电极界面缓冲层对P3HT:PC61BM太阳能电池热稳定性的影响

doi:10.3866/PKU.WHXB201505142

Abstract

Abstract:

The high-temperature thermal stability of solution-processed polymer solar cells is a key issue that determines the feasibility of further thermal encapsulation processes, such as thermal lamination or hightemperature atomic layer deposition. In this article, polymer solar cells with poly(3, 4-ethylenedioxythiophene)/poly(styrenesulfonate) (PEDOT:PSS) or MoO₃ as the anode buffer layer (ABL) and ZnO or LiF as the cathode buffer layer (CBL) were fabricated with a device structure of indium tin oxide (ITO)/ABL/poly(3-hexylthiophene): phenyl- C₆₁- butyric acid methyl ester (P3HT:PC₆₁BM)/CBL/Al. Device performances, especially the hightemperature thermal stability of the devices, were studied in detail. The results indicated that the thermal stability of the organic solar cells was highly dependent on the buffer layer material. Devices with MoO₃ as ABL and ZnO as CBL showed high thermal stability at a temperature of 120-150 ℃, which ensures the possibility of subsequent thermal processing. In addition, the use of ZnO as the cathode buffer layer could also improve longterm device stability.

Key words: Polymer solar cell, Thermal stability, Metal oxide nanoparticle, Electrode buffer layer

WU Na, LUO Qun, WU Zhen-Wu, MA Chang-Qi. Influence of Electrode Interfacial Buffer Layers on Thermal Stability of P3HT:PC₆₁BM Solar Cells[J]. Acta Phys. -Chim. Sin. 2015, 31(7), 1413-1420. doi: 10.3866/PKU.WHXB201505142

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Influence of Electrode Interfacial Buffer Layers on Thermal Stability of P3HT:PC₆₁BM Solar Cells

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Influence of Electrode Interfacial Buffer Layers on Thermal Stability of P3HT:PC₆₁BM Solar Cells