分级多孔γ-Al2O3空心微球微波水热法制备及其对刚果红的快速吸附

doi:10.3866/PKU.WHXB201507201

Acta Phys. -Chim. Sin. ›› 2015, Vol. 31 ›› Issue (9): 1815-1822.doi: 10.3866/PKU.WHXB201507201

• PHYSICAL CHEMISTRY OF MATERIALS • Previous Articles

Fast Adsorption Removal of Congo Red on Hierarchically Porous γ-Al₂O₃ Hollow Microspheres Prepared by Microwave-Assisted Hydrothermal Method

Long-Hui. NIE^1,²(),Qiao. TAN¹,Wei. ZHU¹,Qi. WEI¹,Zhi-Kui. LIN¹

¹ School of Chemistry and Chemical Engineering, Hubei University of Technology, Wuhan 430068, P. R. China
² The Synergistic Innovation Center of Catalysis Materials of Hubei Province, Wuhan 430068, P. R. China

Received:2015-04-03 Published:2015-09-06
Supported by:
the National Natural Science Foundation of China(51572074);Natural Science Foundation of Hubei Province, China(2011CDB079);Hubei College Student Innovation Training Project, China(201310500017);Open Fund of Key Laboratory of Catalysis andMaterials Science of the State Ethnic Affairs Commission & Ministry of Education, South-Central University for Nationalities, China(CHCL12003)

Abstract

Abstract:

Hierarchical nanostructured γ-Al₂O₃ hollow microspheres were synthesized from KAl(SO₄)₂ and urea precursors by the microwave-assisted hydrothermal (MAH) method at 180 ℃ for 20 min followed by calcination at 600 ℃ for 2 h. The as-prepared sample was used to remove the organic dye Congo red (CR) from aqueous solution. The results showed that the obtained γ-Al₂O₃ hollow microspheres are about 0.8-1.0 μm in diameter with a shell thickness of approximately 200 nm. The γ-Al₂O₃ hollow microspheres have a high surface area of 243 m²·g^-1 and a hierarchical meso-macroporous structure, which is beneficial for mass transfer in liquid processes. Therefore, the prepared γ-Al₂O₃ hollow microspheres exhibit faster adsorption and enhanced adsorption performance for CR than particles prepared by the hydrothermal method and commercial γ-Al₂O₃. The adsorption kinetic data follow the pseudo-second-order equation and the equilibrium data fit well to the Langmuir model. The maximum adsorption capacity (q_max) of the obtained γ-Al₂O₃ hollow microspheres calculated by the Langmuir model is up to 515.4 mg·g^-1 at 25 ℃. The γ-Al₂O₃ hollow microspheres prepared by the microwave-assisted hydrotherm method show promise as an adsorbent for environmental applications due to their hierarchical porous structure, high surface area, large pore volume, and adsorption capacity.

Key words: Hierarchically porous material, γ-Al₂O₃, Congo red, Adsorption kinetics

Long-Hui. NIE,Qiao. TAN,Wei. ZHU,Qi. WEI,Zhi-Kui. LIN. Fast Adsorption Removal of Congo Red on Hierarchically Porous γ-Al₂O₃ Hollow Microspheres Prepared by Microwave-Assisted Hydrothermal Method[J].Acta Phys. -Chim. Sin., 2015, 31(9): 1815-1822.

