载体焙烧温度对Rh-Mn-Li/SBA-15催化CO加氢性能的影响

doi:10.3866/PKU.WHXB201607262

Abstract

Abstract:

Rh, Mn and Li were supported on SBA-15 samples that had been calcined at 550, 700, 800, and 900℃, using an incipient co-impregnation technique. The catalytic performances of these materials were subsequently evaluated for the hydrogenation of carbon monoxide. The catalysts were characterized by means of N₂ adsorption-desorption, X-ray diffraction, transmission electron microscopy, H₂ chemisorption, and Fourier transform infrared spectroscopy. The structure of the SBA-15 support remained unchanged even after its calcination at 900℃. However, the specific surface area, pore size, and total pore volume of SBA-15 decreased from 842.6 m²·g^-1, 9.57 nm, and 1.18 cm³·g^-1 to 246.4 m²·g^-1, 5.62 nm, and 0.34 cm³·g^-1, respectively, when the calcination temperature increased from 550 to 900℃. In addition, the Rh particle size increased in the range of 1.5-4.0 nm with increasing calcination temperature. Furthermore, the Rh particles showed a greater tendency towards the mesopores of support when they were calcined at high temperatures, which could be attributed to the reduced number of micropores. These changes therefore made it easier for H₂ and CO to interact with the Rh particles immobilized on the supports calcined at high temperatures. High levels of activity and selectivity towards C₂₊ oxygenates were therefore obtained on the Rh-Mn-Li/SBA-15 prepared using the SBA-15 calcined at 900℃.

Key words: Rhodium, Syngas, COhydrogenation, C₂₊ oxygenates, Calcination temperature, SBA-15

Fei XUE,Ji-Min HE,Wei-Miao CHEN,Xian-Gen SONG,Xian-Bo CHENG,Yun-Jie DING. Effect of the Calcination Temperature of the Support on the Performance of Rh-Mn-Li/SBA-15 Catalysts for CO Hydrogenation[J]. Acta Phys. -Chim. Sin. 2016, 32(11), 2769-2775. doi: 10.3866/PKU.WHXB201607262

