碳纳米管纤维的连续制备及高性能化
吴昆杰, 张永毅, 勇振中, 李清文

Continuous Preparation and Performance Enhancement Techniques of Carbon Nanotube Fibers
Kunjie Wu, Yongyi Zhang, Zhenzhong Yong, Qingwen Li
表1 碳纳米管纤维力学增强方法与增强效果
Table 1 Summary of the efficient enhancement methods for mechanical property of CNTFs.
Enhancement methods for mechanical property of CNT fibersStrength (GPa)Specific strength (N?tex?1)Ref.
FCCVD CNT fibers
CNT alignment by high collecting speed, controlling the gauge length–963
CNT alignment by high collecting speed, densification by mechanical rolling9.6–16
Controlling the CNT length and alignment during FCCVD process–3.148
Stretching with the aid of chlorosulfonic acid4.08–89
Controlling the growth condition of FCCVD, stretching with the aid of chlorosulfonic acid–6.492
Combining with BMI resin, mechanical stretching3.08–84
Combining with polymer and in-situ cross-linking under tension–3.5123
Combining with BMI resin, multi-step stretching6.94–86
Mechanical densification, combining with epoxy resin5.2–101
Densification by mechanical rolling5.53–47
Densification by twisting3.7–99
CNT bonding by Joule heating under tension3.2–118
Covalent bonding between CNTs with small molecules–3.7127
Array spinning CNT fibers
Spinning from ultra-long CNT arrays1.068–75
Controlling wall number and diameter of CNT1.23–58
Controlling the alignment and length of CNT array3.3–33
Controlling waviness morphology of CNT array1.3–81
Twisting, mechanical stretching1.1–39
Alignment and densification by evaporation of solvent under tension3.2–100
Alignment by “Microcombing”3.2–78
Infiltrating with adhesive polymer, heat-induced crosslinking2.2–115
Forming CNT/C composite by infiltrating with poly-dopamine, pyrolysis4.04–116
Combining with Al/Cu by sputtering, heat-induced diffusion6.6–112
Wet spinning CNT fibers
Spinning from liquid crystal CNT dope, using long CNT4.2–17
Spinning from liquid crystal CNT dope, controlling CNT aspect ratio2.4–72
Spinning from liquid crystal CNT dope1–25
Combining with PVA, hot stretching1.4–1.8–87