氯化亚铜氧化反应的化学动力学初探

doi:10.3866/PKU.WHXB19920522

Abstract

Abstract: XRD and SPM techniques were used to identify the products and reaction rates for CuCl oxidization. The results showed tbe reaction between CuCl, O_2 and H_2O is rapid at ambient conditions. The bronze powder-corrosion with Cu(Ⅱ) formed through the corrosion with Cu(Ⅰ) such as (CuCl), as soon as the Cu_2(OH)_3Cl once formed, Cu(Ⅱ) ion occured in the mean while; the fresh corrosion products dispersed in solution as colloidal dispersions, and CuCl transformed into Cu_2(OH)_3Cl through Cu_2O.
The experimental phenomena were discussed. The reaction order, reaction rate, and apparent activation energy of these reaction were calculated.

Key words: Bronze, Corrosion, Activation energy

Fan Chong-Zheng; Wang Chang-Sui; Zhao Hua-Zhang; Wang Sheng-Jun. A Preliminary Approach to the Chemical Kinetics of CuCl Oxidization[J]. Acta Phys. -Chim. Sin. 1992, 8(05), 685-689. doi: 10.3866/PKU.WHXB19920522

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A Preliminary Approach to the Chemical Kinetics of CuCl Oxidization

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