物理化学学报 >> 1986, Vol. 2 >> Issue (05): 457-460.doi: 10.3866/PKU.WHXB19860511

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计算机模拟动力学模型改进光化学反应量子产率的测定

刘文渊; 王岩; 曹红; 宋心琦   

  1. 清华大学化学与化学工程系
  • 收稿日期:1985-07-20 修回日期:1986-01-02 发布日期:1986-10-15

IMPROVEMENT OF THE DETERMINATION OF QUANTUM YIELD IN PHOTOCHEMISTRY REACTION BY USING SIMULATIVE KINETIC MODEL ON COMPUTER

Liu Wenyuan; Wang yan; Cao Hong; Song Xinqi   

  1. Department of Chemistry and chemical Engineering; Tsinghua University; Beijing
  • Received:1985-07-20 Revised:1986-01-02 Published:1986-10-15

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Abstract: Under ordinary conditions, azobenzene exists mainly as transisomer, and its photoisomerism is well known. In this work, We determined the quantum yield of this isomerization reaction by using simulative kinetic model on computer. We suggested a kinetic equation for azobenzene isomerization as
E=E_∞-Aexp(-Bt~σ)
In which, E and E_∞ are the absorbance of the azobenzene solution under radiation and photostatic state respectively, t is the radiation time A, B, C are emperical parameters. The kinetic equation can be solved by computer with a program written by ourselves, the values obtained were fitted to the practical data well.
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