β-环糊精诱导的三氧化钼水溶性的增加

doi:10.3866/PKU.WHXB201301071

Abstract

Abstract:

Increased water solubility of molybdenum trioxide (MoO₃) induced by β-cyclodextrin (CD), with solubility dependent on β-CD concentration is reported. The dynamic equilibrium established between MoO₃ precipitation and dissolution shifted towards dissolution upon the addition of aqueous β-CD, to form a bluish-grey product. This was confirmed to be of β-CD and MoO₄^2- by: (1) X-ray photoelectron spectroscopy showed decreased Mo 3d_5/2 and 3d_3/2 binding energies of the product compared with those of MoO₃; (2) a strong band at 213 nm and new broad peak near 775 nm of the product were attributed to Mo＝O and Mo―O bond absorption; (3) a downfield shift of β-CD protons due to the effect of MoO₄^2- ions. An interaction between β-CD and MoO₄^2- has been revealed and hints at the possibility of exploiting it for improving MoO₃ physical properties

Key words: β-Cyclodextrin, Molybdenum trioxide, Molecule-ion interaction, Water solubility

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SHAO Zhi-Cheng, SONG Le-Xin, TENG Yue, DANG Zheng, XIA Juan. Increased Water Solubility of Molybdenum Trioxide Induced by β-Cyclodextrin[J]. Acta Phys. -Chim. Sin. 2013, 29(03), 460-466. doi: 10.3866/PKU.WHXB201301071

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Increased Water Solubility of Molybdenum Trioxide Induced by β-Cyclodextrin

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