正、负离子表面活性剂凝胶化正丁醇

doi:10.3866/PKU.WHXB20110211

Abstract

Abstract:

The gelation of n-butanol was realized by a mixture of cationic and anionic surfactants (referred to as “catanionic surfactant”). In this study, we used sodium laurate/cetyltrimethylammonium bromide (SL/CTAB) as the catanionic surfactant. The rheological properties and microstructures of the n-butanol gel were studied using a rheometer and scanning electron microscopy (SEM). We found that the concentration and mole ratio of the catanionic surfactant affected the formation of the gel and n-butanol was only efficiently gelled in the presence of the catanionic surfactant at a suitable concentration and mole ratio. When we fixed the concentration of one component in the catanionic surfactant system, the gel viscosity increased with the concentration of the other component on the basis of gel formation. This gel was a non-Newtonian fluid and showed a shear-thinning property in rheological experiments. In addition, SEM results showed that the gel had a representative three-dimensional network structure, which was composed of zonal fibers with uniform thickness. Further investigation indicates that the hydrophobic effect between the hydrocarbon chains, the electrostatic attraction between the polar headgroups, and the hydrogen bond interaction between the surfactants and n-butanol play an important role in gel formation.

Key words: Catanionic surfactant, Physical gel, n-Butanol, Gelation, Hydrogen bond

LU Ting, WANG Xiao-Dong, ZHANG Tao. Gelation of n-Butanol by a Catanionic Surfactant System[J]. Acta Phys. -Chim. Sin. 2011, 27(02), 486-490. doi: 10.3866/PKU.WHXB20110211

