物理化学学报 >> 2006, Vol. 22 >> Issue (10): 1300-1304.doi: 10.1016/S1872-1508(06)60063-6

综述 上一篇    

纳米级无机聚钼酸盐“二级有序聚集体”

贾祥凤;范大伟;唐培芹;郝京诚;马丽英;刘天波   

  1. 山东大学胶体与界面化学教育部重点实验室, 济南 250100; 滨洲医学院基础部, 山东 滨州 256603; Department of Chemistry, Lehigh University, Bethlehem, Pennsylvania 18015, USA
  • 收稿日期:2006-03-07 修回日期:2006-04-18 发布日期:2006-10-11
  • 通讯作者: 郝京诚 E-mail:jhao@sdu.edu.cn

“Second Organized Structures” of Nanoscale Inorganic Polyoxomolybdate Compounds

JIA Xiang-Feng;FAN Da-Wei;TANG Pei-Qin;HAO Jing-Cheng;MA Li-Ying;LIU Tian-Bo   

  1. Key Laboratory of Colloid and Interface Chemistry of Ministry of Education, Shandong University, Jinan 250100, P. R. China; Basic Study Division, Binzhou Medical College, Binzhou 256603, P. R. China; Department of Chemistry, Lehigh University, Bethlehem, Pennsylvania 18015, USA
  • Received:2006-03-07 Revised:2006-04-18 Published:2006-10-11
  • Contact: HAO Jing-Cheng E-mail:jhao@sdu.edu.cn

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摘要：

介绍了纳米级水溶性无机聚钼酸盐分子的逐步生长合成, 对近年来水溶液中纳米级无机聚钼酸盐分子的奇特自聚集行为进行了简述, 从两亲分子“有序聚集体”概念的角度, 提出了水溶性纳米级无机聚钼酸盐“二级有序聚集体”的概念.

关键词: 二级有序聚集体, 纳米级聚钼酸盐, 囊泡两亲分子, 激光光散射

Abstract:

Growth of polyoxomolybdate (POM) clusters and the main role of pentagonal {(Mo)Mo5}-type building blocks in the construction principle for nanoscale inorganic polyoxomolybdate compounds were introduced. The peculiar self-assembly of the nanoscale inorganic ions in aqueous solutions was reviewed. The concepts of “second organized structures” of nanoscale inorganic molybdenum compounds and the mixtures of POMs/surfactants were proposed.

Key words: Second organized structure, Nanoscale polyoxomolybdate, Vesicle amphiphile, Laser light scattering