Ni(pz)4Cl2型络合物的光、热、磁性质的研究

doi:10.3866/PKU.WHXB19961108

Acta Phys. -Chim. Sin. ›› 1996, Vol. 12 ›› Issue (11): 995-1000.doi: 10.3866/PKU.WHXB19961108

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Theoretical Research on Optical,Thermal and Magnetic Properties of Ni(pz)₄Cl₂ Complex

Yan Zhan-Xian,Zhou Xiao-Qing,Dai Wei,Chen Ci-Xing

Department of Physics,Hunan Jishou University,Jishou 416000

Received:1996-05-29 Revised:1996-08-09 Published:1996-11-15
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Abstract

Abstract:

In this paper, we have calculated analyzed theoretically the absorption spectra, the low-temperature Schottky heat capacity and the paramagnetic susceptibility of Ni2+ ions in Ni(pz)4Cl2 (pz=Pyrazole) complex, by using the complete configuration mixing unified crystal field theory for d8(D4h*), and the theoretical results agree with the experimental data very well. Thus we can give a complete and reasonable theortical interpretation of the optical, thermal and magnetic properties of the Ni2+ ions in Ni(pz)4Cl2 complex.

Key words: Ni(pz)₄Cl₂, Absorption spectra, Susceptibility, Schottky heat eapacity

Yan Zhan-Xian,Zhou Xiao-Qing,Dai Wei,Chen Ci-Xing. Theoretical Research on Optical,Thermal and Magnetic Properties of Ni(pz)₄Cl₂ Complex[J]. Acta Phys. -Chim. Sin. 1996, 12(11), 995-1000. doi: 10.3866/PKU.WHXB19961108

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Theoretical Research on Optical,Thermal and Magnetic Properties of Ni(pz)₄Cl₂ Complex

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Theoretical Research on Optical,Thermal and Magnetic Properties of Ni(pz)₄Cl₂ Complex