References

(1) Terech, P.;Weiss, R. G. Chem. Rev. 1997, 97, 3133.
(2) Lee, K. Y.; Mooney, D. J. Chem. Rev. 2001, 101, 1869.
(3) Xing, B. G.; Yu, C.W.; Chow, K. H.; Ho, P. L.; Fu, D. G.; Xu, B. J. Am. Chem. Soc. 2002, 124, 14846.
(4) de Loos, M.; Feringa, B. L.; van Esch, J. H. Eur. J. Org. Chem. 2005, No. 17, 3615.
(5) Liu, K. Q.; Chen, T.; Zhang, Y.; Fu, Q. J.; Fang, Y. Chin. J. xplos. Propellants 2006, 29, 1.
[刘凯强, 陈钿, 张颖, 全军, 房喻. 火炸药学报, 2006, 29, 1.]
(6) Yang, Z. M.; Liang, G. L.; Xu, B. Acc. Chem. Res. 2008, 41, 15.
(7) Lu, T.; Huang, J. B.; Li, Z. H.; Jia, S. K.; Fu, H. L. J. Phys. Chem. B 2008, 112, 2909.
(8) Liu, J.; He, P. L.; Yan, J. L.; Fang, X. H.; Peng, J. X.; Liu, K. Q.; ang, Y. Adv. Mater. 2008, 20, 2508.
(9) Koumura, N.; Kudo, M.; Tamaoki, N. Langmuir 2004, 20, 9897.
(10) Estroff, L. A.; Hamilton, A. D. Chem. Rev. 2004, 104, 1201.
(11) Liu, K. Q.; Qu, Y. L.;Wang, M. Z.; Hu, D. D.; Fang, Y.;Wang, N. F. Chin. J. Explos. Propellants 2003, 26, 23.
[刘凯强, 屈育 , 王明珍, 胡道道, 房喻, 王宁飞. 火炸药学报, 2003, 26, 3.]
(12) Matsumoto, S.; Yamaguchi, S.; Ueno, S.; Komatsu, H.; Ikeda, M.; Ishizuka, K.; Iko, Y.; Tabata, K. V.; Aoki, H.; Ito, S.; Noji, H.; Hamachi, I. Chem. Eur. J. 2008, 14, 3977.
(13) Lin, Y. Y.; Qiao, Y.; Yan, Y.; Huang, J. B. Soft Matter 2009, 5, 047.
(14) Mueller, D. C.; Turns, S. R. J. Propul. Power 1996, 12, 591.
(15) Migliaro, F.W.; Manke, S. A.; Rothgery, E. F.; Knollmueller, K. . Liquid or Gel Propellant Useful in Rockets or Thrusters- ontains Oxidiser and Fuel Consisting of Reduced Volatility ubstd. Hydrazine Cpd(s). US Patent 5433802, 1995-07-18.
(16) Yan, D. Q.; Zhou, H. M.; Shan, J. S. J. Rocket Propul. 2003, 29, 8.
[闫大庆, 周宏民, 单建胜. 火箭推进, 2003, 29, 38.]
(17) Atlantic Res Corp. Gelled Hydrazine Propellant Compositions- ontg Hydrazine Nitrate and Finely Divided Metal. US Patent 811970, 1974-05-21.
(18) Ishikawajima Harima Heavy Ind. Supply Method of Gelling ropellant Used as Fuel for Missile, Rocket-Involves Mixing alt or Alkali to Gelling Propellant in Tank to Liquefy It, and ending Out Liquefied Propellant from Tank. JP Patent 075133, 2008-04-16.
(19) Fu, Q. J.; Du, Z. G.; Lan, H. P.; Yu, S. T.; Yang, C. J. Rocket Propul. 2006, 32, 48.
[符全军, 杜宗罡, 兰海平, 鱼升堂, 超. 火箭推进, 2006, 32, 48.]
(20) Frankel, M. B.;Weber, J. F. New 4-Azido-4,4-Di:nitro-1- utanol and Derivs.-Used in Explosives and Propellants, Prepd. rom 4,4-Di:nitro-1-Butanol and Acetyl Chloride. US Patent 795593, 1989-01-03.
(21) Wang,W. J.; Tang, S. Q. Chem. Propellants Polym. Mater. 2004, 2, 30.
[王万军, 唐松青. 化学推进剂与高分子材料, 2004, 2, 0.]
(22) Wu, Z. J. Journal of Astronautics 2006, 27, 448.
[吴志坚. 宇航报, 2006, 27, 448.]
(23) He, F.; Fang, T.; Li, Y. Y.; Mi, Z. T. Chin. J. Explos. Propellants 2006, 4, 54.
[贺芳, 方涛, 李亚裕, 米镇涛. 火炸药学报, 2006, 4, 54.]
(24) Kaler, E.W.; Murthy, A. K.; Rodriguez, B. E.; Zasadzinski, J. A. Science 1989, 245, 1371.
(25) Shen, Y.W.; Hao, J. C.; Hoffmann, H. Soft Matter 2007, 3, 407.
(26) Lu, T.; Li, Z. H.; Huang, J. B.; Fu, H. L. Langmuir 2008, 24, 0723.
(27) Yin, H. Q.; Lin, Y. Y.; Huang, J. B. J. Collid Interface Sci. 2009, 38, 177.
(28) Gronwald, O.; Snip, E.; Shinkai, S. Curr. Opin. Colloid nterface Sci. 2002, 7, 148.
(29) Koshy, P.; Verma, G.; Aswal, V. K.; Venkatesh, M.; Hassan, P. A. J. Phys. Chem. B 2010, 114, 10462.
(30) Zhao, G. X.; Zhu, B. Y. Principles of Surfactant Action, 1st ed.; hina Light Industry Press: Beijing, 2003; pp 61-95, 25-320.
[赵国玺, 朱瑶. 表面活性剂作用原理. 北京: 中轻工业出版社, 2003: 61-95, 225-320.]
(31) Ishi-I, T.; Shinkai, S. Supramolecular Dye Chemistry. In Topics n Current Chemistry;Wu?rthner, F. Eds.; Springer: Berlin, New ork, 2005; pp258, 119-160.
(32) Han, F.; He, X.; Huang, J. B.; Li, Z. C.;Wang, Y. L.; Fu, H. L. J. Phys. Chem. B 2004, 108, 5256.

