自支撑CNTs/SMF-Ni电极上电催化氧气氧化茴香醚合成茴香醛

doi:10.3866/PKU.WHXB20110828

Abstract

Abstract:

A promising macroscopic carbon nanotube (CNT) system was developed by catalytic chemical vapor deposition through CNT growth on a three-dimensional network of sinter-locked conductive metal microfibers (i.e., SMF-Ni using 8 μm nickel fibers and SMF-SS using 8 μm SS316L fibers). The electrocatalytic performance of CNTs/SMF-Ni [CNTs: 50% (w)] and CNTs/SMF-SS [CNTs: 40% (w)] hybrids were examined as electrodes in the aerobic oxidation of p-anisaldehyde (p-MT) to p-cresol methyl ether (p-MBA). An excellent conversion of 95.4% and a target product selectivity of 96.5% can be obtained with a very high electric current efficiency of >80% in the presence of air at a current density of 16 mA·cm^-2 in a methanol/p-MT/KF electrolyte using SMF-SS and CNTs/SMF-Ni as an anode and a cathode, respectively.

Key words: CNTs, Electrochemical oxidation, p-Anisaldehyde, p-Cresol methyl ether

FANG Yu-Zhu, JIANG Fang-Ting, LU Yong. Electrocatalytic Performance of Self-Supporting CNTs/SMF-Ni Hybrid Electrodes for the Aerobic Oxidation of p-MT to p-MBA[J]. Acta Phys. -Chim. Sin. 2011, 27(08), 1854-1858. doi: 10.3866/PKU.WHXB20110828

