物理化学学报 >> 1991, Vol. 7 >> Issue (05): 543-548.doi: 10.3866/PKU.WHXB19910506

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溶剂化金属原子浸渍法制备高分散载型催化剂 II. Fe,Co,Ni催化剂的分散度和催化性能研究

吴世华; 赵维君; 杨树军; 王序昆; 张书笈; 方延铨   

  1. 南开大学元素有机化学实验室，南开大学化学系，天津 300071
  • 收稿日期:1990-06-12 修回日期:1990-11-23 发布日期:1991-10-15
  • 通讯作者: 吴世华

Preparation of Highly Dispersed Supported Metal Catalyst VIA Solvated Metal Atom Impregnation II. Dispersions and Catalytic Properties of Supported Fe,Co,Ni Catalysts

Wu Shi-Hua; Zhao Wei-Jun; Yang Shu-Jun; Wang Xu-Kun; Zhang Shu-Ji; Fang Yan-Quan   

  1. Laboratory of Elemento-Organic Chemistry and Department of Chemistry, Nankai University, Tianjin 300071
  • Received:1990-06-12 Revised:1990-11-23 Published:1991-10-15
  • Contact: Wu Shi-Hua

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摘要： 本文利用一种新的方法-溶剂化金属原子浸渍法制备了Fe/γ-Al_2O_3, Fe/SiO_2, Co/γ-Al_2O_3,Co/SiO_2, Ni/γ-Al_2O_3和Ni/SiO_2六种催化剂。H_2化学吸附, TEM和XRD测定结果表明这些催化剂中Fe, Co, Ni金属颗粒平均直径都小于3.0 nm, 金属分散度均大于50%。作者研究了Fe/γ-Al_2O_3, Co/γ-Al_2O_3和Ni/γ-Al_2O_3三种催化剂在CO+H_2反应中的催化行为, 测定了碳氢产物分布和比催化活性, 表明随着H_2/CO比增大和反应温度升高。较高分子量物种产量减少, 有利于生成甲烷。催化剂的活性大小次序为Fe>Ni>Co。

关键词: 金属蒸气合成, 溶剂化金属原子, Fe、Co、Ni催化剂, CO+H2反应

Abstract: A new method, Solvated Metal Atom Impregnation (SMAI) technique, was em- ployed to prepare Fe/γ-Al_2O_3, Fe/SiO_2, Co/γ-Al_2O_3, Co/SiO_2, Ni/γ-Al_2O_3 and Ni/SiO_2 catalysts. The results of TEN, XRD and H_2 chemisorption measurements showed that the average particle dimensions of Fe, Co, Ni in these catalysts were <3.0 nm and the dispersions of the metals were >500%. The catalytic behavior of Fe/γ-Al_2O_3, Co/γ-Al_2O_3 and Ni/γ-Al_2O_3 for CO+H_2 reaction was studied. Hydrocarbon product distributions and specifie activities were determined. It showed that, as the H_2/CO ratio and reaction temperature increased, the percentage yield of higher molecular weight molecules decreased and methane formation was favored. The specific activites of these catalysts was in the order as Fe>Ni>Co.

Key words: Metal vapour synthesis, Solvated metal atom, Fe,Co,Ni catalysts, CO+H2 reaction