对固体圆二色光谱测试方法的再认识——兼谈“浓度效应”

doi:10.3866/PKU.WHXB201310152

Abstract

Abstract:

In this paper, the recent developments in measurement methods of solid-state circular dichroism (CD) spectroscopy were summarized and discussed, especially the effects of concentration on solid-state CD spectral distortions. By reinspection and introspection of the solid-state CD spectra of four reported compounds, concentration gradient measurements were proved to be necessary for appropriate concentrations, which are greatly related to the chiroptical properties. The thin film solid-state CD measurements of the inherently chiral atropisomer (S)-1,1'-bi-2-naphthol (S-BINOL) were carried out with concentration gradient measurements. Using this film-state technique for the first time, the results show some subtle correlations between the CD curves and the special concentrations.

Key words: Solid-state chiroptical spectroscopy, Circular dichroism, Method of measurement, Concentration effect, Atropisomerism, Mirror symmetry breaking

ZHANG Hui, YAN Jian-Xin, WU Shu-Ting, LI Dan, WAN Shi-Gang, DING Lei, LIN Li-Rong. Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy——Discussion on Concentration Effects[J].Acta Phys. -Chim. Sin., 2013, 29(12): 2481-2497.

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Further Understanding on the Measurement Methods for Solid-State Circular Dichroism Spectroscopy——Discussion on Concentration Effects

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