Acta Phys. -Chim. Sin. ›› 2003, Vol. 19 ›› Issue (03): 208-211.doi: 10.3866/PKU.WHXB20030304

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Adsorption Thermodynamics of Macroporous Cross-linked Poly (N-methyl-N-p- vinylbenzylacetamine) Resin for Phenols from Non-aqueous System

Huang Jian-Gou;Xu Man-Cai;Li Hai-Tao;Shi Zuo-Qing;He Bing-Lin   

  1. College of Chemistry and Chemical Engineering,Hunan Normal University, Changsha　410081; The State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Institute of Polymer Chemistry, Nankai University, Tianjin　300071
  • Received:2002-06-14 Revised:2002-08-19 Published:2003-03-15
  • Contact: Xu Man-Cai E-mail:xu_mc@yahoo.com.cn

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Abstract: The title resin was synthesized and the adsorption isotherms of phenol from cyclohexane solution were measured. Values of isosteric adsorption enthalpy, adsorption Gibbs free energy and adsorption entropy were calculated. These values implied a hydrogen-bonding adsorption mechanism. Furthermore, difference of adsorption property for phenol and o-nitrophenol from cyclohexane solution was studied, and the result was in accordance with the hydrogen-bonding mechanism.

Key words: Macroporous cross-linked poly(N-methyl-N-p-vinylbenzylacetamine) resin, Non-aqueous system, Phenols, Hydrogen-bonding, Adsorption mechanism