物理化学学报 >> 2010, Vol. 26 >> Issue (07): 1795-1800.doi: 10.3866/PKU.WHXB20100731

结构化学 上一篇    下一篇

晶体范德华半径的70年

胡盛志, 谢兆雄, 周朝晖   

  1. 厦门大学化学系, 固体表面物理化学国家重点实验室, 福建 厦门 361005
  • 收稿日期:2010-01-04 修回日期:2010-04-14 发布日期:2010-07-02
  • 通讯作者: 胡盛志 E-mail:szhu@xmu.edu.cn

70 Years of Crystallographic van der Waals Radii

HU Sheng-Zhi, XIE Zhao-Xiong, ZHOU Zhao-Hui   

  1. State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
  • Received:2010-01-04 Revised:2010-04-14 Published:2010-07-02
  • Contact: HU Sheng-Zhi E-mail:szhu@xmu.edu.cn

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摘要：

对过去70年来发表的稀有气体、非金属元素和金属元素的晶体范德华半径重要数值进行了系统分析和总结. 从常用的数值中推荐了最可靠值, 并指出有关晶体范德华半径值及其应用中的若干问题, 以及有待今后进一步研究的方向.

关键词: 晶体范德华半径, 稀有气体, 非金属元素, 金属元素

Abstract:

Significant data sets of crystallographic van der Waals radii for the noble gases, the non-metal elements, and the metal elements that have appeared within the last seven decades are summarized and examined systematically. From the most useful sets all the reliable data are recommended. Certain remaining problems are identified and the need for further studies in this area is suggested.

Key words: Crystallographic van der Waals radius, Noble gas, Non-metallic element, Metallic element