过渡金属参与C―H键切断模式的理论研究进展
Theoretical Advances of Transition Metals Mediated C―H Bonds Cleavage
Adapted from RSC publisher 40. Computational method: DFT with the M06-2X functional in dichloromethane solvent. The bond lengths are in angstroms.
过渡金属参与C―H键切断模式的理论研究进展 |
| 单春晖,白若鹏,蓝宇 |
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Theoretical Advances of Transition Metals Mediated C―H Bonds Cleavage |
| Chunhui SHAN,Ruopeng BAI,Yu LAN |
| 图12 Ni参与的磺酰酮亚胺酯的炔基化反应中的Friedel-Crafts型亲电芳香取代模式的C―H键切断步的势能面 Adapted from RSC publisher 40. Computational method: DFT with the M06-2X functional in dichloromethane solvent. The bond lengths are in angstroms. |
| Fig 12 Free energy profiles for the C―H bond cleavage step of Ni-mediated alkynylation of N-sulfonyl α-ketiminoesters by Friedel-Crafts-type electrophile substitution |
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