignite FCC 53 Bi Deionized water Citric acid Ar 300 Orthorhombic 13 Bi Ethylene glycol Citric acid, Gelatin N2 350-550 Orthorhombic 21 Sb Ethylene glycol Citric acid, Gelatin N2 350-550 Orthorhombic 21 Te Deionized water Citric acid, Gelatin etc. N2 350-550 HCP 21 Ag Deionized water Gelatin N2 350-550 FCC 21 Pt Deionized water Starch N2 350-550 FCC 20 Pd Deionized water Starch N2 350-550 FCC 20 Cd Deionized water Glucose N2 350-450 HCP 21 Sn Deionized water Glucose N2 900 Quartet 21 Ni-Cu Deionized water Glycine Air 400 FCC 50 Ni-Cu Deionized water Citric acid H2 500 FCC 54 Cu-Pt Deionized water Starch N2 350-550 FCC 20 Ni-Pt Deionized water Starch N2 350-550 FCC 20 Bi-Sb Ethylene glycol Citric acid, Gelatin N2 350-550 Orthorhombic 21 Ni3Sn Deionized water Citric acid N2 350-550 FCC 22 Ni-Co Deionized water Citric acid N2 300 FCC 13 Ni-Co Deionized water Citric acid N2 350-550 FCC 29 Ni3Fe N, N-dimethylformamide L-isoleucine Ar 300-750 FCC 10 Ni3Fe Ethanol Citric acid H2 350-550 FCC 30 Ni3Fe Deionized water Citric acid N2 350-550 FCC 29 Bi2Te3 Ethylene glycol Citric acid, Gelatin N2 350-550 Orthorhombic 21 Sb2Te3 Ethylene glycol Citric acid, Gelatin N2 350-550 Orthorhombic 21 Ag2Te Deionized water Gelatin N2 350-550 Monoclinic 21 NiTe1.5 Deionized water Citric acid, Gelatin N2 350-550 HCP 21 In2Te3 Deionized water Citric acid N2 450 FCC 21 SnTe Deionized water Citric acid N2 450 FCC 21 SnSb Ethylene glycol Citric acid N2 450 Orthorhombic 21 CoTe2 Deionized water Citric acid, Gelatin N2 350-550 Orthogonal 21 CdTe Deionized water Citric acid, Gelatin N2 350-550 FCC 21 CoPt Deionized water Citric acid Ar 700-800 L10 34 CoPt Deionized water Citric acid Ar 700 L10 35 CoPt Deionized water Citric acid Ar 800 L10 36 CoPt-Cu Deionized water Citric acid Ar 600 L10 37 CoPt Deionized water Citric acid Ar 700 L10 38 FePt Ethanol Citric acid H2 470 L10 8 FePt Ethanol Citric acid H2 370-680 L10 9 FePt Deionized water Citric acid Ar 700 L10 19 FePt Deionized water Citric acid Ar 700 L10 39 FePt-Cu Deionized water Citric acid Ar 650 L10 40 FePt Deionized water Citric acid Ar 700 L10 41 FePt Deionized water Citric acid Ar 400-700 L10 42 Ni2.9SnTe2 Deionized water Citric acid N2 350-550 L10 21 CuGaTe2 Deionized water Citric acid N2 450 Quartet 21 CoCrCuNiAl Deionized water Citric acid H2 300-1000 FCC+ BCC 55