石墨烯氧化物薄膜电极的光电化学特性

doi:10.3866/PKU.WHXB20112831

Abstract

Abstract: A series of graphene oxide (GO) thin films were prepared by a dip-coating method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier-transform infrared (FTIR) spectroscopy, ultraviolet-visible (UV-Vis) light absorption, and photoelectrochemical measurements. A cathodic photocurrent was observed for the GO electrodes and the photocurrent density was influenced by the thickness of the films. The GO film electrode with an average thickness of 27 nm gave a photocurrent density of 0.25 μA·cm^-2. The photoresponse of the GO electrodes was found to be influenced by UV irradiation and the cathodic photocurrent decreased gradually with UV irradiation time. This work provides a simple method to change the photoelectrochemical property of GO films by controlling the film thickness or UV irradiation time.

Key words: Graphene oxide, Photoelectrochemical property, Cathodic photocurrent, Film thickness, UV irradiation

ZHANG Xiao-Yan, SUN Ming-Xuan, SUN Yu-Jun, LI Jing, SONG Peng, SUN Tong, CUI Xiao-Li. Photoelectrochemical Properties of Graphene Oxide Thin Film Electrodes[J]. Acta Phys. -Chim. Sin. 2011, 27(12), 2831-2835. doi: 10.3866/PKU.WHXB20112831

References

(1) Novoselov, K. S.; Jiang, Z.; Zhang, Y.; Morozov, S. V.; Stormer, H. L.; Zeitler, U.; Maan, J. C.; Boebinger, G. S.; Kim, P.; Geim, A. K. Science 2007, 315, 1379.

(2) Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183.

(3) Zhang, Y. B.; Tan, Y.W.; Stormer, H. L.; Kim, P. Nature 2005, 438, 201.

(4) Gusynin, V. P.; Sharapov, S. G. Phys. Rev. Lett. 2005, 95, 146801/1-4.
(5) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D.; Zhang, Y.; Dubonos, S. V.; Crigorieva, I. V.; Firsov, A. A. Science 2004, 306, 666.

(6) Fan, Y.; Huang, K. J.; Niu, D. J.; Yang, C. P.; Jing, Q. S. Electrochim. Acta 2011, 56, 4685.

(7) Du, Q. L.; Zheng, M. B.; Zhang, L. F.;Wang, Y.W.; Chen, J. H.; Xue, L. P.; Dai,W. J.; Ji, G. B.; Cao, J. M. Electrochim. Acta 2010, 55, 3897.

(8) Du, X.; Guo, P.; Song, H. H.; Chen, X. H. Electrochim. Acta 2010, 55, 4812.

(9) Zhao, Y. C.; Zhan, L.; Tian, J. N.; Nie, S. L.; Ning, Z. Electrochim. Acta 2011, 56, 1967.

(10) Li, C.; Shi, G. Q. Electrochim. Acta 2011, 10.1016/j. DOI: electacta.2010.12.081.
(11) Zhang, Y.; Sun, X. M.; Zhu, L. Z.; Shen, H. B.; Jia, N. Q. Electrochim. Acta 2011, 56, 1239.

(12) Eda, G.; Mattevi, C.; Yamaguchi, H.; Kim, H.; Chhowalla, M. J. Phys. Chem. C 2009, 113, 15768.

(13) Park, S.; Ruoff, R. S. Nat. Nanotechnol. 2009, 4, 217
(14) Robinson, J. T.; Perkins, F. K.; Snow, E. S.;Wei, Z.; Sheehan, P. E. Nano Lett. 2008, 8, 3137.

(15) Eda, G.; Fanchini, G.; Chhowalla, M. Nat. Nanotechnol. 2008, 3, 270
(16) Yeh, T. F.; Syu, J. M.; Cheng, C.; Chang, T. H.; Teng, H. Adv. Funct. Mater. 2010, 20, 2255.

(17) Chen, C.; Cai,W. M.; Long, M. C.; Zhou, B. X.;Wu, Y. H.;Wu, D. Y.; Feng, Y. J. ACS Nano 2010, 4, 6425.

(18) Lahaye, R. J.W. E.; Jeong, H. K.; Park, C. Y.; Lee, Y. H. Phys. Rev. B 2009, 79, 125435.

(19) Wu, X. S.; Sprinkle, M.; Li, X. B.; Ming, F.; Berger, C.; de Heer,W. A. Phys. Rev. Lett. 2008, 101, 026801.

(20) Gilje, S.; Han, S.;Wang, M.;Wang, K. L.; Kaner, R. B. Nano Lett. 2007, 7, 3394.

(21) Lu, Z. S.; Guo, C. X.; Yang, H. B.; Qiao, Y.; Guo, J.; Li, C. M. J. Colloid Interface Sci. 2011, 353, 588.

(22) Ng, Y. H.; Iwase, A.; Kudo, A.; Amal, R. J. Phys. Chem. Lett. 2010, 1, 2607.

(23) Chang, H. X.; Lv, X. J.; Zhang, H.; Li, J. H. Electrochem. Commun. 2010, 12, 483.

(24) Zhang, X. Q.; Feng, Y. Y.; Tang, S. D.; Feng,W. Carbon 2010, 48, 211.

(25) Manga, K. K.; Zhou, Y.; Yan, Y. L.; Loh, K. P. Adv. Funct. Mater. 2009, 19, 3638.

(26) Zhang, X. Y.; Li, H. P.; Cui, X. L. Chin. J. Inorg. Chem. 2009, 25, 1903.
(27) Hummers,W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80, 1339.

(28) Bourlinos, A. B.; Gournis, D.; Petridis, D.; Szabó, T.; Szeri, A.; Dékány, I. Langmuir 2003, 19, 6050.

(29) Ding, Y. H.; Zhang, P.; Zhuo, Q.; Ren, H. M.; Yang, Z. M.; Jiang, Y. Nanotechnology 2011, 22, 215601.

(30) Jiao, L.; Chen, I.; Collins, R.W.;Wronski, C. R.; Hata, N. Appl. Phys. Lett. 1998, 72, 1057.

(31) Walter, M. G.;Warren, E. L.; McKone, J. R.; Boettcher, S.W.; Mi, Q.; Santori, E. A.; Lewis, N. S. Chem. Rev. 2010, 110, 6446.

(32) Hu, C. C.; Nian, J. N.; Teng, H. Solar Energy Materials & Solar Cells 2008, 92, 1071.

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Photoelectrochemical Properties of Graphene Oxide Thin Film Electrodes

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