碱性介质中氢氧化和析氢反应机理研究现状
李孟婷, 郑星群, 李莉, 魏子栋

Research Progress of Hydrogen Oxidation and Hydrogen Evolution Reaction Mechanism in Alkaline Media
Mengting Li, Xingqun Zheng, Li Li, Zidong Wei
图7 不同金属表面有无OH*时(a) H*和(b) OH*的吸附能;(c) Pt(110)和(d) PtRu(110)上不同电极电势(U,V vs NHE)下,有无OH*时,HOR基本反应步骤和OH*形成的吉布斯自由能变图
Fig 7 Adsorption energies of (a) H* and (b) H2O* on different metals surfaces with and without OH*; Gibbs free energy change of HOR elementary reaction steps and OH* formation at varied electrode potentials (U, V vs NHE) on (c) Pt(110) and (d) PtRu(110) with and without OH*.
(a–d) Adapted with permission 65, Copyright 2019, American Chemical Society.