References

1	Jalil A. A. ; Triwahyono S. ; Adam S. H. ; Rahim N. D. ; Aziz M. A. ; Hairom N. H. ; Razali N. A. ; Abidin M. A. ; Mohamadiah M. K. J.Hazard. Mater 2010, 181, 755.
2	Vimonsesa V. ; Lei S. ; Ji B. ; Chowd C. W. K. ; Saint C. Chem. Eng. J 2009, 148, 354.
3	Asencios Y. J. O. ; Sun-Kou M. R. Appl. Surf. Sci 2012, 258, 10002.
4	Cai W. Q. ; Yu J. G. ; Jaroniec M. J.Mater. Chem 2010, 20, 4587.
5	Xu J. S. ; Zhu Y. J. J.Colloid Interface Sci 2012, 385, 58.
6	Fei J. B. ; Cui Y. ; Zhao J. ; Gao L. ; Yang Y. ; Li J. B. J.Mater. Chem 2011, 21, 11742.
7	Yu C. ; Dong X. ; Guo L. ; Li J. ; Qin F. ; Zhang L. Z. ; Shi J. ; Yan D. J.Phys. Chem. C 2008, 112, 13378.
8	Ai L. ; Zeng Y. ; Jiang J. Chem. Eng. J 2014, 235, 331.
9	Hu J. ; Song Z. ; Chen L. ; Yang H. ; Li J. ; Richards R. J.Chem. Eng. Data 2010, 55, 3742.
10	Yang Z. ; Wei J. ; Yang H. ; Liu L. ; Liang H. ; Yang Y. Eur. J.Inorg. Chem 2010, 5, 3354.
11	Ai L. ; Zeng Y. Chem. Eng. J 2013, 215- 216, 269..
12	Fei J. ; Cui Y. ; Yan X. ; Qi W. ; Yang Y. ; Wang K. ; He Q. ; Li J. Adv. Mater 2008, 20, 452.
13	Cai W. Q. ; Hu Y. Z. ; Chen J. ; Zhang G. X. ; Xia T. Cryst. Eng. Commun 2012, 14, 972.
14	Zhang C. ; Zhang H. ; Du B. ; Hou R. ; Guo S. J.Colloid Interface Sci 2012, 368, 97.
15	Kong L. ; Lu X. ; Bian X. ; Zhang W. ; Wang C. J.Solid State Chem 2010, 183, 2421.
16	Nie L. H. ; Meng A. Y. ; Yu J. G. ; Jaroniec M. Scientific Reports 2013, 3, 3215.
17	Cai W. Q. ; Yu J. G. ; Mann S. Microporous Mesoporous Mat 2009, 122, 42.
18	Wu X. Y. ; Zhang B. Q. ; Hu Z. S. Mater. Lett 2012, 73, 169.
19	Wu X. Y. ; Wang D. B. ; Hu Z. S. ; Gu G. H. Mater. Chem. Phys 2008, 109, 560.
20	Cai W. Q. ; Yu J. G. ; Cheng B. ; Su B. L. ; Jaroniec M. J.Phys. Chem. C 2009, 113 (14739)
21	Feng Y. ; Zhang L. ; Gu G. H. ; Hu Z. S. Rare Metal Mat. Eng 2007, 36, 134.
22	Ren T. Z. ; Yuan Z. Y. ; Su B. L. Langmuir 2004, 20, 1531.
23	Nie L. ; Deng K. ; Yuan S. ; Zhang W. ; Tan Q. Mater. Lett 2014, 132, 369.
24	Sing K. S. W. ; Everett D. H. ; Haul R. A. W. ; Moscou L. ; Pierotti R. A. ; Rouquerol J. ; Siemieniewska T. Pure Appl. Chem 1985, 57, 603.
25	Zhao X. ; Wang W. ; Zhang Y. ; Wu S. ; Li F. ; Liu J. P. Chem. Eng. J 2014, 250, 164.
26	Wang L. ; Li J. ; Wang Y. ; Zhao L. ; Jiang Q. Chem. Eng. J 2012, 181- 182, 72..
27	Lan S. ; Guo N. ; Liu L. ; Wu X. ; Li L. ; Gan S. Appl. Surf. Sci 2013, 283, 1032.
28	Zhang L. ; Lian J. ; Wang L. ; Jiang J. ; Duan Z. ; Zhao L. Chem. Eng. J 2014, 241, 384.
29	Lorenc-Grabowska E. ; Gryglewicz G. Dyes and Pigments 2007, 74, 34.
30	Du Q. ; Sun J. ; Li Y. ; Yang X. ; Wang X. ; Wang Z. ; Xia L. Chem. Eng. J 2014, 245, 99.

[1]	SHEN Qi, FAN Ying-Ju, YIN Long, SUN Zhong-Xi. Two-Dimensional Continuous Online In situ ATR-FTIR Spectroscopic Investigation of Adsorption of Butyl Xanthate on CuO Surfaces [J]. Acta Phys. -Chim. Sin., 2014, 30(2): 359-364.
[2]	DENG Lin, QI Zhi-Mei. Effect of Glass Silylation on the Adsorption Behavior of Rhodamine 6G and Methylene Blue [J]. Acta Phys. -Chim. Sin., 2010, 26(07): 1923-1928.
[3]	SUN Xiao-Li, ZENG Qing-Xuan, FENG Chang-Gen. Adsorption Kinetics of Chromium (VI) onto an Anion Exchange Fiber Containing Polyamine [J]. Acta Phys. -Chim. Sin., 2009, 25(10): 1951-1957.
[4]	ZHOU Tian-Hua; ZHAO Jian-Xi. Adsorption Kinetics of Asymmetric Gemini Surfactants at Air/Water Interface [J]. Acta Phys. -Chim. Sin., 2007, 23(07): 1047-1052.

Fast Adsorption Removal of Congo Red on Hierarchically Porous γ-Al₂O₃ Hollow Microspheres Prepared by Microwave-Assisted Hydrothermal Method

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 4

Metrics

Recommended 0

Fast Adsorption Removal of Congo Red on Hierarchically Porous γ-Al2O3 Hollow Microspheres Prepared by Microwave-Assisted Hydrothermal Method

RichHTML

PDF

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 4

Metrics

Recommended 0

Fast Adsorption Removal of Congo Red on Hierarchically Porous γ-Al₂O₃ Hollow Microspheres Prepared by Microwave-Assisted Hydrothermal Method