物理化学学报 >> 1996, Vol. 12 >> Issue (12): 1057-1060.doi: 10.3866/PKU.WHXB19961201

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β沸石的铝化

杨春,须沁华   

  1. 南京大学化学系，南京 210093
  • 收稿日期:1996-08-11 修回日期:1996-10-07 发布日期:1996-12-15
  • 通讯作者: 须沁华

Alumination of Zeolite β

Yang Chun,Xu Qin-Hua   

  1. Department of Chemistry,Nanjing University,Nanjing 210093
  • Received:1996-08-11 Revised:1996-10-07 Published:1996-12-15
  • Contact: Xu Qin-Hua

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关键词: β沸石, 铝化, 铝酸钠

Abstract:

Zeolite β was aluminated with aqueous solution of NaAlO2. The product was characterized by means of XRD, FTIR techniques. After alumination, the Si/Al ratio of zeolite β is greatly decreased (from 15.2 to 3-4), and the crystallinity is retained mostly. Alumination is favoured by increasing the amount of added NaAlO2 and temperature, a proper high pH condition is also favourable. However, too high alkalinity leads to the destruction of the framework.

Key words: Zeolite β, Alumination, Sodium aluminate