Acta Phys. -Chim. Sin. ›› 2008, Vol. 24 ›› Issue (03): 364-368.doi: 10.1016/S1872-1508(08)60015-7

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Catalytic Combustion of Ethyl Acetate over Al2O3-Ce0.5Zr0.5O2 Supported Metal Oxide Catalysts

YUAN Shu-Hua; SHEN Mei; GONG Mao-Chu; WANG Jian-Li; YAN Sheng-Hui; CAO Hong-Yan; CHEN Yao-Qiang   

  1. Institute of Catalytic Material Science, College of Chemistry, Sichuan University, Chengdu 610064, P. R. China
  • Received:2007-09-25 Revised:2007-11-27 Published:2008-03-10
  • Contact: CHEN Yao-Qiang E-mail:nic7501@email.scu.edu.cn

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Abstract: The catalysts for the combustion of ethyl acetate were prepared using Fe, Co, Cu, Cr, andMn metal oxides as active components supported on Al2O3-Ce0.5Zr0.5O2 mixed oxides and characterized by X-ray diffraction (XRD), temperature programmed reduction (TPR), oxygen storage capacity measurement, BET surface area, XPS measurement, and activity test. According to the results of characterization, it was found that Cu/Al2O3-Ce0.5Zr0.5O2 (1:2, mass ratio) andMn/Al2O3-Ce0.5Zr0.5O2 (1:2) catalysts presented excellent activity for the catalytic combustion of ethyl acetate, because of the more reducible species and high reducibility of the catalysts. For ethyl acetate oxidation, more than 99% conversion was achieved at 245 ℃ over catalysts Cu/Al2O3-Ce0.5Zr0.5O2 (1:2) and Mn/Al2O3-Ce0.5Zr0.5O2 (1:2, mass ratio), indicating that the catalysts had great potential for wide use.

Key words: Ethyl acetate, Catalytic combustion, Volatile organic compound