References

1	Subramani V. ; Gangwal S. K. Energy Fuels 2008, 22 (2), 814.
2	Spivey J. J. ; Egbebi A. Chem. Soc. Rev. 2007, 36, 1514.
3	Xue F. ; Chen W. M. ; Song X. G. ; Cheng X. B. ; Ding Y. J. RSC Adv. 2016, 6, 35348.
4	Xue F. ; Ding Y. J. ; Chen W. M. ; Song X. G. ; Cheng X. B. React. Kinet. Mech. Catal. 2015, 115 (2), 625.
5	Liu W. G. ; Wang S. ; Sun T. J. ; Wang S. D. Catal. Lett. 2015, 145 (9), 1741.
6	Huang Y. L. ; Deng W. H. ; Guo E. ; Chung P.W. ; Chen S. N. ; Trewyn B. G. ; Brown R. C. ; Lin V. S. Y. ChemCatChem 2012, 4 (5), 674.
7	Song X. G. ; Ding Y. J. ; Chen W. M. ; Dong W. D. ; Pei Y. P. ; Zang J. ; Yan L. ; Lu Y. Catal. Commun. 2012, 19, 100.
8	Chen W. M. ; Ding Y. J. ; Song X. G. ; Wang T. ; Luo H. Y. Appl. Catal. A 2011, 407 (1-2), 231.
9	Wang S. R. ; Guo W.W. ; Wang H. X. ; Zhu L. J. ; Qiu K. Z. Catal. Lett. 2014, 144 (7), 1305.
10	Gao J. ; Mo X. H. ; Goodwin J. G. , Jr. J. Catal. 2009, 268 (1), 142.
11	Nunan J. G. ; Bogdan C. E. ; Klier K. ; Smith K. J. ; Young C. W. ; Herman R. G. J. Catal. 1988, 113 (2), 410.
12	Beiramar J. M. ; Constant A. G. ; Khodakov A. Y. ChemCatChem 2014, 6 (6), 1788.
13	Matsuzaki T. ; Takeuchi K. ; Hanaoka T. A. ; Arawaka H. ; Sugi Y. Appl. Catal. A 1993, 105 (2), 159.
14	Christensen J. M. ; Medford A. J. ; Studt F. ; Jensen A. D. Catal. Lett. 2014, 144 (5), 777.
15	Cao A. ; Liu G. L. ; Yue Y. Z. ; Zhang L. H. ; Liu Y. RSC Adv. 2015, 5, 58804.
16	Liu Y. Y. ; Murata K. ; Inaba M. React. Kinet. Mech. Catal. 2014, 113 (1), 187.
17	Hanaoka T. ; Arakawa H. ; Matsuzaki T. ; Sugi Y. ; Kanno K. ; Abe Y. Catal. Today 2000, 58 (4), 271.
18	Van der Lee G. ; Schuller B. ; Post H. ; Favre T. L. F. ; Ponec V. J. Catal. 1986, 98 (2), 522.
19	Gao J. ; Mo X. H. ; Chien A. C. ; Torres W. ; Goodwin J. G. , Jr. J. Catal. 2009, 262 (1), 119.
20	Li C. M. ; Liu J. M. ; Gao W. ; Zhao Y. F. ; Wei M. Catal. Lett. 2013, 143 (11), 1247.
21	Basu P. ; Panayotov D. ; Yates J. T. J. Am. Chem. Soc. 1988, 110 (7), 2074.
22	Solymosi F. ; Tombácz I. ; Kocsis M. J. Catal. 1982, 75 (1), 78.
23	Liu J. J. ; Guo Z. ; Childers D. ; Schweitzer N. ; Marshall C. L. ; Klie R. F. ; Miller J. T. ; Meyer R. J. J. Catal. 2014, 313, 149.
24	Luo H. Y. ; Zhang W. ; Zhou H.W. ; Huang S. Y. ; Lin P. Z. ; Ding Y. J. ; Lin L. W. Appl. Catal. A 2001, 214 (2), 161.
25	Han L. P. ; Mao D. S. ; Yu J. ; Guo Q. S. ; Lu G. Z. Appl. Catal. A 2013, 454, 81.
26	Chen W. M. ; Ding Y. J. ; Xue F. ; Song X. G. Acta Phys. -Chim. Sin. 2015, 31 (1), 1.
26	陈维苗; 丁云杰; 薛飞; 宋宪根. 物理化学学报, 2015, 31 (1), 1.
27	Arakawa H. ; Takeuchi K. ; Matsuzaki T. ; Sugi Y. Chem. Lett. 1984, 13 (9), 1607.
28	Cho J. M. ; Ahn C. I. ; Pang C. ; Bae J. W. Catal. Sci. Technol. 2015, 5 (7), 3525.
29	Prieto G. ; Martínez A. ; Murciano R. ; Arribas M. A. Appl. Catal. A 2009, 367 (1-2), 146.
30	Pérez De Berti I. O. ; Bengoa J. F. ; Stewart S. J. ; Cagnoli M. V. ; Pecchi G. ; Marchetti S. G. J. Catal. 2016, 335, 36.
31	Cano L. A. ; Cagnoli M. V. ; Bengoa J. F. ; Alvarez A. M. ; Marchetti S. G. J. Catal. 2011, 278 (2), 310.
32	Chen G. ; Zhang X. ; Guo C. ; Yuan G. Russ. J. Phys. Chem. A 2010, 84 (13), 2247.
33	Chen G. ; Guo C. Y. ; Zhang X. ; Huang Z. ; Yuan G. Fuel Process. Technol. 2011, 92 (3), 456.
34	Chen G. ; Guo C. Y. ; Huang Z. ; Yuan G. Chem. Eng. Res. Des. 2011, 89 (3), 249.
35	Zhao D. Y. ; Feng J. L. ; Huo Q. S. ; Melosh N. ; Fredrickson G. H. ; Chmelka B. F. ; Stucky G. D. Science 1998, 279 (5350), 548.
36	Bruss A. J. ; Gelesky M. A. ; Machado G. ; Dupont J. J. Mol. Catal. A 2006, 252 (1-2), 212.
37	Kishida M. ; Ichiki K. I. ; Hanaoka T. ; Nagata H. ; Wakabayashi K. Catal. Today 1998, 45 (1-4), 203.
38	Fan Z. L. ; Chen W. ; Pan X. L. ; Bao X. H. Catal. Today 2009, 147 (2), 86.
39	Chuang S. S. C. ; Stevens R.W. ; Khatri R. Top. Catal. 2005, 32 (3-4), 225.
40	Haider M. A. ; Gogate M. R. ; Davis R. J. J. Catal. 2009, 261 (1), 9.

