碱性介质中氢氧化和析氢反应机理研究现状
李孟婷, 郑星群, 李莉, 魏子栋

Research Progress of Hydrogen Oxidation and Hydrogen Evolution Reaction Mechanism in Alkaline Media
Mengting Li, Xingqun Zheng, Li Li, Zidong Wei
图4 (a) Au(111)表面的HOR极化曲线(黑色)和CVs曲线(灰红虚线);(b) 0.1 mol∙L−1 KOH溶液中分别滴加0、3、6和9 mL 5 mmol∙L−1 RuCl3溶液时Pt/C和Pt1Ru1/C的HOR极化曲线;(c) Ar饱和的KOH溶液中加入不同量的RuCl3时Pt/C的CO溶出伏安曲线;(d) Pd/Ni的结构示意图(左),Pd/Ni表面的双功能催化作用(右)
Fig 4 (a) HOR polarization curves (black) and CVs (dashed grey and red) for Au(111); (b) HOR polarization curves of Pt/C with 0, 3, 6 and 9 mL doped 5 mmol∙L−1 RuCl3 and Pt1Ru1/C collected in 0.1 mol∙L−1 KOH electrolyte; (c) CO stripping voltammograms collected for Pt/C with various amount of deposited RuCl3 in Ar-saturated 0.1 mol∙L−1 KOH; (d) schematic diagram of Pd/Ni structure (left), and a zoom-in to show the bifunctional catalytic effect of the Pd/Ni surface (right).
(a) Adapted with permission 35, Copyright 2013, Nature Publishing Group. (b, c) Adapted with permission 37, Copyright 2017, Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. (d) Adapted with permission 44, Copyright 2016, Elsevier BV.