[1]	Ruoning Li, Xue Zhang, Na Xue, Jie Li, Tianhao Wu, Zhen Xu, Yifan Wang, Na Li, Hao Tang, Shimin Hou, Yongfeng Wang. Hierarchical Self-Assembly of Ag-Coordinated Motifs on Ag(111) [J]. Acta Phys. -Chim. Sin., 2022, 38(8): 2011060-.
[2]	Chong Cao, Pei Zhang, Lidong Cao, Mingxin Liu, Yuying Song, Peng Chen, Qiliang Huang, Buxing Han. Experimental and Molecular Dynamic Simulation of Droplet Deposition on Superhydrophobic Plant Leaf Surfaces [J]. Acta Phys. -Chim. Sin., 2022, 38(12): 2207006-.
[3]	Xueqing Gao, Shujiao Yang, Wei Zhang, Rui Cao. Biomimicking Hydrogen-Bonding Network by Ammoniated and Hydrated Manganese (Ⅱ) Phosphate for Electrocatalytic Water Oxidation [J]. Acta Phys. -Chim. Sin., 2021, 37(7): 2007031-.
[4]	Zhiwei Wu, Weilu Ding, Yaqin Zhang, Yanlei Wang, Hongyan He. Interaction and Mechanism between Imidazolium Ionic Liquids and the Zwitterionic Amino Acid Tyr: a DFT Study [J]. Acta Phys. -Chim. Sin., 2021, 37(10): 2002021-.
[5]	Xiaolong Liu, Qiang Wang, Chao Wang, Jun Xu, Feng Deng. Hydrogen-Bond Induced Crystallization of Silicalite-1 Zeolite as Revealed by Solid-State NMR Spectroscopy [J]. Acta Physico-Chimica Sinica, 2020, 36(4): 1905035-.
[6]	Yuhong Li,Xin-Ping Wu,Cong Liu,Meng Wang,Benteng Song,Guiyun Yu,Gang Yang,Wenhua Hou,Xue-Qing Gong,Luming Peng. NMR and EPR Studies of Partially Reduced TiO₂ [J]. Acta Physico-Chimica Sinica, 2020, 36(4): 1905021-.
[7]	Fenfen Wang, Peng Wang, Hongyao Niu, Yingfeng Yu, Pingchuan Sun. Solid-State NMR Studies on Hydrogen Bonding Interactions and Structural Evolution in PAA/PEO Blends [J]. Acta Physico-Chimica Sinica, 2020, 36(4): 1912016-.
[8]	Lu Liu, Yuping Xu, Xia Chen, Mei Hong, Jing Tong. Thermogravimetric Analysis of Enthalpy Variation of 1-Alkyl-3-methylimidazole Chloride [J]. Acta Physico-Chimica Sinica, 2020, 36(11): 2004014-.
[9]	Mingguang PAN,Yongsheng ZHAO,Xiaoqin ZENG,Jianxin ZOU. Moisture-Responsive Behavior in the Azophenolic Ionic Liquid Solution Accompanied by a Naked-Eye Color Change [J]. Acta Physico-Chimica Sinica, 2019, 35(6): 624-629.
[10]	Wenhui CHEN,Shengli CHEN. Effect of Ink Solvents on Low-Pt Loading Proton Exchange Membrane Fuel Cell Performance [J]. Acta Phys. -Chim. Sin., 2019, 35(5): 517-522.
[11]	Wenjun CHEN,Zhimin XUE,Jinfang WANG,Jingyun JIANG,Xinhui ZHAO,Tiancheng MU. Investigation on the Thermal Stability of Deep Eutectic Solvents [J]. Acta Physico-Chimica Sinica, 2018, 34(8): 904-911.
[12]	Yucui HOU,Congfei YAO,Weize WU. Deep Eutectic Solvents: Green Solvents for Separation Applications [J]. Acta Phys. -Chim. Sin., 2018, 34(8): 873-885.
[13]	Xiaoyu JIANG,Wei WU,Yirong MO. Strength of Intramolecular Hydrogen Bonds [J]. Acta Phys. -Chim. Sin., 2018, 34(3): 278-285.
[14]	Rui GUO,Jialin ZHANG,Songtao ZHAO,Xiaojiang YU,Shu ZHONG,Shuo SUN,Zhenyu LI,Wei CHEN. LT-STM Investigation of the Self-Assembled F₁₆CuPc-Corannulene Binary System on Ag (111) and Grap [J]. Acta Phys. -Chim. Sin., 2017, 33(3): 627-632.
[15]	Li WANG,He-Xia SHI,Wen-Yuan WANG,Hong SHI,Xiang SHAO. Identifying the Hydrogen Bonding Patterns of Melamine and Melem Self-Assemblies on Au(111) Surface [J]. Acta Phys. -Chim. Sin., 2017, 33(2): 393-398.

Gelation of n-Butanol by a Catanionic Surfactant System

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Metrics

Recommended 0