References

(1) Hu, A. Z.; Zhang, S. J.; Zhu, R. F. J. Shenyang Inst. Chem. Tech. 2000, 14 (2), 124. [胡爱珠, 张胜建, 朱瑞芬. 沈阳化工学院学报, 2000, 14 (2), 124.]
(2) Shi, Y. X.;Wang, C. L.; Lin, F. L. Appl. Chem. Ind. 2001, 30 (2), 22. [石玉香, 王春林, 林枫玲. 应用化工, 2001, 30 (2), 22.]
(3) Gu, D. P.; Jia, Z. B. Progress of Organic Electrosynthesis Technology; China Petrochemical Press: Beijing; 2001. [顾登平, 贾振斌. 有机电合成进展. 北京: 中国石化出版社, 2001.]
(4) Zhong,W. H. Flavour Frag. Cosmet. 1990, 4, 4. [钟文海. 香料香精化妆品, 1990, 4, 4.]
(5) Bentrup, U.; Martin, A.;Wolf, G. U. Catal. Today 2003, 78 (1-4), 229.
(6) Reddy, B. M.; Vijaya, K. M.; Jeeva, R. K. Appl. Catal. A- Gen. 1999, 181 (1), 77.
(7) Yi, F. P.; Zhou, Y. H.; Li,W. G.; Liu, X. M. J. Guangxi Univ. (Nat. Sci. Ed.) 1998, 23 (1), 54. [易封萍, 周永红, 李伟光, 刘雄民. 广西大学学报(自然科学), 1998, 23 (1), 54.]
(8) Li,W. G.; Su, G. J.; Liu, X. M.; Liang, H. J. Chem. World 2003, 9, 464. [李伟光, 粟桂娇, 刘雄民, 梁红军. 化学世界, 2003, 9, 464.]
(9) Liu, L. H.; Ning, X. L. Guangxi Chem. Ind. 1997, 26 (1), 11. [刘利华, 宁秀玲. 广西化工, 1997, 26 (1), 11.]
(10) Wang, Q. J.; Liu, F. S.; Yu, S. T. J. Qingdao Sci. Tech. (Nat. Sci. Ed.) 2007, 28 (2), 118. [王庆军, 刘富胜, 于世涛. 青岛科技大学学报(自然科学版), 2007, 28 (2), 118.]
(11) Gu, D. P.; Hu, R. S.; Liu, X; Zhang, Y. J. Fine Chem. 2004, 21 (1), 53. [顾登平, 胡瑞省, 刘欣, 张元静. 精细化工, 2004, 21 (1), 53.]
(12) Tang, X. J.; Liang, J. J.; Yan, X.; Li, P. H. Chem. Engineer 2008, 148 (1), 60. [唐新军, 梁建军, 颜鑫, 李平辉. 化学工程师, 2008, 148 (1), 60.]
(13) Tang, X. J.; Ou, L. H.; Yi, J. L.; Zeng, Y. Chem. Res. Appl. 2005, 18 (5), 554. [唐新军, 欧利辉, 易建龙, 曾跃. 化学研究与应用, 2005, 18 (5), 554.]
(14) Bejan, D.; Savall, A. J. Electroanal. Chem. 2001, 507 (1-2), 234.
(15) Hu, R. S.; Liu, X.; Gu, D. P.; Zhang, Y. J. J. Chem. Eng. Chin. Univ. 2005, 19 (1), 134. [胡瑞省, 刘欣, 顾登平, 张元静. 高校化学工程学报, 2005, 19 (1), 134.]
(16) Said, A. H.; Mhalla, F. M.; Amatore, C. Verpeaux, J. N. J. Electroanal. Chem. 1999, 464 (1), 85.
(17) Ogibin, Y. N.; Ilovaisky, A. I.; Merkulova, V. M. Russ. Chem. Bull. 1995, 44, 507.
(18) Fichter, F.; Christen, A. Helv. Chim. Acta 1925, 8, 332.
(19) Yang, A. Y.; Liu, S. R.; Hu, Y. C. Chin. J. Synthetic Chem. 1995, 3 (3), 239. [杨爱云, 刘士荣, 胡云楚. 合成化学, 1995, 3 (3), 239.]
(20) Li, Z. L.; Zhang, Y. K.; Cheng, J. P. Fine Chem. 1995, 12 (11), 16. [李则林, 张永康, 成介平. 精细化工, 1995, 12 (11), 16.]
(21) Jiang, H.;Wu, B. L.; Cha, C. S. Electrochim. Acta 1998, 43 (16-17), 2549.
(22) Yang, J. L.; Li, J. F.; Lu, Y. Acta Phys. -Chim. Sin. 2009, 25, 2045 [杨九龙, 李剑锋, 路勇. 物理化学学报, 2009, 25, 2045.]
(23) Jiang, F. T.; Fang, Y. Z.; Liu, Y.; Chen, L.; Xue, Q. S.; Lu, Y.; Lu, J. X.; He, M. Y. J. Mater. Chem. 2009, 19 (22), 3632.
(24) Liu? Y.;Wang? H.; Li? J. F.; Lu? Y.;Wu? H. H.; Xue? Q. S.; Chen, L. Appl. Catal. A- Gen. 2007, 328, 77.
(25) Jiang, F. T. Preparation, Characterization and Application of Carbon Nano-tubes (CNTs) Grown on Thin-sheet Sinter-locked Ni-/SS-316L-microfibers. Ph. D. Dissertation. East China Normal University, Shanghai, 2009. [姜芳婷. 薄层烧结Ni 或SS-316L纤维上碳纳米管(CNTs)的生长、表征及应用探索研究[D.] 上海: 华东师范大学, 2009.]
(26) Carra, S.; Santacesaria, E. Catal. Rev.-Sci. Eng. 1980, 22, 75.
(27) Yano, T.; Popa, E.; Tryk, D. A.; Hashimoto, K.; Fujishima, A. J. Electrochem. Soc. 1999, 146 (3), 1081.

