物理化学学报 >> 1985, Vol. 1 >> Issue (05): 476-481.doi: 10.3866/PKU.WHXB19850513

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混合溶剂中混合电解质活度系数的研究——HCl+NaCl+PrOH+H2O体系, 298.15 K

初明晨; 杨家振; 梁春余; 郑溪娟; 诸若瑶   

  1. 辽宁大学化学系, 沈阳
  • 收稿日期:1984-10-22 修回日期:1985-05-29 发布日期:1985-10-15

STUDIES OF ACTIVITY COEFFICIENTS OF MIXED ELECTROLYTES IN MIXED SOLVENTS System of HCI+NaCI+PrOH+H2O, at 298.15 K

Chu Mingchen; Yang Jiazhen; Liang Chunyu; Zheng Xijuan; Zhu Ruoyao   

  1. Department of Chemistry, Liaoning University, Shenyang
  • Received:1984-10-22 Revised:1985-05-29 Published:1985-10-15

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Abstract: This paper reports our studies on HCl+NaCl+PrOH+H_2O system by mesns of emf measurements of the cell without liquid junction as type (A)
Pt, H_2 (latm) |HCI (m_A), NaCl (m_B), PrOH(x), H_2O(1-x)| AgCl-Ag (A)
at constant total ionic strengths I=0.1, 0.5, 1.0, 2.0 and 3.0 mol kg~(-1), at 298.15 K, where m_A and m_B are the molalities of HCl and NaCl, respectively, x is the molar fraction of PrOH in mixed solvents, x=0.05.
The results show that HCI approximately follows Harned's Rule from I=0.1 to 3.0 mole kg~(-1)...