[1]	Chengyu Ye, Xiaofei Yu, Wencui Li, Lei He, Guangping Hao, Anhui Lu. Engineering of Bifunctional Nickel Phosphide@Ni-N-C Catalysts for Selective Electroreduction of CO₂-H₂O to Syngas [J]. Acta Phys. -Chim. Sin., 2022, 38(4): 2004054-.
[2]	Zilong Shao, Xiaofang Liu, Shunan Zhang, Hui Wang, Yuhan Sun. CO Hydrogenation to Ethanol over Supported Rh-Based Catalyst: Effect of the Support [J]. Acta Phys. -Chim. Sin., 2021, 37(10): 1911053-.
[3]	Hong-Yan NING,Qi-Lei YANG,Xiao YANG,Ying-Xia LI,Zhao-Yu SONG,Yi-Ren LU,Li-Hong ZHANG,Yuan LIU. Carbon Fiber-supported Rh-Mn in Close Contact with Each Other and Its Catalytic Performance for Ethanol Synthesis from Syngas [J]. Acta Phys. -Chim. Sin., 2017, 33(9): 1865-1874.
[4]	Pei-Yi LIAO,Chen ZHANG,Li-Jun ZHANG,Yan-Zhang YANG,Liang-Shu ZHONG,Xiao-Ya GUO,Hui WANG,Yu-Han SUN. Influences of Cu Content on the Cu/Co/Mn/Al Catalysts Derived from Hydrotalcite-Like Precursors for Higher Alcohols Synthesis via Syngas [J]. Acta Phys. -Chim. Sin., 2017, 33(8): 1672-1680.
[5]	Fang-Fang ZHENG,Qian LI,Hong ZHANG,Wei-Zheng WENG,Xiao-Dong YI,Yan-Ping ZHENG,Chuan-Jing HUANG,Hui-Lin WAN. Preparation and Characterization of Sinter-Resistant Rh-Sm₂O₃/SiO₂ Catalyst and Its Performance for Partial Oxidation of Methane to Syngas [J]. Acta Phys. -Chim. Sin., 2017, 33(8): 1689-1698.
[6]	Xue-Hui HUANG,Xiao-Hui SHANG,Peng-Ju NIU. Surface Modification of SBA-15 and Its Effect on the Structure and Properties of Mesoporous La_0.8Sr_0.2CoO₃ [J]. Acta Phys. -Chim. Sin., 2017, 33(7): 1462-1473.
[7]	Yan. LI,Ting-Ting. ZHANG,Yue. LI,Bing. JIA,Hua-Hua. TAN,Jiang. YU. Influence of Calcination Temperature on Dechlorination Performance of V₂O₅/CNTs-TiO₂ Catalysts [J]. Acta Phys. -Chim. Sin., 2015, 31(8): 1541-1548.
[8]	ZHANG Xiao-Ya, ZHENG Cong-Ye, ZHENG Xue-Li, FU Hai-Yan, YUAN Mao-Lin, LI Rui-Xiang, CHEN Hua. Preparation of Silica-Bonded Phosphine and Its Influence on 1-Octene Hydroformylation Catalyzed by Rhodium Complex [J]. Acta Phys. -Chim. Sin., 2015, 31(4): 738-742.
[9]	HU Long-Xing, XU Dan-Dan, ZOU Lian-Pei, YUAN Hang, HU Xing. Heterogeneous Fenton Oxidation of Refractory Dye Rhodamine B in Aqueous Solution with Mesoporous Fe/SBA-15 [J]. Acta Phys. -Chim. Sin., 2015, 31(4): 771-782.
[10]	CHEN Wei-Miao, DING Yun-Jie, XUE Fei, SONG Xian-Gen. Role of Common Promoters in Rh-Based Catalysts for CO Hydrogenation to C₂-Oxygenates [J]. Acta Phys. -Chim. Sin., 2015, 31(1): 1-10.
[11]	WU Ying-Quan, WANG Si-Chen, XIE Hong-Juan, GAO Jun-Wen, TIAN Shao-Peng, HAN Yi-Zhuo, TAN Yi-Sheng. Influence of Cu on the K-LaZrO₂ Catalyst for Isobutanol Synthesis [J]. Acta Phys. -Chim. Sin., 2015, 31(1): 166-172.
[12]	LI Jian-Mei, LIU Jian, REN Li-Wei, LIU Qing-Long, ZHAO Zhen, WEI Yue-Chang, DUAN Ai-Jun, JIANG Gui-Yuan. Selective Oxidation of Ethane to Aldehydes over Potassium-Promoted SBA-15-Supported Molybdenum Oxide Catalysts [J]. Acta Phys. -Chim. Sin., 2014, 30(9): 1736-1744.
[13]	DONG Wen-Da, ZHU He-Jun, DING Yun-Jie, PEI Yan-Peng, DU Hong, WANG Tao. Effect of Trace Amounts of Li Doping on Performance of Co/AC Catalysts for Syntheses of Mixed Linear α-Alcohols [J]. Acta Phys. -Chim. Sin., 2014, 30(9): 1745-1751.
[14]	ZHANG Zhao-Yan, ZHU Quan-Jing, DING Jing, DAI Wei-Lin, ZONG Bao-Ning. Effect of Support on the Structural Evolution and Catalytic Performance of WO₃-Supported Catalysts in the Synthesis of Adipic Acid [J]. Acta Phys. -Chim. Sin., 2014, 30(8): 1527-1534.
[15]	HAN Tao, HUANG Wei, WANG Xiao-Dong, TANG Yu, LIU Shuang-Qiang, YOU Xiang-Xuan. Study of Ce-Cu-Co/CNTs Catalysts for the Synthesis of Higher Alcohols and Ethanol from Syngas [J]. Acta Phys. -Chim. Sin., 2014, 30(11): 2127-2133.

Effect of the Calcination Temperature of the Support on the Performance of Rh-Mn-Li/SBA-15 Catalysts for CO Hydrogenation

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0