物理化学学报 >> 1991, Vol. 7 >> Issue (02): 146-151.doi: 10.3866/PKU.WHXB19910204

研究论文 上一篇    下一篇

邻氨基酚电聚合膜的研究

张爱强; 陈衍珍; 田昭武   

  1. 厦门大学化学系，厦门 361005
  • 收稿日期:1989-10-14 修回日期:1990-03-30 发布日期:1991-04-15
  • 通讯作者:

Studies of Electropolymerized Polyortho-Aminophenol Film

Zhang Ai-Qiang; Chen Yan-Zhen; Tian Zhao-Wu   

  1. Department of Chemistry, Xiamen University, Xiamen 361005
  • Received:1989-10-14 Revised:1990-03-30 Published:1991-04-15
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摘要： 在酸性溶液中, 邻氨基酚(OAP)可电聚合成均匀的活性聚邻氮基酚膜(POAP), 膜有致密结构和“张开”结构。POAP膜的主要结构形式为: 与Ni~(2+)络合后, 形成POAP—Ni~(2+)膜, 其主要结构形式为:

关键词: 邻氨基酚(OAP), 电聚合, 聚邻氨基酚(POAP), 致密结构, 张开结构

Abstract: OAP can be electropolymerized into an uniform film of active POAP in acid solution. The films formed in different acid solutions have compact or open structures. The main structure of the POAP film is (A), The POAP film can be complexed with Ni~(2+) to form POAP-Ni~(2+) film in which the main structure is (B).

Key words: Ortho-aminophenol(OAP), Electropolymerization, Poly-ortho-aminophenol(POAP), Compact Structure, Open Structure