[1]	Ya-Peng HE,Rong-Ling CHEN,Chao-Nan WANG,Hong-Dong LI,Wei-Min HUANG,Hai-Bo LIN. Electrochemical Oxidation of Substituted Phenols on a Boron Doped Diamond Electrode [J]. Acta Phys. -Chim. Sin., 2017, 33(11): 2253-2260.
[2]	Yan. LI,Ting-Ting. ZHANG,Yue. LI,Bing. JIA,Hua-Hua. TAN,Jiang. YU. Influence of Calcination Temperature on Dechlorination Performance of V₂O₅/CNTs-TiO₂ Catalysts [J]. Acta Phys. -Chim. Sin., 2015, 31(8): 1541-1548.
[3]	WANG Guan-Nan, CHEN Li-Min, GUO Yuan-Yuan, FU Ming-Li, WU Jun-Liang, HUANG Bi-Chun, YE Dai-Qi. Effect of Chromium Doping on the Catalytic Behavior of Cu/ZrO₂/CNTs-NH₂ for the Synthesis of Methanol from Carbon Dioxide Hydrogenation [J]. Acta Phys. -Chim. Sin., 2014, 30(5): 923-931.
[4]	YANG Jia-Ping, YU Hui-Yao, HE Yu-Xiu, XIE Jing-Xuan, BI Wen-Yan, GAO Qing-Yu. Model Simulation and Analysis of Spatiotemporal Dynamics for the Electro-Oxidation of Sulfide on Platinum [J]. Acta Phys. -Chim. Sin., 2014, 30(4): 686-692.
[5]	HAN Tao, HUANG Wei, WANG Xiao-Dong, TANG Yu, LIU Shuang-Qiang, YOU Xiang-Xuan. Study of Ce-Cu-Co/CNTs Catalysts for the Synthesis of Higher Alcohols and Ethanol from Syngas [J]. Acta Phys. -Chim. Sin., 2014, 30(11): 2127-2133.
[6]	SHANGGUAN Peng-Peng, TONG Shao-Ping, LI Hai-Li, LENG Wen-Hua. Influence of the Potential on the Charge-Transfer Rate Constant of Photooxidation of Water over α-Fe₂O₃ and Ti-Doped α-Fe₂O₃ [J]. Acta Phys. -Chim. Sin., 2013, 29(09): 1954-1960.
[7]	TANG Jing, ZENG Qiao, CHEN Zhen-Dong, HUANG Xiang-Qian. Electrochemical Indirect Measurement for the Study of Glutathione Adsorption on Multiwalled Carbon Nanotubes and Activated Carbon [J]. Acta Phys. -Chim. Sin., 2012, 28(05): 1269-1274.
[8]	TANG Yu-Bao, LIU Jiang. Fueling Solid Oxide Fuel Cells with Activated Carbon [J]. Acta Phys. -Chim. Sin., 2010, 26(05): 1191-1194.
[9]	WU Ying-Lei, YANG Jun, WANG Jiu-Lin, YIN Li-Chao, NULI Yan-Na. Composite Cathode Structure and Binder for High Performance Lithium-Sulfur Battery [J]. Acta Phys. -Chim. Sin., 2010, 26(02): 283-290.
[10]	LU Yue-Mei, GONG Qian-Ming, LIANG Ji. Preparation of Carbon Nanotubes/Activated Carbon Composite Microspheres and Their Application to Adsorption of VB₁₂ [J]. Acta Phys. -Chim. Sin., 2009, 25(08): 1697-1702.
[11]	GAO Yun-Fang, YU Li-Li\| LU Qing-Qing, MA Chun-An. Electrochemical Oxidation Behavior of Iodide on Platinum Electrode in Acid Solution [J]. Acta Phys. -Chim. Sin., 2009, 25(07): 1421-1426.
[12]	DU Bing, JIANG Qi, ZHAO Xiao-Feng, LIN Sun-Zhong, MU Pei-Shan, ZHAO Yong. Preparation of PPy/CNTs Composite Based on the Electrostatic Absorption Effect [J]. Acta Phys. -Chim. Sin., 2009, 25(03): 513-518.
[13]	GAO Cheng-Yao; CHANG Ming. Ta/BDD Film Electrode for Electrochemical Oxidation Nitrophenol [J]. Acta Phys. -Chim. Sin., 2008, 24(11): 1988-1994.
[14]	ZHANG Wei; CUI Xiao-Li; JIANG Zhi-Yu. Effect of Composite Modes on Photoelectrochemical Properties of MWCNTs/TiO₂ Nanocomposite Films [J]. Acta Phys. -Chim. Sin., 2008, 24(11): 1975-1980.
[15]	CHEN Yu-Ting; ZHANG Hai-Yan; ZHANG Guo-Qing; CHEN Yi-Ming; ZHU Qing-Feng. Influence of Addition of Carbon Nanotubes in the Hydrogen Storage Alloy Electrode on the Performance of SC High Power Batteries [J]. Acta Phys. -Chim. Sin., 2008, 24(03): 527-532.

Electrocatalytic Performance of Self-Supporting CNTs/SMF-Ni Hybrid Electrodes for the Aerobic Oxidation of p-MT to p-MBA

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0